Phase separation self cleaning acrylate stone-like paint emulsion and preparation method thereof
A technology of acrylate and butyl methacrylate, which is applied in the self-cleaning acrylate real stone paint emulsion and its preparation, and in the field of acrylate emulsion, which can solve the problems that the coating is not easy to clean, affect the appearance of the building, and the color difference. Achieve the effect of preventing pollution particles from staying, high efficiency, and high glass transition temperature
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[0036] In addition, the present invention also provides a preparation method of the phase-separated self-cleaning acrylic real stone paint emulsion, specifically comprising the following steps:
[0037] a) Preparation of base liquid A: at normal temperature, add 40-50 parts of deionized water and 1-5 parts of emulsifier into the reaction kettle, stir evenly, and raise the temperature to 80-90°C in the kettle;
[0038] b) Preparation of pre-emulsion B: at normal temperature and pressure, add 30-50 parts of deionized water and 1-10 parts of emulsifier to the pre-emulsification cylinder with unit metering and agitator, stir well, and then Add 15-30 parts of styrene, 10-30 parts of methyl methacrylate, 20-40 parts of butyl methacrylate, 20-40 parts of 2-ethylhexyl acrylate, and 5-20 parts of functional monomer, and stir 10-30 minutes for standby;
[0039] c) Preparation of pre-emulsion C: at normal temperature and pressure, add 50-60 parts of deionized water and 1-5 parts of emul...
Embodiment 1
[0046] A phase-separated self-cleaning acrylic real stone paint emulsion, comprising the following raw materials in parts by mass: 160 parts of deionized water, 30 parts of styrene, 30 parts of methyl methacrylate, 40 parts of butyl methacrylate, acrylic acid - 40 parts of 2-ethylhexyl ester, 10 parts of functional monomer, 4 parts of emulsifier, 2 parts of initiator, and 4 parts of pH regulator.
[0047] The functional monomer is mixed with acrylic acid, acrylamide, fluorine monomer, silane coupling agent and isobornyl methacrylate according to the ratio of 5:1.5:1:1.5:1.
[0048] The fluorine monomer is trifluoroethyl acrylate.
[0049] The silane coupling agent is γ-methacryloxytrimethoxysilane.
[0050] The emulsifier is disodium decyl polyoxyethylene (6) ether ester of sulfosuccinate.
[0051] The initiator is ammonium persulfate.
[0052] The pH regulator is ammonia water.
[0053] In addition, the present invention also provides a preparation method of the phase-sep...
Embodiment 2
[0063] A phase-separated self-cleaning acrylic real stone paint emulsion, comprising the following raw materials in parts by mass: 200 parts of deionized water, 45 parts of styrene, 55 parts of methyl methacrylate, 60 parts of butyl methacrylate, acrylic acid - 60 parts of 2-ethylhexyl ester, 25 parts of functional monomer, 14 parts of emulsifier, 11 parts of initiator, and 5 parts of pH regulator.
[0064] The functional monomer is mixed with acrylic acid, acrylamide, fluorine monomer, silane coupling agent and isobornyl methacrylate according to the ratio of 5.5:1.5:1:1:1.
[0065] The fluorine monomer is hexafluorobutyl ester. The silane coupling agent is vinyltrimethoxysilane.
[0066] The emulsifier is allyloxy fatty alcohol oxyethylene ether ammonium sulfate.
[0067] The initiator is azobisisobutyronitrile. The pH regulator is sodium hydroxide.
[0068] In addition, the present invention also provides a preparation method of the phase-separated self-cleaning acrylic...
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