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A kind of biodegradable polymer porous composite material and preparation method thereof

A porous composite material and biodegradable technology, which is applied in the field of biodegradable polymer porous composite materials and its preparation, can solve the problems of difficult air bubble fixing and molding, mechanical properties and mechanical strength performance need to be strengthened, and achieve low cost and water absorption. Good, easy-to-operate results

Active Publication Date: 2019-01-18
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when used alone, it is not easy to form a gel, it is difficult to fix the air bubbles, and the mechanical properties and mechanical strength properties need to be strengthened

Method used

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  • A kind of biodegradable polymer porous composite material and preparation method thereof
  • A kind of biodegradable polymer porous composite material and preparation method thereof
  • A kind of biodegradable polymer porous composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Using natural polymer materials and synthetic polymers as raw materials, the biodegradable polymer porous composite material is prepared by introducing microorganisms to increase the biodegradability of the material. The preparation steps are:

[0033] In the first step, add 0.5 parts of polyvinyl alcohol in parts by mass to 100 parts of deionized water, and stir at 80° C. for 12 hours to obtain matrix A; 1.2 parts by mass of carboxymethyl cellulose, Add 0.1 part of cyclodextrin to 10 parts of deionized water, and stir at 30°C for 0.1 hour to obtain matrix B.

[0034] In the second step, the prepared foaming matrix is ​​cooled to room temperature, and the mass parts are 10 parts of matrix A, 10 parts of matrix B, 0.5 parts of fresh yeast, 0.2 parts of glucose, 0.1 parts of amino acids, and 0.05 parts of starch , 0.05 parts of citric acid-disodium hydrogen phosphate buffer solution, the temperature is 25 ° C, the stirring speed is 300r / min, stirring for 4 hours, poured i...

Embodiment 2

[0040] Using natural polymer materials and synthetic polymers as raw materials, the biodegradable polymer porous composite material is prepared by introducing microorganisms to increase the biodegradability of the material. The preparation steps are:

[0041] In the first step, add 10 parts of polyvinyl alcohol to 1000 parts of deionized water in parts by mass, and stir at 120°C for 1 hour to obtain matrix A; 2 parts by mass of gelatin and 4 parts of alginic acid Sodium was added to 1000 parts of deionized water, stirred at 100° C. for 8 hours, and matrix B was obtained.

[0042] In the second step, the prepared foaming matrix is ​​cooled to room temperature, and the mass parts are 12.5 parts of matrix A, 16 parts of matrix B, 10 parts of dry yeast, 1 part of wheat starch, 1 part of beef extract, 0.1 part of citric acid-dipotassium hydrogen phosphate buffer solution at a temperature of 40°C and a stirring speed of 400r / min, placed in a constant temperature incubator, stirred f...

Embodiment 3

[0047] Using natural polymer materials and synthetic polymers as raw materials, the biodegradable polymer porous composite material is prepared by introducing microorganisms to increase the biodegradability of the material. The preparation steps are:

[0048] In the first step, add 0.2 parts of polyvinyl alcohol into 10 parts of deionized water in parts by mass, and stir at 100°C for 2 hours to obtain matrix A; add 0.5 parts of sodium alginate, 0.1 parts of Add water-soluble chitin and 0.6 parts of hydroxyethyl cellulose to 20 parts of deionized water, and stir at 100° C. for 6 hours to obtain matrix B.

[0049] In the second step, the prepared foaming matrix is ​​cooled to room temperature, and the mass parts are 12 parts, 16 parts of matrix B, 2.5 parts of instant yeast, 2 parts of potato starch, 0.1 part of bean sprouts extract, 3 parts of Malic acid-potassium citrate buffer solution was stirred at a temperature of 36°C and a stirring speed of 500r / min for 7 hours, poured i...

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Abstract

The invention discloses a biodegradable high-polymer porous composite material and a preparation method thereof. The composite material is prepared by subjecting a porous aqueous solution system to physical cross-linked gelation. The porous aqueous solution system is prepared from, by mass, 10 to 20 parts of an aqueous polyvinyl alcohol solution, 10 to 20 parts of an aqueous solution of a waterborne natural high polymer, 0.5 to 10 parts of microbes, 0.01 to 10 parts of a nutrient solution and 0.05 to 5 parts of a pH conditioning agent. The aqueous polyvinyl alcohol solution is prepared by adding 0.1 to 20 parts of polyvinyl alcohol into 10 to 1000 parts of deionized water. The aqueous solution of the waterborne natural high polymer is prepared by adding 0.1 to 4 parts of the waterborne natural high polymer into 10 to 1000 parts of deionized water. According to the invention, the natural environment-friendly porous composite material is prepared from a foaming matrix formed by synergism, blending and compounding of the natural high polymer and synthetic high polymers, with the microbes used as a pore-forming source; the raw materials are widely and easily available and economically efficient; and the prepared composite material has the characteristics of biodegradability and no toxic and harm.

Description

【Technical field】 [0001] The invention belongs to the technical field of porous composite materials, and in particular relates to a biodegradable polymer porous composite material and a preparation method thereof. 【Background technique】 [0002] The introduction of chemical agents such as foaming agents and cross-linking curing agents during the preparation of traditional porous polymer materials pollutes the material itself, limiting its wide application in the fields of biomedicine and food packaging. Chinese patent CN102702559A discloses a method for preparing ultra-porous hydrogel by microbial fermentation, and the gel is formed by introducing a chemical cross-linking agent for monomer polymerization and cross-linking reaction. These methods avoid the use of chemical preparations such as porogens and blowing agents. Chinese patent CN10492726 discloses a preparation method of a porous hydrogel, which is to immerse the porous scaffold in the feed liquid of polyvinylpyrrol...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L1/28C08L5/16C08L29/04C08L5/04C08L89/00C08L3/02C08L5/08C08L5/12C08J9/36C08J9/04C08J3/24
CPCC08J3/246C08J9/04C08J9/36C08J2205/044C08J2205/05C08J2301/28C08J2305/04C08J2329/04C08J2389/00C08J2405/16C08L1/284C08L5/04C08L29/04C08L89/00C08L2201/06C08L2203/14C08L2205/03C08L2205/035C08L5/16C08L3/02C08L5/08C08L5/12
Inventor 张敏杨鱼李成涛刘智勇李八军
Owner SHAANXI UNIV OF SCI & TECH