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Accelerator for accelerating anaerobic digestion of excess sludge, preparation method and application thereof

A technology of excess sludge and anaerobic digestion, which is applied in the field of resource utilization of solid waste, can solve the problems of low sludge reduction and resource utilization, iron cannot be reused, and iron dissolution rate is slow, so as to broaden the pH range, accelerated dissolution, and enhanced hydrolysis effects

Active Publication Date: 2020-10-02
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In view of the existing iron treatment process of excess sludge, the dissolution rate of iron is slow and the efficiency is low. At the same time, it needs to be combined with enhanced pretreatment to achieve better digestion effect. Iron cannot be reused, the amount of methane produced is small, and sludge reduction and Due to the low degree of resource utilization and narrow application range, the present invention provides an accelerator for accelerating the anaerobic digestion of excess sludge and its preparation method and application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Preparation of accelerator for accelerating anaerobic digestion of excess sludge

[0040] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. Add 100ml of a 20% mass concentration polyaluminum chloride aqueous solution to the 20L of remaining sludge, and then add 200g of sodium ethylenediaminetetraacetate and stir. The stirring time is 1 hour, the stirring speed is 200r / min, and the water content is dehydrated to 75%. Sodium hydroxide solution is added to adjust the pH to 10-11, and then the pH is adjusted to 7-8 with dilute hydrochloric acid to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, dry one part of the neutral sludge at a drying temperature of 80℃, drying time of 20 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 400℃ The pyrolysis time is 1 hour to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserved for later use. The obtai...

Embodiment 2

[0042] Preparation of accelerator for accelerating anaerobic digestion of excess sludge

[0043] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. To the 20L of the remaining sludge, add 140ml of a 20% mass concentration polyaluminum chloride aqueous solution, and then add 400g of sodium ethylenediaminetetraacetate and stir. The stirring time is 1.5 hours, the stirring speed is 250r / min, and the water content is dehydrated to 80%. Sodium hydroxide solution is added to adjust the pH to 10-11, and then diluted hydrochloric acid is used to adjust the pH to 7-8 to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, and dry one part of the neutral sludge at a drying temperature of 100°C and a drying time of 22 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 450°C , The pyrolysis time is 1.5 hours to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserv...

Embodiment 3

[0045] Preparation of accelerator for accelerating anaerobic digestion of excess sludge

[0046] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. Add 200ml of a 20% mass concentration polyaluminum chloride aqueous solution to the 20L of remaining sludge, and then add 800g of sodium ethylenediaminetetraacetate and stir. The stirring time is 2 hours, the stirring speed is 300r / min, the water content is dehydrated to 85%, sodium hydroxide solution is added to adjust the pH to 10-11, and then the pH is adjusted to 7-8 with dilute hydrochloric acid to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, and dry one part of the neutral sludge at a drying temperature of 120°C and a drying time of 24 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 500°C The pyrolysis time is 2 hours to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserved for later use....

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Abstract

The invention discloses an accelerant for accelerating anaerobic digestion of excess sludge as well as a preparation method and application thereof, and belongs to the field of solid waste reclamation. According to the accelerant as well as a preparation method and application thereof, the problems that in existing iron treatment excess sludge, pretreatment needs to be enhanced, the iron dissolution rate is low, the efficiency is low, and the sludge reduction and reclamation degree is low can be solved, the excess sludge is used as a raw material, a series of steps are carried out so as to obtain sludge activated carbon which is highly activated, then the sludge activated carbon, iron powder, common activated carbon and a binder are mixed according to a specific ratio and are pressed intoballs, sintering is carried out, then sodium ethylene diamine tetracetate is added, pressing forming is carried out, and drying is carried out so as to obtain the accelerant for accelerating anaerobicdigestion of the excess sludge; and an iron-carbon micro-electrolysis principle is utilized, the dissolution of iron is accelerated, due to the existence of ethylene diamine tetraacetic acid and Mn,the pH range of the accelerant in the sludge treatment is widened, the pH of the sludge does not need to be adjusted, the sludge can be treated by directly using the accelerant obtained through the method, and the cost is lowered.

Description

Technical field [0001] The invention belongs to the field of solid waste resource utilization, and specifically relates to an accelerator for accelerating anaerobic digestion of excess sludge, and a preparation method and application. Background technique [0002] With the continuous improvement of the level of urbanization in my country, the development of sewage treatment technology has been informed. According to statistics, 3,501 urban sewage treatment plants have been built across the country, with a sewage treatment capacity of 147 million m3 / day (a kind of increase in excess activated sludge Oxygen elimination supplement). With the continuous improvement of processing capacity and throughput, the accompanying problem is a substantial increase in the amount of remaining sludge. According to statistics, my country produces more than 30 million tons of sludge every year (calculated with a moisture content of 80%). The sludge contains a large amount of organic matter, bacteri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/04
CPCC02F11/04Y02E50/30
Inventor 刘波杜凌峰程绍举侯玉倩盛世雄周德超葛志斌
Owner NANJING UNIV
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