Heavy metal stabilizer for bottom mud in aquaculture pond, and manufacturing method and application thereof

A technology of heavy metal stabilizer and pond bottom sludge, which is applied in the agricultural field, can solve the problems of different adsorption and fixation effects of heavy metals, differences in physical and chemical properties, microbial inactivation, etc., and achieve the effect of reducing effectiveness, good effect and rich nutrition

Active Publication Date: 2018-04-20
HOHAI UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Microbial activity is the key factor affecting the stabilization of heavy metals in sediment by microbial inoculation method. At present, most inoculation agents are directly put into the sediment, which may easily cause microbial inactivation or loss. Therefore, the development of new microbial carriers to ensure microbial activity is a main technology of this patent breakthrough
The inventor's previous studies have shown that biomass charcoal has a porous structure and a high specific surface area, and the surface contains various functional groups such as hydroxyl, carbonyl, and carboxyl. It is an excellent microbial immobilization carrier and heavy metal adsorbent, but it is affected by different raw materials and preparation processes. , the physical and chemical properties of the prepared carriers are quite different, and the adsorption and fixation effects on heavy metals are also different.

Method used

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  • Heavy metal stabilizer for bottom mud in aquaculture pond, and manufacturing method and application thereof
  • Heavy metal stabilizer for bottom mud in aquaculture pond, and manufacturing method and application thereof
  • Heavy metal stabilizer for bottom mud in aquaculture pond, and manufacturing method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Embodiment 1, sediment stabilizer component optimization scheme

[0044] 1. Raw material processing:

[0045] Raw materials are processed before each treatment group is formulated

[0046] 1. Preparation of straw biochar: first cut the straw into small sections of 3cm to 5cm, air-dry until the water content is 10% to 12%, use the carbonization furnace, adopt the method of oxygen limitation and slow temperature rise, first pass in nitrogen, and discharge the furnace Inner air, then raised from room temperature to 100°C at a rate of 10°C / min, preheated for 50 minutes to make the raw materials evenly heated, then raised to 600°C, pyrolyzed at a constant temperature for 1.5 hours, taken out, cooled and crushed through an 80-mesh sieve for later use.

[0047] 2. Preparation of Mailuoning medicinal dregs biochar: collect the medicinal dregs of Mailuoning, air-dry until the water content is about 50%, use a pulverizer to crush it into debris less than 3cm, and air-dry until t...

Embodiment 2

[0064] Embodiment 2 Bottom sludge heavy metal stabilizer dosage optimization scheme

[0065] The heavy metal stabilizers prepared by the 5 treatment groups in Example 1 were added to the bottom mud at the ratio of 2%, 3%, 5%, and 10% by mass, and piled up for 7 days at 30°C. , turn the pile every 1d, and take samples on the 7th day to determine the leaching value of heavy metals and the adsorption stability rate. The results are shown in Table 3.

[0066] Table 3 The effect of stabilizer dosage on the leaching value and adsorption stability rate of heavy metals in sediment

[0067]

[0068] The results in Table 3 show that: with the increase of heavy metal stabilizers in the sediment, the leaching value of heavy metals is gradually decreasing, and the adsorption stability rate is gradually increasing. When it increases from 2% to 3%, the heavy metal adsorption stability rate increases significantly. When it reaches 5%, the increase in the heavy metal adsorption stability ...

Embodiment 3

[0069] Example 3, optimization scheme of sediment heavy metal stabilization time

[0070] With the heavy metal stabilizer prepared by 5 treatment groups in Example 1, add the bottom mud in a ratio of 5% (mass ratio), and under the condition of 30°C, pile up 3d, 5d, 7d, 9d respectively, and turn over once every 1d , the sediment samples were taken at 3d, 5d, 7d, and 9d to measure the leaching value and adsorption stability rate of heavy metals in the sediment. The results are shown in Table 4.

[0071] Table 4 Effect of stabilizer action time on heavy metal leaching value and adsorption stability rate of sediment

[0072]

[0073] The results in Table 4 show that as the stacking time increases, the heavy metal adsorption stability rate increases first and then decreases. From 3d to 5d, the heavy metal adsorption stability rate increases significantly. From 5d to 7d, the difference in the increase of heavy metal adsorption rate becomes smaller. From From 7d to 9d, the adsorp...

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Abstract

The invention relates to a heavy metal stabilizer for bottom mud in an aquaculture pond, and a manufacturing method and an application thereof. The heavy metal stabilizer comprises a microbial carrierand a composite microbial agent loaded on the microbial carrier, wherein the microbial carrier is a mixture of Mailuoning herb residue biomass carbon powder, tea residue powder, alternanthera philoxeroides powder and a binder; and a composite active bacterial liquid is obtained through the following steps: mixing a bottom mud sample and deionized water so as to obtain a supernatant diluent, carrying out culturing so as to obtain a seed solution of bacillus and yeast, adding an EM active bacterial liquid, and carrying out culturing under the condition of aerobic fermentation. The preparation method comprises the following preparation process: (1) allowing Mailuoning herb residues to be converted into biomass carbon at a high temperature, and mixing the biomass carbon with raw materials soas to obtain the microbial carrier; and (2) loading the composite microbial agent onto the microbial carrier. According to the invention, the bottom mud fermented by stacking with the heavy metal stabilizer can be used as a base fertilizer and applied to soil, so the fertility of the soil is improved; the effectiveness of heavy metals in the soil is reduced; the usage amount of an inorganic fertilizer is decreased; and the yield and quality of crops are improved.

Description

technical field [0001] The invention relates to the field of agriculture, in particular to a production method and application of a heavy metal stabilizer for bottom sludge in aquaculture ponds. Background technique [0002] The bottom mud of aquaculture ponds is rich in organic matter, N, P, K and other nutrient elements. It is a high-quality organic fertilizer. It can not only improve soil fertility, but also increase crop yield. However, due to natural or man-made factors such as atmospheric subsidence, surface runoff, unreasonable application of fishing medicine and bait, a large amount of toxic heavy metals enter the aquaculture water environment, and are finally enriched in the sediment through adsorption, precipitation, etc. The heavy metal contents of Pb, Cu, Zn and Cr in the soil were significantly higher than the local soil background value and the content of Cd was seriously exceeded (≥0.5mg / kg). Therefore, if the heavy metals in the sediment are not repaired in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/02C02F11/00C12N1/02C12N1/20C12N1/16C12N11/14C12N11/10C02F103/20C02F101/20
CPCC02F11/004C02F11/008C02F11/02C02F2101/20C02F2103/007C02F2103/20C12N1/02C12N1/16C12N1/20C12N11/10C12N11/14
Inventor 毛欣宇秦恒基王惠文许明王明月李静战意和邵孝侯
Owner HOHAI UNIV
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