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Multifunctional membrane coating liquid suitable for ink-jet and laser printing, and preparation method thereof

A laser printing and multi-functional technology, applied in the direction of coating, polyurea/polyurethane coating, etc., can solve the problems of single function and inability to be widely used in different products, and achieve the effect of smooth surface, good antistatic effect and avoiding paper jams

Active Publication Date: 2018-11-30
JIANGSU HUAXIN NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the single function of the current printing materials, which cannot be universally applicable to different product requirements, and provide a multi-functional film coating solution suitable for inkjet and laser printing and its preparation method, which can improve the polymer film to a certain extent. Insufficiency of sheets in the application of printing materials

Method used

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  • Multifunctional membrane coating liquid suitable for ink-jet and laser printing, and preparation method thereof
  • Multifunctional membrane coating liquid suitable for ink-jet and laser printing, and preparation method thereof
  • Multifunctional membrane coating liquid suitable for ink-jet and laser printing, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Add 15g of polycarbonate diol into a 500ml four-necked flask, raise the temperature to 85°C, then vacuum-dry for 1 hour, cool down to 55°C, add 40g of isophorone diisocyanate, and then gradually raise the temperature to 80°C. After reacting for 1.5 hours, lower the temperature to 45°C, add 0.015g of bismuth-zinc composite catalyst, 8.20g of hydrophilic chain extender dimethylol butyric acid, 5.10g of crosslinking agent 1,4-butanediol, trimethylolpropane 2.75g, 4.05g of 4-hydroxybutyl acrylate, gradually raise the temperature to 63°C, then add 10.52g of acetone, and continue the reaction for 4 hours. Cool down to 20°C, add 3.21g of triethylamine for neutralization, and continue the reaction for 15 minutes. 68.16g of ionized water, after stirring for 15min, slowly add 1.10g of chain extender ethylenediamine for secondary chain extension and last for 15min, the rate of dropping ethylenediamine is controlled between 0.10g / min, and the modified waterborne polyurethane is obt...

Embodiment 2

[0073] Add 12g of polycarbonate diol into a 500ml four-necked flask, raise the temperature to 85°C, then vacuum-dry for 1.5 hours, cool down to 60°C, add 40g of isophorone diisocyanate, and then gradually raise the temperature to 85°C. After reacting for 2 hours, lower the temperature to 55°C, add 0.016g of bismuth-zinc composite catalyst, 7.80g of hydrophilic chain extender dimethylol butyric acid, 5.20g of crosslinking agent 1,4-butanediol, trimethylolpropane 2.60g, 4.68g of 4-hydroxybutyl acrylate, gradually raise the temperature to 65°C, then add 11.20g of acetone, and continue the reaction for 5 hours. Cool down to 20°C, add 3.01g of triethylamine for neutralization, and continue the reaction for 15 minutes. 71.20g of ionized water, after stirring for 15min, slowly add 1.08g of chain extender ethylenediamine for secondary chain extension and last for 15min, the rate of dropping diamine is controlled between 0.15g / min, and the modified waterborne polyurethane is obtained ...

Embodiment 3

[0086] Add 16g of polycarbonate diol into a 500ml four-necked flask, raise the temperature to 83°C, then vacuum-dry for 1.5 hours, cool down to 58°C, add 40g of isophorone diisocyanate, and then gradually raise the temperature to 85°C. After reacting for 2 hours, lower the temperature to 55°C, add 0.020g of bismuth-zinc composite catalyst, 5.60g of hydrophilic chain extender dimethylol butyric acid, 4.48g of crosslinking agent 1,4-butanediol, trimethylolpropane 1.68g, 3.92g of 4-hydroxybutyl acrylate, the temperature was gradually raised to 65°C, and then 10.80g of acetone was added, and the reaction was continued for 5 hours. Cool down to 20°C, add 2.90g of triethylamine for neutralization, and continue the reaction for 15 minutes. 75.10g of ionized water, after stirring for 15min, slowly add 1.12g of chain extender ethylenediamine for secondary chain extension and last for 15min, the rate of dropping diamine is controlled between 0.09g / min, and the modified waterborne polyur...

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Abstract

The invention discloses a multifunctional membrane coating liquid suitable for ink-jet and laser printing, and a preparation method thereof. The preparation method comprises following steps: firstly,isophorone diisocyanate and a polycarbonate diol are subjected to polymerization, an appropriate amount of a hydroxyl acrylate is added, chain propagation, neutralization, and emulsification are carried out so as to obtain a primarily modified aqueous polyurethane; polyvinyl alcohol solutions with different functions are prepared, and a mixed dispersion solution of silica and alumina is prepared,and at last, mixing with auxiliary agents such as a wetting agent, an anti-foaming agent, a thickening agent, and an antistatic agent is carried out so as to obtain the multifunctional membrane coating liquid suitable for ink-jet and laser printing. The preparation method is low in preparation cost and excellent in printing effect; the production technology is simple; the multifunctional membranecoating liquid is convenient for coating; the solid content is as high as 35%; the multifunctional membrane coating liquid is suitable for coating of a plurality of polyester or polyolefin membranes such as PET, PVC, and PETG membranes, and can be used for production of coated products with different functions.

Description

technical field [0001] The invention relates to a multifunctional diaphragm coating solution suitable for inkjet and laser printing and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] The rapid development of computer technology, digital imaging technology, and the popularization of computers have made various digital printing and digital printing technologies continue to improve. Compared with digital printing, digital printing is more flexible and more personalized. The advancement of science and technology and the development of the economy have promoted the innovation of emerging materials, especially functional polymer materials. By coating the surface of ordinary plastic diaphragms, the diaphragms are endowed with various specific functions. [0003] There are two most commonly used digital printing technologies. Among them, inkjet printing has higher resolution and clearer printed images, but its disa...

Claims

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Application Information

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IPC IPC(8): C09D129/04C09D175/04C09D7/61C08G18/44C08G18/10C08G18/66C08G18/75C08G18/32C08G18/34C08G18/67C08J7/04
CPCC08G18/10C08G18/44C08G18/6651C08G18/6659C08G18/755C08J2329/04C08J2427/06C08J2467/02C08J2475/04C08L2205/025C08L2205/03C09D129/04C08J7/0427C08L29/04C08L75/04C08K3/36C08K2003/2227C08G18/348C08G18/672C08G18/3228
Inventor 周建石张道远王光战吴彬
Owner JIANGSU HUAXIN NEW MATERIAL
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