The invention relates to a preparation method of a BaTiO3 micron fiber with a resistance characteristic. An Si chip is selected and sequentially subjected to ultrasonic treatment with acetone, absolute ethanol and deionized water, Ba(CH3COO)2 powder is dissolved in a glacial acetic acid and ethylene glycol monomethyl ether mixed solution, a solution A is obtained after stirring, a Ti(OC4H9)4 solution is dissolved in an ethanol and lactic acid mixed solution, a solution B is obtained after stirring, PVP powder is dissolved in a mixed solution of A and B and stirred in a water bath at 80 DEG C, a solution C is obtained, BaTiO3 micron fiber is spun on the Si chip with a glass rod, and the fiber is annealed in a tubular furnace at 900 DEG C. The defects of low operation speed, high loss and short service life of traditional Flash memory are overcome. The process is simple, the fiber is synthesized in one step, raw materials are cheap, the synthesis quantity is large, and the fiber is flexible and convenient, has very high resistive switch ratio and has the good resistive switch characteristic under the control of voltage.