The invention relates to 3D direct writing zirconium oxide colloid ink, which comprises the following raw materials: zirconium oxide particles, a solvent, a binder, an acid agent, an alkali agent anda dispersant, wherein the particle size of the zirconium oxide particles is 0.05-2 [mu]m, the solid content of the zirconium oxide particles in the ink is 40-56 vol%, the dispersant is one or a variety of materials selected from polyacrylic acid, polyvinyl acid, ammonium polyacrylate, polyethyleneimine, polyacrylate, polyvinyl acid salt and polycarboxylate, the dispersant accounts for 0.1-4 wt% ofthe mass of the zirconium oxide particle dry powder, the amount of the acid does not exceed 0.1% of the mass of the ink, the amount of the alkali does not exceed 0.1% of the mass of the ink, and a molar ratio of the hydrogen ion to the hydroxide ion in the acid agent and the alkali agent is (0.01-4):1. According to the present invention, with the application of the 3D direct writing zirconium oxide colloid ink to print at the room temperature, the high solid content can be provided while the 3D direct writing zirconium oxide colloid ink can be outflow from the fine spraying nozzle and the clogging cannot occur, the 3D direct writing zirconium oxide colloid ink can be rapidly cured into the fine wire with a certain strength so as to be used for various modeling, and the 3D direct writing zirconium oxide colloid ink has good rheological property.