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Preparation method of hydrophobic, oleophobic and antibacterial coating for surface of textile material

A hydrophobic and oleophobic, fabric material technology, applied in textile material processing, liquid/gas/vapor textile processing, textile and papermaking, etc. Hydrophobic and oleophobic properties, strong self-protection ability, strong self-cleaning ability

Inactive Publication Date: 2019-03-22
佛山市南海区里水镇经济促进局 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, in the current technology, the moisture resistance and oil repellency of the fabric cannot be fully expressed, so that the tensile strength of the fabric is easily reduced due to moisture in the application of the material, and it is easy to be damaged; because of poor oil repellency, the fabric is in use The process is polluted by oil, which leads to unsightly packaging or use, causing unnecessary losses; at the same time, cloth materials are flammable, and fire hazards must be prevented at all times during storage and use; for food in daily life The use of packing tape and the contact of a large number of living things will easily form a microbial adsorption layer on the surface of the cloth, which will affect human safety and health
[0006] In the currently disclosed technology, there is a modification of the cloth, through the dehydration condensation reaction with the hydroxyl group on the surface of the cloth, the hydrophobic group is linked to the end of the molecular surface of the cloth, and the hydrophobic effect of the group is used to resist the interference of external water. However, Surface modification cannot change the internal properties of the cloth material, and it is still a flammable product; some cloth is modified first with TiO 2 Modify the surface of the cloth material, so that through TiO 2 Improve the flame retardant performance of the material, and then graft low surface energy materials on the surface through surface modification technology, and finally obtain hydrophobic and flame retardant materials, but use TiO 2 In the process of changing the surface roughness of the cloth, the color of the cloth material may be changed, affecting the appearance and display effect

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Preparation method of hydrophobic, oleophobic and antibacterial coating for surface of textile material

Examples

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Embodiment 1

[0036] A method for preparing a hydrophobic, oleophobic and antibacterial coating on the surface of a fabric material, the selected base material is cloth, specifically comprising the following steps:

[0037]1. Pretreatment: The base material is ultrasonicated for 5 minutes at room temperature with a surface eluent. The composition of the surface eluent is: sodium bicarbonate (1.5%), ethanol (10%), fatty alcohol polyoxyethylene ether sodium sulfate ( 7.5 w / %), sodium dodecylbenzenesulfonate (8w / %), cocoic acid diethanolamide (0.6w / %), pure water (72.4%); then rinse the surface with ultrapure water, and then place Soak in strong alkaline electrolytic water for 1min. The components of the strong alkaline solution are: NaOH (0.5%), sodium bicarbonate (1%), sodium phosphate (2%), ethanol (6.5%), pure water (90%) . Take it out and rinse the surface with ultrapure water, then soak it in 40°C ethanol solution for 5 minutes, finally rinse it with ultrapure water, put it in an oven a...

Embodiment 2

[0041] A method for preparing a hydrophobic, oleophobic and antibacterial coating on the surface of a fabric material, the selected base material is cloth, specifically comprising the following steps:

[0042] 1. Pretreatment: The base material is ultrasonicated for 5 minutes at room temperature with a surface eluent. The composition of the surface eluent is: sodium bicarbonate (1.5%), ethanol (10%), fatty alcohol polyoxyethylene ether sodium sulfate ( 7.5 w / %), sodium dodecylbenzenesulfonate (8w / %), cocoic acid diethanolamide (0.6w / %), pure water (72.4%); then rinse the surface with ultrapure water, and then Soak in strong alkaline electrolyzed water for 1min. The components of the strong alkaline solution are: NaOH (0.5%), sodium bicarbonate (1%), sodium phosphate (2%), ethanol (6.5%), pure water (90% ). Take it out and rinse the surface with ultrapure water, then soak it in 40°C ethanol solution for 5 minutes, finally rinse it with ultrapure water, put it in an oven at 70°...

Embodiment 3

[0046] A method for preparing a hydrophobic, oleophobic and antibacterial coating on the surface of a fabric material, the selected base material is cloth, specifically comprising the following steps:

[0047] 1. Pretreatment: The base material is ultrasonicated for 5 minutes at room temperature with a surface eluent. The composition of the surface eluent is: sodium bicarbonate (1.5%), ethanol (10%), fatty alcohol polyoxyethylene ether sodium sulfate ( 7.5 w / %), sodium dodecylbenzenesulfonate (8w / %), cocoic acid diethanolamide (0.6w / %), pure water (72.4%); then rinse the surface with ultrapure water, and then Soak in strong alkaline electrolyzed water for 1min. The components of the strong alkaline solution are: NaOH (0.5%), sodium bicarbonate (1%), sodium phosphate (2%), ethanol (6.5%), pure water (90% ). Take it out and rinse the surface with ultrapure water, then soak it in 40°C ethanol solution for 5 minutes, finally rinse it with ultrapure water, put it in an oven at 70°...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses hydrophobic, oleophobic and antibacterial coating for the surface of a textile material. The hydrophobic, oleophobic and antibacterial coating is prepared from the following components according to the mol ratio: the ratio of methyltriethoxysilane to perfluorooctyltriethoxysilane to modified nano silicon dioxide to water is (3 to 4) to (4 to 5) to (3 to 4) to (7 to 9); thehydrophobic, oleophobic and antibacterial coating further contains ethyl lauroyl arginate hydrochloride which accounts for 0.1 to 5 weight percent of the coating. According to the hydrophobic, oleophobic and antibacterial coating, a cloth material is washed through a specific pre-treatment technology and dip-coating of the coating is carried out; curing treatment is carried out by adopting a specific technology to obtain a hydrophobic, oleophobic and antibacterial coating layer. The hydrophobic, oleophobic and antibacterial coating layer provided by the invention has the advantages of good adhesion force, strong self-cleaning capability, strong hydrophobic and oleophobic performance, flame-retarding performance and antibacterial performance, is applicable to various cloth materials and hasan extremely strong self-protection capability; the surface of cloth has hydrophobic and oleophobic characteristics and the pollution-resisting property can be effectively enhanced; the hydrophobic,oleophobic and antibacterial coating has a relatively great application prospect.

Description

technical field [0001] The invention belongs to the technical field of material surface modification, and more specifically relates to a method for preparing a hydrophobic, oleophobic and antibacterial coating on the surface of a fabric material. Background technique [0002] While the extensive use of existing petroleum-based packaging materials brings convenience to people's lives, it also produces a series of negative effects, namely, environmental pollution caused by packaging waste and the intensified consumption of non-renewable petroleum resources. For this reason, biomass green environmental protection materials are gradually being developed and utilized by researchers. Cloth materials, as a kind of biomass materials, have unique advantages in terms of economic benefits and environmental protection benefits, and there are many kinds of fabrics, and the price is low for the public. Accepted, from its production to the end of its life, is pollution-free and pollution-f...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06N3/00D06N3/12D06B3/10D06B15/00D06M11/38D06M11/71D06M11/76D06M13/144D06M13/256D06M13/402D06M15/53
CPCD06B3/10D06B15/00D06M11/38D06M11/71D06M11/76D06M13/144D06M13/256D06M13/402D06M15/53D06N3/0002D06N3/0088D06N3/128D06N2209/067D06N2209/142D06N2209/145D06N2209/1671
Inventor 曾晖李瑞李金辉
Owner 佛山市南海区里水镇经济促进局
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