Flexible geopolymer-based anticorrosive paint and preparation method and application thereof

Inactive Publication Date: 2019-10-08
SOUTH CHINA UNIV OF TECH
View PDF8 Cites 12 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional toughening modification methods (aqueous emulsion toughening, cellulose toughening, etc.) simply physically blend flexible organic polymer materials with geopolymers, and cannot change the properties of geopolymers at the molecular level. structure, it is difficult to fundamentally improve the brittleness of the geopolymer; and the addition of toughening materials also hinders the formation of the tetrahedral structure of the geopolymer SiAl
Finally, although the toughness of the modified geopolymer has been improved to a certain extent, its mechanical strength will also be greatly reduced, which has obvious shortcomings.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Flexible geopolymer-based anticorrosive paint and preparation method and application thereof
  • Flexible geopolymer-based anticorrosive paint and preparation method and application thereof
  • Flexible geopolymer-based anticorrosive paint and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Mix 30 parts of diatomaceous earth, 5 parts of titanium dioxide, 1 part of carbon black, 20 parts of talcum powder, and 44 parts of micaceous iron oxide to obtain component A;

[0038] (2) 85 parts of sodium silicate with a modulus of 3.3, 2.5 parts of curing regulator potassium hydroxide, 5.5 parts of rheology modifier bentonite, and 7 parts of water are uniformly mixed to obtain component B;

[0039] (3) Mix 50 parts of diphenyldiethoxysilane, 30 parts of phenyltrimethoxysilane and 20 parts of tetraethyl orthosilicate to obtain component C;

[0040] (4) Stir with a high-speed disperser, slowly add 52 parts by weight of component A to 28 parts by weight of component B, and then continue to add 20 parts by weight of component C to obtain a flexible geopolymer-based anti-corrosion coating.

Embodiment 2

[0042] (1) Mix 30 parts of fly ash, 35 parts of diatomaceous earth, 2 parts of iron red, 10 parts of heavy calcium carbonate, and 23 parts of glass flakes to obtain component A;

[0043] (2) 55 parts of sodium silicate with a modulus of 2.5, 3 parts of curing regulator calcium hydroxide, 0.5 part of rheology modifier fumed silica, and 41.5 parts of water are mixed uniformly to obtain component B;

[0044] (3) Mix 40 parts of methyltrimethoxysilane, 45 parts of phenyltriethoxysilane and 15 parts of octadecyltrimethoxysilane to obtain component C;

[0045] (4) Stir with a high-speed disperser, slowly add 27 parts by weight of component A to 15 parts by weight of component B, and then continue to add 58 parts by weight of component C to obtain a flexible geopolymer-based anti-corrosion coating.

Embodiment 3

[0047] (1) Mix 15 parts of kaolin, 5 parts of titanium dioxide, 1 part of carbon black, 30 parts of talcum powder, and 49 parts of quartz powder to obtain component A;

[0048] (2) 64 parts of modulus are 1.7 sodium water glass, 5 parts of curing regulator sodium hydroxide, 3 parts of rheology modifier polyamide wax, 3 parts of rheology modifier xanthan gum, 25 parts of water mix Obtain B component evenly;

[0049] (3) Mix 60 parts of methylphenyldimethoxysilane and 40 parts of butyltrimethoxysilane evenly to obtain component C;

[0050] (4) Use a high-speed disperser to stir, slowly add 60 parts by weight of A component to 28 parts by weight of B component, and then continue to add 12 parts by weight of C component to obtain a flexible geopolymer-based anti-corrosion coating.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention belongs to the technical field of anticorrosive paint and discloses flexible geopolymer-based anticorrosive paint and a preparation method and application thereof. The flexible geopolymer-based anticorrosive paint comprises a component A, a component B and a component C. The component A is prepared from, by weight, 15-80 parts of a geopolymer gel base material and 20-85 parts of pigments and fillers. The component B is prepared from, by weight, 40-85 parts of an alkali activator, 0-15 parts of a curing regulator, 0-6 parts of a rheological modifier and 7-45 parts of water. The component C refers to a functional toughening additive. The lexible geopolymer-based anticorrosive paint has advantages that defects of high brittleness and proneness to cracking failure of traditionalpolymer paint are overcome, and excellent flexibility of a material is achieved; in addition, the paint contains zero VOC and is low in toxicity and environmentally friendly, a coating is compact andstable, excellent corrosion resistance, permeation resistance and durability are achieved, and the flexible geopolymer-based anticorrosive paint is applicable to steel structure and concrete surface protection of infrastructures of cultural relics, buildings, municipal administration, roads, subways and the like.

Description

technical field [0001] The invention belongs to the field of inorganic anticorrosion coatings, in particular to a flexible geopolymer-based anticorrosion coating and its preparation method and application. Background technique [0002] Geopolymer is a new type of water-based inorganic gel material produced by the reaction of solid aluminosilicate and high-concentration alkali solution. As an inorganic material, geopolymers have a unique polymer-like bonded structure. The difference is that polymer materials are connected to each other by C-C bonds, while geopolymers are connected to each other by Si-O bonds or Al-O bonds to form a tetrahedral structure. Therefore, geopolymer has the advantages of both inorganic materials and polymer materials. It has a dense molecular structure and good corrosion resistance; it has high mechanical strength, good heat resistance, and has excellent compatibility with concrete, stone, ceramics and other substrates. Excellent bonding ability; ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C09D1/00C09D1/08C09D5/08C09D7/61C09D7/63C09D7/20C09D7/65
CPCC09D1/00C09D1/08C09D5/08C09D7/20C09D7/61C09D7/63C09D7/65C09D7/70C04B28/006C04B2111/00482C04B2111/26Y02P40/10
Inventor 张广照张国梁马春风陈玉娴
Owner SOUTH CHINA UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products