The invention relates to an organic photochromic composite nano materials and method for preparing same, wherein the material has the structural formula of [R1]-[M]-[R2][R3], wherein [M] is naphtha or benzoxazine, spiro-pyrans and naphthopyrans chemical functional group, [R1] is straight chain alkyl, alkoxy, halogen, halogenated alkyl, nitro, [R2] is alkoxy, cycloalkyl, oxygen-containing, nitrogen-containing heterocycte, halogen, nitro. [R3] is straight chain alkyl, branched chain alkyl, hydroxyalkyl, carboxylic alkyl. The carrier can employ PVB resin, polystyrene resin, polymethyl methacryate, acetyl butyryl cellulose, PET resin powder, or polyvinyl pyrrolidon resin. The material also includes anti-oxidant, hindered amine light stabilizer, and single state oxygen quencher.