Synthetic leather water-based mist-surface skin-feeling high-temperature-resistant pretreatment agent and preparation process thereof
A pre-treatment agent, synthetic leather technology, applied in the direction of fiber treatment, improved hand fiber, textiles and papermaking, etc., to achieve the effect of optimizing cost, good film formation, and better texture plumpness
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Embodiment 1
[0045] ⑴ Preparation of water-based polyurethane: Put 135g of polyol (50% of polyethylene adipate diol and 50% of poly-1,4-butanediol adipate) into a 1L reactor, 8g of chain extender (50% of ethylene glycol, 25% of 1,4-butanediol, 25% of 2,2 dimethylolpropionic acid), heat to 50°C, stir for 30 minutes, add diisocyanate (isophore Ketone diisocyanate 50%, toluene diisocyanate 50%) 55g, heated to 65℃~75℃, reacted for 2 hours, add 40g acetone and 0.1g catalyst organic bismuth, react at 65℃~70℃ for 2 hours, and cool to At 55°C, 1.5g of triethylamine was added for neutralization. After 20 minutes, 465.5g of water was added to the reactor for dispersion. The temperature was maintained within the range of 50°C to 60°C. The acetone was vacuumed out and filtered after 1 hour. The solid content of waterborne polyurethane is 30%.
[0046] ⑵Preparation of surface agent: accurately weigh 60g of light powder (including 100% silica), 500g of water (where water is tap water), and 500g of the wat...
Embodiment 2
[0048] ⑴ Preparation of water-based polyurethane: Put 145g of polyol (50% of polytetrahydrofurandiol, 30% of polyoxypropylene glycol, and 20% of polycaprolactone diol) and 7.5g of chain extender (of which Ethylene glycol 50%, 1,4-butanediol 20%, 2,2 dimethylolpropionic acid 30%), heat to 55°C, stir for 30 minutes, add diisocyanate (isophorone diisocyanate 60% , Toluene diisocyanate 40%) 53g, heated to 65℃~75℃, after 2 hours of reaction, add 42g acetone and 0.1g catalyst organic bismuth, react at 65℃~70℃ for 2 hours, cool to 55℃, add triethyl Neutralize with 1.9g of amine. After 20 minutes, add 622.2g of water to the reactor for dispersion. Keep the temperature in the range of 50℃~60℃. Vacuum extract acetone. After 1 hour, discharge and filter. The solid content of waterborne polyurethane is 25%.
[0049] ⑵ Preparation of surface agent: accurately weigh 60g of polished powder (including 100% silica), 400g of water (of which water is tap water), and 600g of the water-based polyure...
Embodiment 3
[0051] ⑴ Preparation of water-based polyurethane: Put 115g of polyol (50% of polytetrahydrofurandiol, 50% of polyethylene adipate-1,4-butanediol) and 6g of chain extender (in which Ethylene glycol 40%, 1,4-butanediol 30%, 2,2 dimethylolpropionic acid 30%), heat to 56°C, stir for 30 minutes, add diisocyanate (isophorone diisocyanate 80% , Toluene diisocyanate 20%) 55g, heated to 65℃~75℃, after 2 hours of reaction, add 35g acetone and 0.1g catalyst organic bismuth, react at 65℃~70℃ for 2 hours, cool to 50℃, add triethyl Neutralize with 2.1g of amine. After 20 minutes, add 457.9g of water to the reactor for dispersion. Keep the temperature in the range of 50℃~60℃. Vacuum extract acetone. After 1 hour, discharge and filter. The solid content of waterborne polyurethane is 28%.
[0052] ⑵ Preparation of surface agent: accurately weigh 55g of polished powder (including 100% silicon dioxide), 535.7g of water (where water is tap water), and 464.3g of water-based polyurethane, add them to...
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