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Anti-adhesive flame-retardant waterproof membrane and preparation method thereof

A waterproof membrane, flame-retardant technology, applied in the direction of adhesive types, adhesives, fire-resistant coatings, etc., can solve the problems of aggravated fire, continuous burning, and easy fire of the adhesive layer, so as to improve waterproof performance and strengthen bonding The effect of improving compatibility

Active Publication Date: 2021-11-02
HUIZHOU NENGHUI CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003]In order to solve the above problems, people try to achieve flame retardant through flame retardant modification of the polymer substrate layer, but only the flame retardant modification of the Burning effect is not ideal
This is because a large amount of softening oil is added to the viscose layer, which is a flammable building material. When a fire occurs accidentally during storage, transportation and construction, the viscose layer is very easy to catch fire and continues to burn, generating a lot of heat, which will instead Ignite the flame-retardant modified polymer substrate layer, and the viscose burning droplets are easy to ignite the combustibles below, further aggravating the fire
[0004] Moreover, the existing adhesive layer cannot penetrate into the cement mortar, and the bonding with the concrete is not tight enough. When the waterproof membrane is damaged or pierced by foreign objects, water easily enters between the adhesive layer and the concrete, so that The problem of water channeling after partial water leakage of the waterproof membrane leads to complete failure of waterproofing

Method used

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  • Anti-adhesive flame-retardant waterproof membrane and preparation method thereof
  • Anti-adhesive flame-retardant waterproof membrane and preparation method thereof
  • Anti-adhesive flame-retardant waterproof membrane and preparation method thereof

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Experimental program
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Effect test

Embodiment approach

[0035] In order to better describe the above-mentioned anti-adhesive flame-retardant waterproof membrane and its preparation method, so as to better understand the concept of the above-mentioned anti-adhesive flame-retardant waterproof membrane and its preparation method. For an implementation, see figure 2, a non-adhesive flame-retardant waterproof roll material, including a flame-retardant polymer substrate layer 110, a flame-retardant pressure-sensitive adhesive layer 120, and a flame-retardant anti-stick coating 130 that are sequentially stacked; wherein, the flame-retardant pressure-sensitive The adhesive layer includes the following components by mass: 15-45 parts of styrene thermoplastic elastomer, 30-60 parts of tackifier, 20-40 parts of softener, 20-50 parts of flame retardant, 0.3-50 parts of antioxidant 0.6 parts and 0.3-1.2 parts of coupling agent; the flame-retardant anti-stick coating includes the following components in parts by mass: 30-60 parts of acrylic emu...

Embodiment 1

[0063] S111, providing a flame-retardant polymer substrate layer, where the flame-retardant polymer substrate layer is a flame-retardant modified thermoplastic polyolefin;

[0064] S121, at a vacuum degree of -0.05Mpa and a temperature of 160°C, for 8kg styrene-isoprene block copolymer, 4kg styrene-butadiene block copolymer, 3kg styrene-butadiene Hydrogenated block copolymer of alkene, 16kg hydrogenated petroleum resin, 8kg rosin pentaerythritol ester, 6kg terpene phenol resin, 11kg naphthenic oil, 9kg nitrile rubber liquid, 0.3kg three [2.4-di-tert-butylphenyl] Phosphate ester and 0.3kg gamma-aminopropyltriethoxysilane were stirred until completely melted, then added 10kg ammonium polyphosphate, 4kg melamine uric acid ester, 4kg bromotriazine and 3kg zinc borate and continued to stir until completely melted to obtain resistance burning pressure sensitive adhesive;

[0065] S131, stir 30kg of acrylic emulsion at a speed of 450rpm for 3min, then add 0.1kg of hexenyl bisstearam...

Embodiment 2

[0068] S112, providing a flame-retardant polymer substrate layer, where the flame-retardant polymer substrate layer is a flame-retardant modified thermoplastic polyolefin;

[0069] S122, at a vacuum degree of -0.1Mpa and a temperature of 180°C, for 25kg styrene-isoprene block copolymer, 12kg styrene-butadiene block copolymer, 8kg styrene-butadiene Hydrogenated block copolymer of alkene, 32kg hydrogenated petroleum resin, 10kg rosin pentaerythritol ester, 8kg terpene phenol resin, 22kg naphthenic oil, 18kg nitrile rubber liquid, 0.6kg three [2.4-di-tert-butylphenyl] Phosphate ester and 1.2kg gamma-aminopropyltriethoxysilane were stirred until completely melted, then added 30kg ammonium polyphosphate, 12kg melamine uric acid ester, 8kg bromotriazine and 3kg zinc borate and continued to stir until completely melted to obtain resistance burning pressure sensitive adhesive;

[0070] S132, stir 60kg acrylic emulsion at a speed of 550rpm for 8min, then add 1kg hexenyl bisstearamide,...

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Abstract

The present invention relates to the field of waterproof coiled material, which is an anti-adhesive and flame-retardant waterproof coiled material, which comprises a flame-retardant polymer substrate layer, a flame-retardant pressure-sensitive adhesive layer and a flame-retardant and anti-adhesive coating which are sequentially stacked; wherein, the flame-retardant The pressure-sensitive adhesive layer includes the following components by mass: 15-45 parts of styrene thermoplastic elastomer, 30-60 parts of tackifier, 20-40 parts of softener, 20-50 parts of flame retardant, antioxidant 0.3-0.6 parts and 0.3-1.2 parts of coupling agent; the flame-retardant anti-stick coating includes the following components by mass: 30-60 parts of acrylic emulsion, 30-50 parts of flame-retardant powder, 0.1-1 part of dispersant, 0.3-1 part of defoaming agent, 0.2-2 parts of coupling auxiliary agent, 4-8 parts of film-forming auxiliary agent and 2-8 parts of silicon dioxide. This anti-adhesive and flame-retardant waterproof membrane has flame-retardant modification on the polymer substrate layer and the adhesive layer to achieve the overall flame-retardant design, and adds a flame-retardant and anti-adhesive coating. The synergistic effect of these two different flame retardant systems of powder makes the waterproof membrane have excellent flame retardant function.

Description

technical field [0001] The invention relates to the field of waterproof coiled materials, in particular to an anti-adhesive and flame-retardant waterproof coiled material and a preparation method thereof. Background technique [0002] Waterproof membranes currently on the market are generally formed by coating an adhesive layer on a polymer substrate layer. As a material with high molecular polymer as the main body, it must have the disadvantage of being extremely flammable. Moreover, high molecular polymers produced with oil and natural gas as basic raw materials can produce gas, smoke and dust particles in case of accidental fire during storage, transportation and construction, which can damage the respiratory system in the slightest and be fatal in severe cases. [0003] In order to solve the above problems, people try to achieve flame retardancy by flame-retardant modification of the polymer substrate layer, but the flame-retardant effect is not satisfactory only by fla...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/24C09J7/38C09J157/02C09J153/02C09J191/00C09J193/04C09J109/02C09J11/04C09J11/06C09D133/04C09D7/61C09D7/63C09D7/65E02D31/02E04B1/66
CPCC08K2003/2227C08K2003/323C08K2003/387C08L2201/02C08L2205/025C08L2205/035C09D5/18C09D133/04C09J11/04C09J11/06C09J157/02C09J2423/006C09D7/61C09D7/63C09D7/65C09J7/24C09J7/38E02D31/025E04B1/665C08L53/02C08L53/025C08L93/04C08L91/00C08K13/02C08K5/526C08K5/544C08K3/32C08L83/04C08K5/5425C08K3/22C08K3/38
Inventor 梁鼎贤江强吴兆辉林金鸿杨学根
Owner HUIZHOU NENGHUI CHEM CO LTD