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Glass bead modified PBT material and preparation method thereof

The technology of glass microbeads and hollow glass microbeads is applied in the field of glass microbead modified PBT material and its preparation, which can solve the problems of reduced encapsulation efficiency, difficulty in controlling the curing process of epoxy resin viscosity changes, etc., so as to improve the adhesion , Excellent interface bonding effect

Inactive Publication Date: 2018-03-13
刘健文
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patent CN104610711B discloses a PBT material with good epoxy resin adhesion and its preparation method. Through the synergistic effect of each component, the material has excellent anti-aging performance, and the introduction of reactive functional groups with the ability to react with epoxy resin improves the interface adhesion with epoxy resin, but the viscosity of epoxy resin changes during use Rapid curing process is difficult to control, and rapid curing results in reduced encapsulation efficiency

Method used

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Examples

Experimental program
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Effect test

Embodiment

[0026] Weigh: 70 kg of PBT, 18 kg of aluminum dihydrogen phosphate, 18 kg of borax, 6 kg of potassium sodium silicate, 6 kg of zinc oxide, 10 kg of hydrogenated castor oil, 2 kg of cryolite, and 2452 kg of antioxidant;

[0027] The hydrogenated castor oil includes the following parts by weight: 10 parts of PBT, 5 parts of hollow glass beads, and 2 parts of PP-g-MAH graft compatibilizer.

[0028] Specific steps are as follows:

[0029] (1) Preparation of hydrogenated castor oil:

[0030] Mix the PBT and PP-g-MAH grafting compatibilizers evenly, and pour them into the main feed port of the twin-screw extruder; put hollow glass beads into the side feed port at the rear end of the extruder; The screw extruder extrudes strands and pellets to obtain hydrogenated castor oil, ready for use;

[0031] (2) Preparation of microcapsule curing agent:

[0032] ①. Under stirring conditions, add 0.5wt% zinc oxide aqueous solution and 0.5wt% potassium sodium silicate aqueous solution, and disperse for 40...

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PUM

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Abstract

The invention discloses a glass bead modified PBT (polybutyleneterephthalate) material. The material comprises the following raw materials in parts by weight: 60-80 parts of PBT, 15-20 parts of aluminium dihydrogen phosphate, 15-20 parts of borax, 5-8 parts of sodium potassium silicate, 5-10 parts of zinc oxide, 6-12 parts of hydrogenated castor oil, 1-3 parts of cryolite, and 1-3 parts of an anti-oxidant 245. A curing agent after coating is introduced in order to increase content of function group which has reaction capability with epoxy resin in the material, and at the same time, the microcapsule curing agent can break microcapsules at a certain condition for slow release in order to complete solidification behavior, so that the purpose that the casting glue solidification process between the material and an epoxy resin is controlled is realized, and interface caking property between the material and epoxy resin is improved; further, the advantage of the hollow glass bead vacuum structure is fully performed, and density, dielectric constant and electric conductivity of the PBT material are reduced.

Description

Background technique [0001] Polybutylene terephthalate (English name Polybutylene Terephthalate, PBT for short) is a milky white translucent to opaque, crystalline thermoplastic polyester. It has excellent electrical properties, high heat resistance, toughness, fatigue resistance, self-lubrication, low friction coefficient, weather resistance, low water absorption, and maintains various physical properties (including electrical properties) in a humid environment, and moldability Good, so it is widely used in automobiles, electronic and electrical parts as engineering plastics. [0002] The engine ignition coil is the main component of the engine ignition system. Its function is to increase the low voltage of the car battery to a high voltage of 20kv to 40kv that can cause spark plug discharge. Therefore, in order to prevent electrical breakdown of the ignition coil under high voltage and increase the insulation strength of the ignition coil components, the ignition coil component...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L51/06C08K13/04C08K7/28C08K3/32C08K3/38C08K3/34C08K3/22
CPCC08L67/02C08L2205/025C08L2205/03C08L51/06C08K13/04C08K7/28C08K2003/327C08K2003/387C08K3/34C08K2003/2296
Inventor 刘健文
Owner 刘健文
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