Accelerator for accelerating anaerobic digestion of excess sludge, preparation method and application thereof
A technology of excess sludge and anaerobic digestion, which is applied in the field of resource utilization of solid waste, can solve the problems of low sludge reduction and resource utilization, iron cannot be reused, and iron dissolution rate is slow, so as to broaden the pH range, accelerated dissolution, and enhanced hydrolysis effects
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Embodiment 1
[0039] Preparation of accelerator for accelerating anaerobic digestion of excess sludge
[0040] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. Add 100ml of a 20% mass concentration polyaluminum chloride aqueous solution to the 20L of remaining sludge, and then add 200g of sodium ethylenediaminetetraacetate and stir. The stirring time is 1 hour, the stirring speed is 200r / min, and the water content is dehydrated to 75%. Sodium hydroxide solution is added to adjust the pH to 10-11, and then the pH is adjusted to 7-8 with dilute hydrochloric acid to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, dry one part of the neutral sludge at a drying temperature of 80℃, drying time of 20 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 400℃ The pyrolysis time is 1 hour to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserved for later use. The obtai...
Embodiment 2
[0042] Preparation of accelerator for accelerating anaerobic digestion of excess sludge
[0043] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. To the 20L of the remaining sludge, add 140ml of a 20% mass concentration polyaluminum chloride aqueous solution, and then add 400g of sodium ethylenediaminetetraacetate and stir. The stirring time is 1.5 hours, the stirring speed is 250r / min, and the water content is dehydrated to 80%. Sodium hydroxide solution is added to adjust the pH to 10-11, and then diluted hydrochloric acid is used to adjust the pH to 7-8 to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, and dry one part of the neutral sludge at a drying temperature of 100°C and a drying time of 22 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 450°C , The pyrolysis time is 1.5 hours to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserv...
Embodiment 3
[0045] Preparation of accelerator for accelerating anaerobic digestion of excess sludge
[0046] Take 20L of the remaining sludge in the secondary settling tank and weigh it. The weight is 20kg. Add 200ml of a 20% mass concentration polyaluminum chloride aqueous solution to the 20L of remaining sludge, and then add 800g of sodium ethylenediaminetetraacetate and stir. The stirring time is 2 hours, the stirring speed is 300r / min, the water content is dehydrated to 85%, sodium hydroxide solution is added to adjust the pH to 10-11, and then the pH is adjusted to 7-8 with dilute hydrochloric acid to obtain neutral sludge. Divide the obtained neutral sludge into two equal parts, and dry one part of the neutral sludge at a drying temperature of 120°C and a drying time of 24 hours, crushing, vacuum pyrolysis, and a pyrolysis temperature of 500°C The pyrolysis time is 2 hours to obtain the sludge activated carbon matrix raw material, and the other neutral sludge is reserved for later use....
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