A kind of high-sensitivity environment-friendly one-component rotary mesh photoresist and its preparation method and application

A high-sensitivity, single-component technology, applied in the direction of optomechanical equipment, photosensitive materials for optomechanical equipment, optics, etc., can solve the problems of unseen high-sensitivity photosensitive adhesive patent disclosure, photosensitive adhesive pollution, resolution accuracy and Exposure speed can not be achieved and other problems, to achieve the effect of fast exposure speed, improved physical and chemical properties, water resistance and stability

Active Publication Date: 2022-07-01
浙江易能感光材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The application of DMD lithography technology is a great progress in the field of screen making technology, but it also puts forward high requirements on the resolution performance and exposure rate of photosensitive adhesives. Currently, commercially available photosensitive adhesives are not only polluted by heavy metals such as hexavalent chromium The problem is that the resolution accuracy and exposure rate are far from meeting the requirements of DMD lithography technology, and there is no way to maximize the advantages of DMD lithography technology
Equally, also do not see the relevant high-sensitivity photoresist patent disclosure that can be used for DMD lithography technology

Method used

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  • A kind of high-sensitivity environment-friendly one-component rotary mesh photoresist and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] 30wt% bisphenol A epoxy resin, 5wt% acrylic resin, 5wt% liquid nitrile rubber and 20wt% modified acid anhydride as thermosetting resin composition and 10wt% polyvinyl alcohol cinnamate, 5wt% organic styrylpyridine Onium salt, 5wt% tetramethylbenzoquinone, 5wt% benzophenone are in a water bath at a constant temperature of 80 degrees Celsius, slowly add 3wt% phenethylphenol polyoxypropylene polyoxyethylene ether aqueous solution for modification while stirring, and stir After one hour, a stable aqueous mixture was obtained, and the reaction was kept for 2 hours. After cooling to room temperature, 10% polyvinyl acetate acrylic copolymer, defoamer, surfactant, dyeing agent, and acrylic acid copolymer were added to the prepared emulsion while stirring. Add water appropriately to adjust the viscosity to obtain photosensitive colloid. Then, according to the method of Comparative Example 1, a rotary screen printing screen was prepared.

Embodiment 2

[0038] 30wt% bisphenol A epoxy resin, 5wt% acrylic resin, 5wt% liquid nitrile rubber and 20wt% modified acid anhydride were used as thermosetting resin composition and 10wt% 1,6 hexanediol diacrylate, 5wt% organic benzene Vinyl pyridinium salt, 5wt% tetramethylbenzoquinone, 5wt% benzophenone are slowly added in 3wt% phenethyl cumyl phenol polyoxyethylene ether aqueous solution while stirring at a constant temperature of 80 degrees Celsius in a water bath. Modified, stirred for one hour to obtain a stable aqueous mixture, incubated for 2 hours, cooled to room temperature, and added 10% polyvinyl acetate acrylic copolymer and defoamer, surface Activating agent, dyeing agent, and appropriately adding water to adjust the viscosity to obtain photosensitive colloid. Then, according to the method of Comparative Example 1, a rotary screen printing screen was prepared.

Embodiment 3

[0040] 20wt% bisphenol A epoxy resin, 5wt% acrylic resin, 5wt% liquid nitrile rubber and 10wt% modified acid anhydride as thermosetting resin composition and 40wt% 1,6 hexanediol diacrylate, 15wt% organic benzene Vinylpyridinium salt, 15wt% tetramethyl benzoquinone, 15wt% benzophenone are slowly added 10wt% phenethyl cumyl phenol polyoxyethylene ether aqueous solution under the condition of constant temperature of 80 degrees Celsius in a water bath. Modified, stirred for one hour to obtain a stable aqueous mixture, incubated for 2 hours, cooled to room temperature, and added 50% polyvinyl acetate acrylic copolymer and defoamer, surface Activating agent, dyeing agent, and appropriately adding water to adjust the viscosity to obtain photosensitive colloid. Then, according to the method of Comparative Example 1, a rotary screen printing screen was prepared.

[0041] Table 1: Experimental Results

[0042]

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Abstract

The invention relates to a new environment-friendly photosensitive polymer material, in particular to a high-sensitivity environment-friendly single-component rotary mesh photosensitive adhesive and a preparation method and application thereof. The high-sensitivity and environment-friendly one-component rotary network photosensitive adhesive of the present invention is mainly composed of a thermosetting resin, a latent curing agent, a toughening resin, a photocurable resin, a photopolymerization initiator, a sensitizer, a free radical scavenger and an additive. The self-emulsifying process is used to make high-sensitivity and environmental-friendly one-component rotary screen photosensitive adhesive. Due to the efficient sensitization reaction of the photosensitive system, a high-sensitivity photosensitive speed and an ultra-high resolution of 20um are obtained; the environmentally friendly one-component rotary screen photosensitive adhesive made from this can be stored stably for a long time, not only can replace the traditional Bichromate / PVA and other two-component photosensitive systems solve the problem of hexavalent chromium heavy metal pollution in the prior art, and its exposure speed is extremely fast, which can be quickly exposed and cured under low ultraviolet energy under DMD lithography rays to complete fine The requirements for rapid mesh making of the pattern are suitable for the rapid mesh making of DMD lithography technology.

Description

technical field [0001] The invention relates to a new environment-friendly photosensitive polymer material, in particular to a high-sensitivity environment-friendly single-component rotary mesh photosensitive adhesive and a preparation method and application thereof. Background technique [0002] Rotary screen printing is a printing technology that uses a scraper to make the color paste in the circular screen made of the pattern printed on the substrate under pressure. This technology can continuously and quickly produce printed textiles or walls in large quantities. cloth, etc., so as to be applied on a large scale. The exquisite patterns of rotary screen printing are realized by rotary screen printing screen plates made of rotary screen photosensitive adhesives through the processes of coating-drying-ultraviolet exposure-developing imaging-heat curing. [0003] DMD lithography technology is currently the most advanced mesh technology in the world. The core of the system i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/004G03F7/027G03F7/029G03F7/031
CPCG03F7/004G03F7/027G03F7/029G03F7/031
Inventor 王宁王路王艳奇陈海平
Owner 浙江易能感光材料有限公司
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