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Surface treatment method of tire bead steel wire of radial tire

A radial tire and bead steel wire technology, applied in liquid chemical plating, coating, metal material coating technology, etc., can solve problems such as tire burst, loose bead, traffic accidents, etc., to enhance adhesion, improve Adhesive rate and the effect of prolonging the storage time

Active Publication Date: 2016-11-23
无锡益联机械有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, in the bead wire manufacturing industry, the tin bronze coating on the surface of the steel wire is mainly low-tin bronze. The tin bronze layer on the surface of the steel wire is used to enhance the adhesion between the bead wire and the tire rubber, so as to realize the bond between the steel wire and the tire rubber. Tightly combined to play the role of bead steel wire as the tire frame material. Once rust occurs, the low-tin bronze will not be corroded but the steel wire substrate will be corroded quickly, the coating will lose its protective effect on the steel wire substrate, and the low-tin bronze will peel off from the steel wire substrate. It is difficult for the bead wire to withstand the tension, compression, torsion, and centrifugal force generated during the driving process of the car, which can easily cause the bead to loosen and cause the tire to burst, resulting in traffic accidents

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A method for surface treatment of bead steel wire of radial tires, which is obtained by sequentially undergoing chemical salt pickling, electrolytic sulfuric acid washing, electroless copper plating, coating and drying processes for the bead steel wire;

[0016] Among them, the electroless copper plating solution is copper sulfate 10g / L, magnesium stearate 0.5g / L, sodium edetate 30g / L, alcohol amine 10g / L, sodium dodecylbenzenesulfonate 0.5g / L , sodium hypophosphite 4g / L, hydrazine hydrate 2g / L, boric acid 0.5g / L, sodium polydithiodipropane sulfonate 0.05g / L, lecithin 0.1g / L, acetate starch 0.05g / L aqueous solution;

[0017] The paint formula used in the coating coating is calculated in parts by weight: 10 parts of coumarone resin, 3 parts of hexamethoxymethylmelamine, 0.8 part of benzotriazole, 2 parts of chlorinated natural rubber, 1 part of phenolic resin, 0.5 parts of nano-silica dispersion, 0.2 parts of chlorinated polyethylene, 10 parts of toluene, and 10 parts of...

Embodiment 2

[0021] A method for surface treatment of bead steel wire of radial tires, which is obtained by sequentially undergoing chemical salt pickling, electrolytic sulfuric acid washing, electroless copper plating, coating and drying processes for the bead steel wire;

[0022] Among them, the electroless copper plating solution is copper sulfate 13g / L, magnesium stearate 0.9g / L, sodium edetate 37g / L, alcohol amine 14g / L, sodium dodecylbenzenesulfonate 0.9g / L , sodium hypophosphite 8g / L, hydrazine hydrate 3g / L, boric acid 0.7g / L, sodium polydithiodipropanesulfonate 0.09g / L, lecithin 0.3g / L, acetate starch 0.08g / L aqueous solution;

[0023] The paint formula used in the coating coating is calculated in parts by weight: 12 parts of coumarone resin, 5 parts of hexamethoxymethylmelamine, 1.7 parts of benzotriazole, 4 parts of chlorinated natural rubber, 1.8 parts of phenolic resin, 0.9 parts of nano-silica dispersion, 0.4 parts of chlorinated polyethylene, 13 parts of toluene, and 11 parts...

Embodiment 3

[0027] A method for surface treatment of bead steel wire of radial tires, which is obtained by sequentially undergoing chemical salt pickling, electrolytic sulfuric acid washing, electroless copper plating, coating and drying processes for the bead steel wire;

[0028] Among them, the electroless copper plating solution is copper sulfate 17g / L, magnesium stearate 1.1g / L, sodium edetate 44g / L, alcohol amine 18g / L, sodium dodecylbenzenesulfonate 1.1g / L , sodium hypophosphite 8g / L, hydrazine hydrate 3g / L, boric acid 1.7g / L, sodium polydithiodipropane sulfonate 0.14g / L, lecithin 0.3g / L, acetate starch 0.06g / L aqueous solution;

[0029] The paint formula used in the coating coating is calculated in parts by weight: 13 parts of coumarone resin, 6 parts of hexamethoxymethylmelamine, 3.3 parts of benzotriazole, 5 parts of chlorinated natural rubber, 2 parts of phenolic resin, 0.9 parts of nano-silica dispersion, 0.6 parts of chlorinated polyethylene, 13 parts of toluene, and 14 parts ...

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Abstract

The invention provides a surface treatment method of a tire bead steel wire of a radial tire. The tire bead steel wire is successively treated by the following working procedures including chemical hydrochloric acid washing, electrolysis sulfuric acid washing, electroless copper plating, paintcoat coating and drying, wherein chemical copper plating solution is aqueous solution of copper sulfate, magnesium stearate, sodium ethylene diamine tetracetate, alkylol amine, sodium dodecyl benzene sulfonate, sodium hypophosphite, hydrazine hydrate, boracic acid, sodium 3,3'-dithiodipropane sulfonate, lecithin and starch acetate. A paint formula adopted by paintcoat coating comprises coumarone resin, hexakis methoxymethyl melamine, benzotriazole, chloride natural rubber, phenolic resin, nanosilicon dioxide dispersoid, chlorinated polyethylene, methylbenzene and acetone. According to the treatment method, adhesive force between the tire bead steel wire and rubber can be enhanced, the surface rubber adhesion ratio of the steel wire after bonding is improved, and steel wire preservation time is prolonged.

Description

technical field [0001] The invention belongs to the technical field of tire production, and in particular relates to a surface treatment method for radial tire bead wire. Background technique [0002] Today's tire industry is making great strides in the direction of active research and development of "three modernizations" (that is, radial tires, tubeless tires and flat tires) with high technical content, high precision and excellent performance. Radial tires are increasingly favored for their excellent performances such as high speed, wear resistance, fuel economy and high mileage. In recent years, the development of steel wire skeleton materials for tires is mainly reflected in new technologies and new products (new structural steel cords), the purpose of which is to provide steel wire skeleton materials with better performance and a wider selection range for the tire industry. [0003] Radial tire bead wire is a steel wire plated with bronze, copper or brass, etc., whi...

Claims

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Application Information

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IPC IPC(8): C23C18/38C23C18/18C09D145/02C09D7/12
CPCC08L2205/035C09D145/02C23C18/1824C23C18/1848C23C18/38C08L15/02C08L61/06C08L23/286C08K13/02C08K5/3475C08K5/3492C08K3/36C08K5/01
Inventor 邱勤晓邱益诚王亚芳
Owner 无锡益联机械有限公司
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