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A kind of calcium magnesium zinc liquid stabilizer and application thereof

A liquid stabilizer, calcium-magnesium-zinc technology, applied in the field of calcium-magnesium-zinc liquid stabilizers, can solve the problems of large difference in refractive index of silicone oil substances, affecting product opacity, affecting product quality, etc., to achieve good synergistic performance and excellent transparency , Durable processability and the effect of peeling performance

Active Publication Date: 2020-11-20
ZHEJIANG TRANSFAR WHYYON CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the commonly used surfactant additives have high hydrophilicity and low molecular weight. According to the national standard for the ultraviolet absorption test of the blood transfusion (liquid) equipment extract, the results are often high, which affects product quality; and silicone oils The refractive index of the substance is quite different from that of PVC, and the opacity of the product will be seriously affected after adding

Method used

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  • A kind of calcium magnesium zinc liquid stabilizer and application thereof
  • A kind of calcium magnesium zinc liquid stabilizer and application thereof
  • A kind of calcium magnesium zinc liquid stabilizer and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Zinc isooctanoate 350g, zinc 4-tert-butylbenzoate 250g, liquid calcium oleate 300g, magnesium laurate 300g, diethylene glycol monobutyl ether 100g, kerosene 400g, block polyethylene oxide-polypropylene oxide castor oil Ester 300g.

[0028] After mixing the above formula into a uniform stabilizer, let it stand for use.

[0029] According to the composition ratio of PVC resin: PVC (SG-1000) 100kg, dioctyl terephthalate 35kg, epoxy soybean oil (B-22) 10kg, antifogging agent AF 0.5kg, stabilizer 3kg. Put the above formula into a high-speed mixer for high-speed thermal mixing, and the end temperature of thermal mixing is 125°C. Enter the cold mix and set aside.

[0030] The cooled powder is subjected to single-screw granulation, the temperature of the granulation die head is 168°C, and the detection value during melting and compaction is not greater than 12.5pa. After granulation, pass through a vibrating sieve and collect.

[0031] The collected pellets are put into a s...

Embodiment 2

[0037] The raw material ratio of the stabilizer: 60g of zinc 4-tert-butylbenzoate, 30g of liquid calcium oleate, 30g of magnesium stearate, 30g of block polyethylene oxide-polypropylene oxide ricinoleate, Octyl ester 20g, diethylene glycol monobutyl ether 5g, liquid paraffin 25g.

Embodiment 3

[0041] Raw material ratio of stabilizer: 35g of zinc oleate, 25g of zinc 4-tert-butylbenzoate, 30g of liquid calcium oleate, 30g of magnesium stearate, 30g of block polyethylene oxide-polypropylene oxide ricinoleate, Dioctyl terephthalate 20g, diethylene glycol monobutyl ether 5g, liquid paraffin 25g.

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Abstract

The invention discloses a Ca-Mg-Zn liquid stabilizer and an application thereof. At present, a common PVC material has the problems of white frost generation in water mist and bag body adhesion afterhigh temperature and pressure steam disinfection. The Ca-Mg-Zn liquid stabilizer includes: zinc organic acid salt, calcium oleate, magnesium organic acid salt, a blocked polyethylene oxide-polypropylene oxide ricinoleate being 2400-2600 in molecular weight, and a solvent; wherein EO / PO molar ratio of the blocked polyethylene oxide-polypropylene oxide ricinoleate is 1:3-4. The components have excellent synergistic effect, so that the stabilizer is good in compatibility with polyvinyl chloride resin and is toxic-free and environment-friendly. The stabilizer has excellent transparency, can resisthigh temperature adhesion and prevent white frost generation in water mist, and has outstanding solution effect for problems in (blood) transfusion devices in practical application at present.

Description

technical field [0001] The invention relates to a polyvinyl chloride heat stabilizer, in particular to a calcium-magnesium-zinc liquid stabilizer and its application. Background technique [0002] In the field of medical blood transfusion (liquid) apparatus, the application of polyvinyl chloride resin (PVC) is very important. Usually use soft PVC material calendering to make medical blood transfusion (liquid) container film, then make bag through high-frequency heat sealing, combine PVC catheter and other auxiliary parts to form a complete set of blood (liquid) equipment. During this process, due to the easily degradable characteristics of polyvinyl chloride, once it degrades, it cannot pass the strict standard of the national standard GB15593 for medical blood transfusion (liquid) appliances. Therefore, such stabilizers must have efficient thermal stability properties. [0003] Since blood transfusion (liquid) equipment needs specific monitoring when used, good transparen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L71/02C08L91/00C08L91/06C08K5/098C08L27/06C08K5/12C08K5/11
CPCC08K5/005C08K5/098C08K5/11C08K5/12C08K2201/014C08L27/06C08L71/02C08L91/00C08L91/06C08L2201/08C08L2201/10C08L2205/02C08L2205/025C08L2205/035
Inventor 丁礼源童敏伟胡奋奋俞凯
Owner ZHEJIANG TRANSFAR WHYYON CHEM
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