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A method for the treatment of tebuconazole pesticide production wastewater and the recovery of potassium sulfate resources

A technology for producing wastewater and treatment methods, which is applied in biological water/sewage treatment, natural water treatment, multi-stage water treatment, etc. It can solve the problems of ineffective resource recovery and poor treatment effect, and achieve excellent treatment effect and high COD. Removal rate and the effect of recycling

Active Publication Date: 2020-06-26
NANJING UNIV YANCHENG ENVIRONMENTAL PROTECTION TECH & ENG RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] In view of the problem that the treatment effect of tebuconazole pesticide wastewater in the prior art is not good, and the resources therein cannot be effectively recovered, the present invention aims to provide a tebuconazole with low cost, good comprehensive treatment effect, and the ability to recover potassium sulfate resources at the same time. Treatment method of azole alcohol pesticide wastewater

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  • A method for the treatment of tebuconazole pesticide production wastewater and the recovery of potassium sulfate resources
  • A method for the treatment of tebuconazole pesticide production wastewater and the recovery of potassium sulfate resources
  • A method for the treatment of tebuconazole pesticide production wastewater and the recovery of potassium sulfate resources

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Comparison scheme
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Embodiment 1

[0039] This embodiment provides a method for treating tebuconazole pesticide production wastewater, in which effective recovery of potassium sulfate resources is carried out, and the treatment object is tebuconazole pesticide wastewater from a workshop of a pesticide enterprise in Binhai, Jiangsu. The process flow diagram of the present invention is as figure 1 As shown, the processing steps are as follows:

[0040] (1) Treatment of wastewater from ketene and condensation production section: including blow-off-micro-electrolysis-Fenton oxidation-neutralization precipitation treatment. The specific steps of the treatment process are:

[0041] a) Stripping: Collect the ketene from the tebuconazole pesticide preparation process in the workshop and the wastewater from the condensation production section separately into the collection tank, pump the wastewater into the stripping tower, and strip it at 60°C for 2 hours.

[0042] b) Micro-electrolysis: The waste water is pumped into the ir...

Embodiment 2

[0063] This embodiment provides a method for the treatment of tebuconazole pesticide production wastewater, in which effective recovery of potassium sulfate resources is carried out, and the treatment object is tebuconazole pesticide wastewater from a workshop of a pesticide company in Binhai, Jiangsu. The combined treatment process steps are as follows:

[0064] (1) Treatment of wastewater from ketene and condensation production sections. The treatment process includes the following steps:

[0065] a) Blowing off: After collecting the ketene from the tebuconazole pesticide preparation process in the workshop and the wastewater from the condensation production section separately into the collection tank, pump the waste water in the collection tank into the blowing off tower at 70℃ Blow off for 4h.

[0066] b) Micro-electrolysis: use a pump to pump water into the iron-carbon micro-electrolysis kettle, first adjust the pH of the wastewater to 3 with sulfuric acid, and then add cast ir...

Embodiment 3

[0080] This embodiment provides a method for the treatment of tebuconazole pesticide production wastewater, in which effective recovery of potassium sulfate resources is carried out, and the treatment objects are the same as in embodiment 2. The combined treatment process steps in this embodiment are as follows:

[0081] (1) Treatment of wastewater from ketene and condensation production sections. The treatment process includes the following steps:

[0082] a) Blowing off: After collecting the ketene from the tebuconazole pesticide preparation process and the wastewater from the condensation production section in the workshop separately into the collection tank, pump the waste water in the collection tank into the blowing off tower at 65℃ Blow off for 3h.

[0083] b) Micro-electrolysis: Then pump the water into the iron-carbon micro-electrolysis kettle, first adjust the pH of the wastewater to 4 with sulfuric acid, then add cast iron powder to the wastewater and mechanically stir for...

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Abstract

The invention discloses a tebuconazole pesticide production wastewater treatment and potassium sulphate salt resource recovery method, and belongs to the technical field of pesticide wastewater treatment. The treatment method is characterized in that ketene in the tebuconazole pesticide production process, wastewater at condensation production work section and wastewater at epoxy production work section are collected and treated in a separated way, wherein the ketene and the wastewater at condensation production work section are subjected to air stripping-microelectrolysis-Fenton oxidation-neutralization sedimentation treatment; the wastewater at epoxy production work section is subjected to resin adsorption treatment and potassium sulphate recovery; finally, effluent treated by the two modes is merged and enters biochemical treatment. The treatment method solves the problem that the subsequent treatment effect during the mixed treatment of the ketene, the degradable wastewater generated at the condensation production work section and the degradable wastewater generated at the epoxy production work section are poor; the potassium sulphate salt in wastewater realizes resource recovery and utilization.

Description

Technical field [0001] The invention belongs to the field of pesticide wastewater treatment technology, and specifically relates to a method for tebuconazole pesticide production wastewater treatment and potassium sulfate resource recovery. Background technique [0002] Tebuconazole is a triazole fungicide and a sterol demethylation inhibitor. At present, it can be used in the seed treatment or foliar spraying of important economic crops all over the world. The medicament has a wide bactericidal spectrum, high activity, and long lasting period. It can effectively control a variety of rust, powdery mildew, net spot, root rot, head blight, smut and seed-borne wheel spot of cereal crops. Wait. Tebuconazole has been registered and widely used in more than 50 countries and more than 60 crops in the world. It is the fastest growing and largest sales species among triazole fungicides. [0003] Tebuconazole production generally uses p-chlorobenzaldehyde as the starting material, and is ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C02F101/32C02F101/30C02F103/36
CPCC02F1/04C02F1/20C02F1/28C02F1/461C02F1/66C02F1/722C02F1/725C02F3/02C02F3/2846C02F9/00C02F2101/32C02F2101/40C02F2103/36C02F2301/08
Inventor 戴建军刘莉莉李正斌双陈冬赵选英周伟伟杨峰陈利芳
Owner NANJING UNIV YANCHENG ENVIRONMENTAL PROTECTION TECH & ENG RES INST