Ceramic alloy coating and coating layer

A ceramic alloy and coating technology, applied in the field of ceramic alloy coatings and coatings, can solve the problems of coating failure, limited toughening effect, shutdown, etc., and achieve the effect of ensuring hardness, construction difficulty and cost reduction

Inactive Publication Date: 2018-11-13
深圳陶金材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the coatings prepared by these materials and processes are excellent in high temperature resistance, oxidation resistance, and corrosion resistance, due to the intrinsic brittleness of ceramic materials, the coatings prepared by them are easily damaged under extreme conditions such as high temperature and thermal shock. Cracking and peeling occurs, leading to coating failure, and in severe cases, damage to equipment and shutdown
[0004] Some people have proposed a toughening scheme for ceramic coatings. For example, CN201710839455 uses carbon nanotubes to toughen SiBCN ceramics, but the method is complicated and uses a large amount of organic gas raw materials, which is costly and pollutes heavily; CN201710604226 discloses a multi-metal hybrid ceramic Matrix composite material, a sandwich structure composed of C / SiC ceramic matrix composite material and metal sheet, however, due to the anisotropy of the sandwich structure, the physical properties of the coating in each scheme are very different, which increases the difficulty of construction; CN201610241996 provides nano Alumina ceramic coating is used to modify the existing ceramic coating. By adding nano-sized particles to the components, the grains, grain boundaries and the combination between them can reach the nano-level, which greatly improves the strength and toughness of the coating. , but the toughening principle of nano-scale particles is mainly based on the point pinning effect, while nano-scale particles are easy to grow during the heating process, and the toughening effect is limited

Method used

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  • Ceramic alloy coating and coating layer
  • Ceramic alloy coating and coating layer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Weigh the high hardness Al 2 O 3 25 kg of ceramic powder, 30 kg of SiC ceramic powder with high emissivity, 15 kg of kaolin, and 50 kg of sodium silicate aqueous solution, pour into a stirring vessel, stir evenly to obtain a liquid mixture; inject the above liquid mixture into the vertical In the sand mill, the ball-to-battery ratio is 1:1, the sand is homogenized for 2 hours, and the high-temperature functional ceramic slurry is obtained after filtration.

[0042] Weigh 40 kilograms of high-toughness metallic Cr fiber, 20 kilograms of high thermal conductivity aluminum powder, and 50 kilograms of sodium silicate aqueous solution into a stirring vessel for stirring treatment, add the high-temperature functional ceramic slurry prepared above and stir at high speed for 30 minutes. After filtering, the high-temperature ceramic alloy coating is obtained after packaging.

[0043] The obtained high-temperature ceramic alloy coating is stirred and filtered, sprayed onto the surface...

Embodiment 2

[0046] Weigh high hardness SiO 2 Ceramic powder 30 kg, high emissivity Si 3 N 4 30 kg of ceramic powder, 40 kg of montmorillonite, and 80 kg of potassium silicate aqueous solution are poured into a stirring vessel and stirred evenly to obtain a liquid mixture; the above liquid mixture is injected into a vertical sand mill with a ball-to-material ratio of 1:1, sanding and homogenizing treatment for 2 hours, and filtering treatment to obtain high-temperature functional ceramic slurry.

[0047] Weigh 20 kilograms of high-toughness metallic Ni fiber, 10 kilograms of high thermal conductivity copper powder, and 40 kilograms of potassium silicate aqueous solution into a stirring vessel for stirring treatment. Add the high-temperature functional ceramic slurry prepared above and stir at high speed for 30 minutes. After filtering, the high-temperature ceramic alloy coating is obtained after packaging.

[0048] The obtained high-temperature ceramic alloy coating is stirred and filtered, spr...

Embodiment 3

[0051] Weigh high hardness ZrO 2 40 kg of ceramic powder, 40 kg of BN ceramic powder with high emissivity, 10 kg of rectorite, 60 kg of aluminum dihydrogen phosphate aqueous solution, pour into a stirring vessel, stir evenly to obtain a liquid mixture; combine the above liquid mixture Inject into a vertical sand mill with a ball-to-battery ratio of 1:1, sand and homogenize for 2 hours, and filter to obtain high-temperature functional ceramic slurry.

[0052] Weigh 15 kilograms of high-toughness metal Ti fiber, 25 kilograms of high thermal conductivity aluminum powder, and 30 kilograms of aluminum dihydrogen phosphate aqueous solution into a stirring vessel for stirring. Add the high-temperature functional ceramic slurry prepared above and stir at high speed for 30 minutes , After filtering and packaging, high-temperature ceramic alloy coatings can be obtained.

[0053] The obtained high-temperature ceramic alloy coating is stirred and filtered, sprayed onto the surface of the metal...

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Abstract

The invention discloses a ceramic alloy coating and a coating layer, wherein the coating includes a ceramic solid phase component, a metal solid phase component and a liquid phase component; the ceramic alloy coating is characterized in that the ceramic solid phase component includes high-hardness oxide ceramic powder, high-emissivity non-metallic oxide ceramic powder and lamellar structural silicate powder; the metal solid phase component includes high-toughness metal fibers and high-thermal-conductivity metal powder; the liquid phase component is one of a liquid silicate inorganic binder, aliquid phosphate inorganic binder and a liquid sol inorganic binder, the strength and toughness of the ceramic coating layer can be effectively improved. Moreover, the preparation method is simple andis prone to promotion and application.

Description

Technical field [0001] The invention relates to the field of ceramic alloy coatings and coatings, and is suitable for long-term heat-resistant and corrosion-resistant protection of metal materials in high-temperature environments. Background technique [0002] As the industry has higher and higher requirements for materials and structures that work in high-temperature environments, people have developed a variety of high-temperature protective coatings for metal anti-corrosion, from single-layer coatings to multi-layers in the traditional sense Composite gradient coating, the coating material is from pure metal material to current ceramic coating and composite coating of metal material and ceramic material, and gives the coating material anti-corrosion, anti-oxidation protection and some special functions. [0003] The coating materials have developed from pure aluminide coatings to the current ceramic thermal barrier coating technology, and the construction methods also range from...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/26C04B28/34C04B40/02C04B111/20
CPCC04B28/26C04B28/344C04B2111/00525C04B2111/2038C04B2111/2084C04B2201/10C04B2201/32C04B2201/50C04B14/303C04B14/324C04B14/106C04B14/48C04B22/04C04B40/0263C04B20/008C04B14/328C04B14/06C04B14/104C04B14/327C04B14/306C04B14/10
Inventor 戴雷魏一杰王亚文唐知桥刘春艳
Owner 深圳陶金材料科技有限公司
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