Self-healing photoresponsive supramolecular fluorescent hydrogel and preparation method and application thereof

A supramolecular, light-responsive technology, applied in the field of supramolecular chemistry, can solve the problems of not meeting the needs of the society, less light-responsive fluorescent hydrogels, etc., achieving low production cost, good self-healing, and excellent self-healing performance. Effect

Active Publication Date: 2019-10-25
XI'AN PETROLEUM UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are very few studies and analyzes on light-responsive fluorescent hydrogels in the current conventional technical solutions. In addition, the research on self-healing gel materials is far from meeting the needs of society.

Method used

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  • Self-healing photoresponsive supramolecular fluorescent hydrogel and preparation method and application thereof
  • Self-healing photoresponsive supramolecular fluorescent hydrogel and preparation method and application thereof
  • Self-healing photoresponsive supramolecular fluorescent hydrogel and preparation method and application thereof

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Effect test

preparation example Construction

[0048] A preparation method of self-healing photoresponsive supramolecular fluorescent hydrogel, comprising the following steps:

[0049] (A) Preparation of Polymer 1: Dissolve β-cyclodextrin monomer, tetraphenylethylene monomer, and acrylic acid in dimethyl sulfoxide, stir the resulting mixture for the first time, bubble and add azobisisobutyronitrile , rapid cooling and quenching after secondary stirring, the obtained polymer solution was dropped into diethyl ether, the precipitated solid was collected by repeated filtration, and the obtained solid was dried to obtain polymer 1;

[0050] (B) Preparation of Polymer 2: Dissolve azo compound monomer, tetraphenylethylene monomer, and acrylic acid in benzene, stir and bubble the resulting mixture for the first time and add azobisisobutyronitrile, and speed up after the second stirring. Cooling quenched, the resulting polymer solution was dropped into diethyl ether, the precipitated solid was collected by filtration several times,...

Embodiment 1

[0058] Preparation of Polymer 1:

[0059] Polymer 1 was prepared by radical polymerization from β-cyclodextrin 4, tetraphenylethylene 5 and acrylic acid. Specific operation: β-cyclodextrin monomer 4, tetraphenylethylene monomer 5 and acrylic acid were dissolved in dimethyl sulfoxide (DMSO), and the resulting mixture was stirred at room temperature and bubbled with argon (Ar) for 30 minute. Azobisisobutyronitrile was added in one portion and the mixture was stirred at 70°C for 24 hours, then the polymerization was quenched by liquid nitrogen snap freezing. The resulting mixed solution was dropped into ether, and the precipitated solid was collected by vacuum filtration. After repeated filtration three times, the collected polymer was vacuum-dried to obtain a total of 12.47 g of polymer 1 with a yield of 55.4%. The structure of polymer 1 is shown in the following formula:

[0060]

[0061] polymer 1 about 1 The data of H-NMR, Mn, Mw, and PDI are shown in the following tab...

Embodiment 2

[0064] Preparation of Polymer 2:

[0065] Polymer 2 was prepared from azo compound 6, tetraphenylethylene 5 and acrylic acid by radical polymerization. Azo compound monomer 6, tetraphenylethylene monomer 5 and styrene were dissolved in benzene, and the resulting mixture was stirred at room temperature and bubbled with argon (Ar) for 30 minutes. Azobisisobutyronitrile was added in one portion and the mixture was stirred at 70°C for 24 hours, then the polymerization reaction was quenched by liquid nitrogen flash freezing. The resulting mixture was dropped into diethyl ether and the precipitated solid was collected by vacuum filtration. After repeated filtration three times, the collected polymer was vacuum-dried to obtain a total of 22.05 g of polymer 2 with a yield of 58.1%. The structure of polymer 2 is shown in the following formula:

[0066]

[0067] polymer 2 about 1 The data of H-NMR, Mn, Mw, and PDI are shown in the following table:

[0068]

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Abstract

The invention belongs to the technical field of supramolecular chemistry, and particularly relates to a self-healing photoresponsive supramolecular fluorescent hydrogel and a preparation method and application thereof. The self-healing photoresponsive supramolecular fluorescent hydrogel and the preparation method and application thereof adopt the recognition advantage of the beta-cyclodextrin fora specific group of an azo object to obtain a supramolecular hydrogel material which is stable at room temperature by simple solution mixing, the supramolecular hydrogel material has good self-healingproperty, viscoelasticity, fluorescence and light responsiveness, the preparation method is simple, operation is carried out at normal temperature, the production cost is low, no secondary pollutionis generated, fluorescence changing is carried out under different illumination while accompanied by gel-sol conversion, and promotion value and broad application prospects in the files such as drug delivery, biological imaging and biological probes are great.

Description

technical field [0001] The invention belongs to the technical field of supramolecular chemistry, and in particular relates to a self-healing light-responsive supramolecular fluorescent hydrogel and its preparation method and application. Background technique [0002] Supramolecules usually refer to the combination of two or more molecules relying on intermolecular interactions to form complex and organized aggregates, and maintain a certain integrity so that they have definite microstructure and macroscopic properties. The concept and terminology of supramolecular chemistry was proposed in 1973, and people gradually realized that there is a field of molecular chemistry based on covalent bonds, and there is a field of supramolecular chemistry based on molecular assemblies and intermolecular bonds. [0003] Supramolecular chemistry is the chemistry of molecular aggregates based on intermolecular non-covalent interactions. In other words, the interaction between molecules is th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J3/075C08L5/16C08L33/02C08F220/06C08F212/32A61K49/00A61K41/00A61K9/06A61K47/40A61K47/32C09K11/06
CPCC08J3/075C08F220/06A61K49/0073A61K41/0042A61K9/06A61K47/40A61K47/32C09K11/06C08J2305/16C08J2433/02C08F212/32
Inventor 韩薇薇薛丹吴亚姬悦王嗣昌
Owner XI'AN PETROLEUM UNIVERSITY
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