Low power consumption charge trapping type storage device based on graphene oxide quantum dots and preparation method thereof

A technology of graphene quantum dots and charge trapping, applied in electric solid devices, circuits, electrical components, etc., can solve the problems of high power consumption and high operating voltage, and achieve the effects of low power consumption, long-lasting data storage, and low operating voltage

Active Publication Date: 2018-03-06
HEBEI UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] One of the objectives of the present invention is to provide a low-power charge-trap memory based on graphene oxide quantum dots, to overcome the problems of high operating voltage and hig

Method used

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  • Low power consumption charge trapping type storage device based on graphene oxide quantum dots and preparation method thereof
  • Low power consumption charge trapping type storage device based on graphene oxide quantum dots and preparation method thereof
  • Low power consumption charge trapping type storage device based on graphene oxide quantum dots and preparation method thereof

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Example Embodiment

[0034] Example 1

[0035] The charge trapping memory structure prepared by the present invention is as follows: figure 1 As shown, its structure is that SiO is sequentially integrated on the Si substrate 1 2 Tunneling layer 2, GQODs / Zr 0.5 hf 0.5 O 2 Trap layer, SiO 2 Barrier layer 5, Pd electrode film layer 6, GQODs / Zr 0.5 hf 0.5 O 2 The trapping layer consists of GQODs layer 3 and Zr 0.5 hf 0.5 O 2 Layer 4 is formed, and GQODs layer 3 is a single-layer graphene oxide quantum dot layer.

[0036] Si substrate 1 is a p-type Si material with 100 crystal orientation; SiO 2 The thickness of tunneling layer 2 is 2~5nm; GQODs / Zr 0.5 hf 0.5 O 2 The thickness of the trapping layer 4 is 5~80nm, preferably 10~40nm; SiO 2 The thickness of the barrier layer 5 is 5-50 nm, most preferably 5-20 nm; the Pd electrode film layer 6 is a circular electrode film with a thickness of 20-150 nm and a diameter of 60-300 μm.

Example Embodiment

[0037] Example 2

[0038] The preparation method of the charge trapping memory of the present invention, the steps are as follows:

[0039] (a) The p-Si substrate was ultrasonically cleaned in acetone, alcohol, and deionized water in sequence, and HF solution (volume ratio H 2 O:HF=2:1) ​​clean for 2 minutes, then ultrasonically clean with deionized water, remove it with N 2 Blow dry; put the treated silicon substrate into a high temperature annealing furnace, and anneal and grow SiO in an oxygen environment 2 Tunneling layer: first use 20s to raise from room temperature to 200°C, 60s to raise from 200°C to 500°C, 500°C to hold for 150s, 10s to drop to 100°C, 40s to drop from 100°C to room temperature, the obtained SiO 2 The thickness of the tunneling layer is 3nm, and SiO is obtained 2 / Si structure substrate.

[0040] (c) The SiO 2 / Si structure substrate is placed on the rotating suction cup of SC-1B glue dispenser, the speed is set to 4000r / min, the graphene oxide qua...

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Abstract

The invention provides a low power consumption charge trapping type storage device based on graphene oxide quantum dots and a preparation method thereof. The storage device is structurally composed ofan Si substrate, an SiO2 tunneling layer, a GQODs/Zr0.5Hf0.5O2 trapping layer, an SiO2 blocking layer and a Pd top electrode in sequence. The preparation method comprises the following steps: carrying out cleaning corrosion on the Si substrate, carrying out high temperature annealing growth on the SiO2 tunneling layer, uniformly paving a GQODs layer on the SiO2 tunneling layer by using an SC-1B spin coater, and plating a trapping layer, a blocking layer and an electrode film layer on an existing structure through a magnetron sputtering method. Relative to a general charge trapping type storage device, the storage device has the advantages of relatively low operating voltage, high fatigue resistance, data storage durability, large storage window, little charge leakage, low power consumption, low cost and the like, is extremely applicable for being applied to electronic equipment, and has certain market application values.

Description

technical field [0001] The invention relates to a non-volatile memory device and a preparation method thereof, in particular to a low-power charge-trapping memory based on graphene oxide quantum dots and a preparation method thereof. Background technique [0002] The traditional Flash memory is a non-volatile memory, which consists of a silicon substrate, a tunneling layer, a floating gate layer, a barrier layer and a top electrode from bottom to top. Under the action of a certain bias voltage, the carriers in the substrate will tunnel through the oxide insulating layer and enter the floating gate layer. At this time, the metal floating gate is charged compared with before, and there are two completely different states of charged and uncharged. Realized the storage of information. Affected by Moore's Law, in order to miniaturize the device and scale it down, the tunneling layer has reached the physical limit of 7nm. Since the charge is evenly distributed in the floating ga...

Claims

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Application Information

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IPC IPC(8): H01L27/11563H01L27/11568
CPCH10B43/00H10B43/30
Inventor 闫小兵王宏张园园赵建辉周振宇
Owner HEBEI UNIVERSITY
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