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Phase separation self cleaning acrylate stone-like paint emulsion and preparation method thereof

A technology of acrylate and butyl methacrylate, which is applied in the self-cleaning acrylate real stone paint emulsion and its preparation, and in the field of acrylate emulsion, which can solve the problems that the coating is not easy to clean, affect the appearance of the building, and the color difference. Achieve the effect of preventing pollution particles from staying, high efficiency, and high glass transition temperature

Inactive Publication Date: 2018-08-10
佛山市顺德区巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, due to the increasingly fierce competition in the real stone paint market, in order to compete with their peers and increase profits, many real stone paint manufacturers and constructors do not carry out surface treatment after the real stone paint is constructed. It will soon become gray, and the color is obviously different from that at the beginning of construction, and the coating is not easy to clean, which affects people's perception of the appearance of the building

Method used

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Examples

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preparation example Construction

[0036] In addition, the present invention also provides a preparation method of the phase-separated self-cleaning acrylic real stone paint emulsion, specifically comprising the following steps:

[0037] a) Preparation of base liquid A: at normal temperature, add 40-50 parts of deionized water and 1-5 parts of emulsifier into the reaction kettle, stir evenly, and raise the temperature to 80-90°C in the kettle;

[0038] b) Preparation of pre-emulsion B: at normal temperature and pressure, add 30-50 parts of deionized water and 1-10 parts of emulsifier to the pre-emulsification cylinder with unit metering and agitator, stir well, and then Add 15-30 parts of styrene, 10-30 parts of methyl methacrylate, 20-40 parts of butyl methacrylate, 20-40 parts of 2-ethylhexyl acrylate, and 5-20 parts of functional monomer, and stir 10-30 minutes for standby;

[0039] c) Preparation of pre-emulsion C: at normal temperature and pressure, add 50-60 parts of deionized water and 1-5 parts of emul...

Embodiment 1

[0046] A phase-separated self-cleaning acrylic real stone paint emulsion, comprising the following raw materials in parts by mass: 160 parts of deionized water, 30 parts of styrene, 30 parts of methyl methacrylate, 40 parts of butyl methacrylate, acrylic acid - 40 parts of 2-ethylhexyl ester, 10 parts of functional monomer, 4 parts of emulsifier, 2 parts of initiator, and 4 parts of pH regulator.

[0047] The functional monomer is mixed with acrylic acid, acrylamide, fluorine monomer, silane coupling agent and isobornyl methacrylate according to the ratio of 5:1.5:1:1.5:1.

[0048] The fluorine monomer is trifluoroethyl acrylate.

[0049] The silane coupling agent is γ-methacryloxytrimethoxysilane.

[0050] The emulsifier is disodium decyl polyoxyethylene (6) ether ester of sulfosuccinate.

[0051] The initiator is ammonium persulfate.

[0052] The pH regulator is ammonia water.

[0053] In addition, the present invention also provides a preparation method of the phase-sep...

Embodiment 2

[0063] A phase-separated self-cleaning acrylic real stone paint emulsion, comprising the following raw materials in parts by mass: 200 parts of deionized water, 45 parts of styrene, 55 parts of methyl methacrylate, 60 parts of butyl methacrylate, acrylic acid - 60 parts of 2-ethylhexyl ester, 25 parts of functional monomer, 14 parts of emulsifier, 11 parts of initiator, and 5 parts of pH regulator.

[0064] The functional monomer is mixed with acrylic acid, acrylamide, fluorine monomer, silane coupling agent and isobornyl methacrylate according to the ratio of 5.5:1.5:1:1:1.

[0065] The fluorine monomer is hexafluorobutyl ester. The silane coupling agent is vinyltrimethoxysilane.

[0066] The emulsifier is allyloxy fatty alcohol oxyethylene ether ammonium sulfate.

[0067] The initiator is azobisisobutyronitrile. The pH regulator is sodium hydroxide.

[0068] In addition, the present invention also provides a preparation method of the phase-separated self-cleaning acrylic...

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Abstract

The invention discloses phase separation self cleaning acrylate stone-like paint emulsion and a preparation method thereof, and belongs to the field of stone-like paint emulsion. The phase separationself cleaning acrylate stone-like paint emulsion is prepared from the following raw materials in parts by weight: 160 to 240 parts of deionized water, 30 to 60 parts of styrene, 30 to 80 parts of methyl methacrylate, 40 to 80 parts of butyl methacrylate, 40 to 80 parts of acrylic acid-2-ethylhexyl acrylate, 10 to 40 parts of functional monomers, 4 to 25 parts of emulsifying agents, 2 to 20 parts of initiators and 1 to 10 parts of pH regulators. The self cleaning acrylate stone-like paint emulsion provided by the invention has the advantages that a copolymerization and shell-core technology composite process is used; a special synthesis processing method is used; special latex particles with two phases in one emulsion are finally obtained; latex particles in the film forming process are mutually interlinked and wound; the formed film is compact and hydrophobic; the pollution particle dwell can be effectively prevented.

Description

technical field [0001] The invention relates to an acrylic ester emulsion, in particular to a phase-separated self-cleaning acrylic real stone paint emulsion and a preparation method thereof, belonging to the field of real stone paint emulsions. Background technique [0002] Real stone paint is a kind of coating product mainly made of high-performance polymer emulsion, natural or artificially dyed colored sand of various colors, and various additives. Real stone paint has the following characteristics: environmental protection and durability, fire prevention, waterproof, acid and alkali resistance, pollution resistance, non-toxic, tasteless, strong adhesion, etc., can effectively prevent the external harsh environment from eroding buildings, and is suitable for use in most areas ; The cost is low, equivalent to about a quarter of dry-hanging marble; the construction process is simple, and the color and pattern can be selected according to personal preferences to achieve pers...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F212/08C08F220/14C08F220/06C08F220/56C08F220/24C08F230/08C09D133/10C09D133/08C09D5/16
CPCC08F220/18C08F220/1804C08F220/1806C09D5/1668C09D133/08C09D133/10C08F212/08C08F220/14C08F220/06C08F220/56C08F220/24C08F230/08C08F220/1811
Inventor 林中华曾庆乐杨文涛何美娟
Owner 佛山市顺德区巴德富实业有限公司
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