Biopolymer fiber and processing technology thereof

A technology of biomass fiber and processing technology, which is applied in the direction of cellulose/protein conjugated artificial filament, conjugated synthetic polymer artificial filament, heat treatment of artificial filament, etc., which can solve the problem of high brittleness of biomass fiber and the limitation of industrialization Application, minimum demand gap and other issues, to achieve the effect of increasing intermolecular pores, promoting sustainable development, and accelerating thermal movement

Inactive Publication Date: 2019-10-18
裴广华
View PDF8 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, almost all research results show that the single fiber length of these new fibers is even less than 1cm, which is far from the minimum requirement of traditional spinning for fiber length.
Currently commonly used biomass fibers have high brittleness, poor mechanical properties, and poor hygroscopicity, which limit industrial applications.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Biopolymer fiber and processing technology thereof
  • Biopolymer fiber and processing technology thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A kind of biomass fiber, the biomass fiber is prepared by blending melt spinning of biomass polyester chips and cellulose nanocrystals, the weight ratio of biomass polyester chips and cellulose nanocrystals is 8:1; Substance Polyester chips are prepared from the following raw materials in parts by weight: 20 parts of bio-based succinic acid, 20 parts of bio-based mixed polyols, 20 parts of sodium 1,4-dihydroxybutane-2-sulfonate and 0.001 parts of nickel catalyst cellulose nanocrystals are prepared from the following raw materials in parts by weight: 10 parts of microcrystalline cellulose and 1 part of concentrated sulfuric acid; bio-based mixed polyols are ethylene glycol, 1,2-propylene glycol, 1,2-butane A mixture of diol, pentylene glycol and sorbitol, the weight ratio of ethylene glycol, 1,2-propanediol, 1,2-butanediol, pentylene glycol and sorbitol is 100:0.5:0.2:0.1:0.1.

[0036] Adopt above-mentioned raw material to process a kind of biomass fiber, the processing ...

Embodiment 2

[0042] A kind of biomass fiber, this biomass fiber is prepared by blending melt spinning by biomass polyester chip and cellulose nanocrystal, the weight ratio of biomass polyester chip and cellulose nanocrystal is 8.5:1; Substance Polyester chips are prepared from the following raw materials in parts by weight: 22 parts of bio-based succinic acid, 25 parts of bio-based mixed polyols, 22 parts of sodium 1,4-dihydroxybutane-2-sulfonate and 0.0015 parts of iron catalyst cellulose nanocrystals are prepared from the following raw materials in parts by weight: 12 parts of microcrystalline cellulose and 1.2 parts of concentrated sulfuric acid; bio-based mixed polyols are ethylene glycol, 1,2-propylene glycol, 1,2-butane A mixture of diol, pentylene glycol and sorbitol, the weight ratio of ethylene glycol, 1,2-propanediol, 1,2-butanediol, pentylene glycol and sorbitol is 100:1:0.6:0.2:0.2.

[0043] Adopt above-mentioned raw material to process a kind of biomass fiber, the processing t...

Embodiment 3

[0049] A kind of biomass fiber, the biomass fiber is prepared by blending melt spinning of biomass polyester chips and cellulose nanocrystals, the weight ratio of biomass polyester chips and cellulose nanocrystals is 9:1; Substance Polyester chips are prepared from the following raw materials in parts by weight: 25 parts of bio-based succinic acid, 30 parts of bio-based mixed polyols, 25 parts of sodium 1,4-dihydroxybutane-2-sulfonate and 0.01 parts of manganese catalyst cellulose nanocrystals are prepared from the following raw materials in parts by weight: 15 parts of microcrystalline cellulose and 1.5 parts of concentrated sulfuric acid; bio-based mixed polyols are ethylene glycol, 1,2-propylene glycol, 1,2-butane A mixture of diol, pentylene glycol and sorbitol, the weight ratio of ethylene glycol, 1,2-propanediol, 1,2-butanediol, pentylene glycol and sorbitol is 100:3:1:2:0.5.

[0050] Adopt above-mentioned raw material to process a kind of biomass fiber, the processing t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
elongation at breakaaaaaaaaaa
elongation at breakaaaaaaaaaa
Login to view more

Abstract

The invention discloses a biopolymer fiber and a processing technology thereof. The biopolymer fiber is prepared from biopolymer polyester chips and cellulose nanocrystals by blend melt spinning. Interaction of biopolymer polyester chip molecules is enhanced by association hydrogen bonds formed among the cellulose nanocrystals and the biopolymer polyester chips, connecting bridges among biopolymerpolyester chip macromolecules are formed, relative slip of biopolymer polyester chip macromolecular chains is inhibited, so that the breaking strength of the biopolymer fiber is improved. As bio-based mixed polyols contain a large quantity of hydroxide radicals, hydrophilic groups are introduced into the prepared biopolymer polyester chip macromolecular chains, the hydrophilic performance of thebiopolymer polyester chips is improved, and hygroscopicity of the biopolymer fiber is improved. Experimental results indicate that the prepared biopolymer fiber has higher breaking strength, good toughness and mechanical performance and excellent hygroscopicity.

Description

technical field [0001] The invention relates to the technical field of biomass fibers, in particular to a biomass fiber and a processing technology thereof. Background technique [0002] China is the largest producer of chemical fiber in the world. The development of chemical fiber has been strong in recent years. However, more than 90% of the growth of the chemical fiber industry depends on limited and non-renewable petroleum resources. The raw material for synthetic chemical fiber polyester chips is ethylene glycol. Alcohol and ethylene glycol are basically derived from petroleum industry products, while petroleum resources are decreasing day by day, the contradiction between oil supply and demand is increasing day by day, and the war for oil is intensifying. The whole world is working hard to research and explore the inexhaustible biological resources on the earth. Using renewable biomass resources to develop bio-based chemical industry and replace petrochemical products...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/02D01F8/14C08G63/688C08G63/82C08G63/83D01D5/08D01D5/12D01D10/02
CPCC08G63/6886C08G63/826C08G63/83D01D5/08D01D5/12D01D10/02D01F8/02D01F8/14
Inventor 裴广华
Owner 裴广华
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap