The present invention involves a double -layer floating grid flexible organic storage device and its preparation methods. The invention is mainly based on substrate, medium layer, control grid, blocking layer, first floating grid layer, isolation layer, second floating grid layer, tunnel, tunnel, tunnel, tunnel, tunnelThe wearing layer, organic semiconductor layer, source electrode and leakage electrode composition, where the source electrode and leakage electrode are located on the tunnel through the tunnel layer.The use of double -layer gold nano crystals as the floating grille layer will help improve the storage window of the storage device and increase the working voltage range; use femtosecond laser restoration technology to reduce repeated sedimentary electrodes in the middle, simplify the production process, reduce production, and reduce production.The doping of pollution in China is conducive to improving product yields; the blocking layers, quarantine layers, and then wearing layers used in the present invention are all graphene with high -agency constants, which can effectively reduce the leakage current and improve the stability of the memory.It can reduce the working voltage; the materials used in the present invention are flexible, can be bent, and can be applied to a flexible circuit.The femtosecond laser restoration technology, vacuum thermal evaporation and rotation technology used in the preparation process of the present invention, mature process, low production costs, can achieve large -scale production.