Preparation method of graphene coating metal base composite powder through vapour deposition

A metal matrix composite, graphene coating technology, applied in metal processing equipment, metal material coating process, transportation and packaging, etc., can solve the problems of limited materials, decreased quality of composite powder, low output, etc., to avoid physical damage , The effect of improving material strength and low cost

Inactive Publication Date: 2016-11-09
石京
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Problems solved by technology

The chemical synthesis of the reaction solution is one of the main methods. For example, CN102130334A proposes to carry out a hydrothermal reaction in a reaction kettle with an iron salt solution and a graphene oxide mixed solution, and dry the reaction product to obtain a graphene iron oxide composite material; CN101937985A will Graphene oxide and titanium sources are mixed in different proportions, stirred until uniform, the graphene oxide/titania composite material is synthesized by the liquid phase method, and the graphene/titania composite particles are obtained through the reduction reaction, and the composite material can be used for battery anode materials; The main drawback of the method is that the output is less, the materials that can be reacted are limited, and the reaction conditions are difficult to control
The electrochemical method is also one of the main technologies for preparing graphene-containing composite particles. CN102174702 proposes a method for preparing metal nanoparticles-graphene composites. The principle is to insert conductive substrates and working electrodes into graphene oxide-containing and In the aqueous dispersion of metal compounds and depositing graphene oxide and metal compounds on the surface of the working electrode; CN 201410759742 describes the method of depositing nickel on the surface of graphene cathodes by electrophoresis to obtain graphene composite particles; although electrochemical methods can More kinds of graphene-containing composite ma

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  • Preparation method of graphene coating metal base composite powder through vapour deposition
  • Preparation method of graphene coating metal base composite powder through vapour deposition

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Embodiment Construction

[0020] A method for preparing a graphene-coated metal matrix composite powder by vapor deposition, the specific steps are as follows:

[0021] 1. After ultrasonically cleaning 3Kg of copper powder with deionized water, ethanol, and acetone, and drying at 50 to 80°C, place the obtained copper powder in the middle of a clean quartz tube;

[0022] 2. Put the quartz tube into the tube-type electric furnace, align the middle part of the quartz tube with the middle part of the tube-type electric furnace, start heating, the heating rate is 25 ℃ per minute, pass non-oxidizing gas into the quartz tube for 60 minutes, and the air flow rate is 50 sccm , while evacuating to a suitable pressure of 10 -1 Pa;

[0023] 3. When the temperature in the middle area of ​​the quartz tube reaches 1100-1200°C, maintain the reaction pressure, and feed carbon monoxide and acetylene into the quartz tube at 50 sccm, so that graphene begins to deposit on the surface of the copper powder;

[0024] 4. Dur...

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Abstract

The invention discloses a preparation method of graphene coating metal base composite powder through vapour deposition, which is easy to operate and low in cost. Through the adoption of the method, many limits in conventional methods for preparing graphene reinforcing metal base composite powder can be effectively avoided, and the produced graphene reinforcing metal base composite powder can be adapted to conventional powder metallurgy and the manufacturing process of a plurality of additional materials. According to the method disclosed by the invention, a single layer or a few layers of graphene can be uniformly coated on the surface of metal matrix powder, the combination between the metal matrix powder and the graphene is reliable, and not liable to fall, and the method disclosed by the invention is adapted to large-scale industrial production.

Description

technical field [0001] The invention relates to a method for preparing graphene-coated metal matrix composite powder by vapor phase deposition. technical background [0002] Graphene (graphene) was first obtained by Novoselov et al. of the University of Manchester in 2004 by using tape to peel off highly oriented pyrolytic graphite. It is a new material with a two-dimensional honeycomb lattice structure closely packed with carbon atoms. According to the number of layers, it can be divided into single-layer graphene and multi-layer graphene, and the thickness is generally below 100nm. Since graphene was artificially prepared, it has become a key research topic in the field of physics and materials science, and has attracted extensive attention from scholars and industrialists. Graphene is the thinnest material known in the world. It has many excellent physical properties, such as light transmittance as high as 97.7%, high thermal conductivity, high electron mobility, and res...

Claims

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Application Information

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IPC IPC(8): B22F1/02C23C16/26
CPCC23C16/26B22F1/16
Inventor 王亚超石京
Owner 石京
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