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Anti-corrosion protective coating on metal substrate surface and its preparation method and application

A technology of protective coating and metal substrate, which is applied in the direction of metal material coating process, coating, vacuum evaporation plating, etc., and can solve the problems of rough surface, increased manufacturing cost, and large coating thickness

Active Publication Date: 2021-04-20
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above-mentioned surface coating can significantly improve the anti-corrosion and wear-resisting performance of seawater pump parts, the preparation process often experiences high temperature, which easily reduces the mechanical properties of the parts. At the same time, the prepared coating is thick and has a rough surface, which requires high assembly precision. Parts with small matching clearance need to reserve processing amount or carry out post-polishing, which greatly increases the manufacturing cost

Method used

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  • Anti-corrosion protective coating on metal substrate surface and its preparation method and application
  • Anti-corrosion protective coating on metal substrate surface and its preparation method and application
  • Anti-corrosion protective coating on metal substrate surface and its preparation method and application

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preparation example Construction

[0035] An aspect of the embodiments of the present invention also provides the preparation method of the aforementioned anti-wear protective coating, which includes:

[0036] S1. Pretreating the surface of the metal substrate;

[0037] S2. Using DC magnetron sputtering technology to sequentially deposit Ti transition layer and TiC on the surface of the metal substrate x Gradient layer, and then using linear ion source technology in TiC x Depositing the first DLC layer on the surface of the gradient layer;

[0038] S3. Using DC magnetron sputtering technology to deposit TiC on the surface of the first DLC layer x / Ti / TiC x sandwich layer, and a second DLC layer was deposited using linear ion source technology, and the TiC x / Ti / TiC x The sandwich layer and the second DLC layer are stacked alternately to form TiC x / Ti / TiC x / DLC alternate layers;

[0039] S4. Using linear ion source technology on TiC x / Ti / TiC x A third DLC layer is deposited on the alternating layers...

Embodiment 1

[0054] In this embodiment, the base material is AISI 316L austenitic stainless steel, and the structure of the coating is as follows figure 1 As shown, the total thickness of the coating is 1.6 μm.

[0055] The coating preparation steps on the above-mentioned 316L surface are as follows:

[0056] Step 1: Use 120#~3000# SiC metallographic sandpaper to polish the 316L substrate in sequence, and then use Al with a particle size of 0.2~0.3μm 2 o 3 The abrasive paste is used for metallographic polishing of the stainless steel substrate for 15 minutes;

[0057] Step 2: Place the polished 316L stainless steel substrate in acetone, ethanol and deionized water in sequence for ultrasonic cleaning for 10 minutes, and then dry it with cold air for later use;

[0058] Step 3: Place the 316L stainless steel substrate in the thin film deposition vacuum chamber, and use mechanical pump and turbomolecular pump to evacuate to 2.0×10 -5 After Torr, turn on the heater and set the heating temp...

Embodiment 2

[0066] In this example, the base material is UNS S32750 (SAF 2507) super duplex stainless steel, and the coating is TiC x / Ti / TiC x Layers and DLC layers are periodically stacked alternately in a multilayer structure, in which the surface of S32750 is a Ti transition layer, and the total thickness of the coating is 2.3 μm.

[0067] The coating preparation steps on the surface of the above S32750 are as follows:

[0068] Step 1: Use 120#~3000# SiC metallographic sandpaper to polish the S32750 substrate in turn, and then use Al with a particle size of 0.2~0.3μm 2 o 3 The abrasive paste is used for metallographic polishing of the substrate for 12 minutes;

[0069] Step 2: Place the polished S32750 substrate in acetone, ethanol and deionized water in sequence for ultrasonic cleaning for 10 minutes, and then dry it with cold air for later use;

[0070] Step 3: Place the S32750 substrate in the film deposition vacuum chamber, and successively use a mechanical pump and a turbomol...

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Abstract

The invention discloses an anti-corrosion protective coating on the surface of a metal substrate, a preparation method and application thereof. The coating includes a Ti transition layer, a TiC x Gradient layer, first DLC layer, TiC x / Ti / TiC x / DLC alternately stacked layer and top layer, the TiC x / Ti / TiC x / DLC Alternate Layer Laminated by TiC x / Ti / TiC x A sandwich layer and a second DLC layer are alternately laminated, the TiC x / Ti / TiC x The sandwich layer consists of two TiC x layer and are provided on the two TiC x A Ti layer between layers, the top layer includes a third DLC layer, the TiC x The value range of X is 0.8-1.3. The anti-corrosion protective coating provided by the invention adopts the structure of "alternating multi-layer + interface gradient + top layer extension", so that the coating has good comprehensive mechanical properties, and has excellent corrosion resistance and abrasion resistance. At the same time, the anti-wear protective coating can still maintain a good friction-reducing and lubricating effect within a certain period of time after being worn through, showing high wear-resistant failure tolerance.

Description

technical field [0001] The invention belongs to the technical field of surface treatment of mechanical parts, in particular relates to an anti-abrasion protective coating on the surface of a metal substrate and its preparation method and application, in particular to a seawater pump impeller and friction pair parts with long service life and high damage tolerance on the surface Erosion resistant protective coating and its preparation method and application. Background technique [0002] my country's exploration, development and utilization of marine resources are increasingly strengthened. As a new technology emerging to adapt to marine development, seawater hydraulic transmission technology with seawater as the working fluid has been gradually applied to the sea due to its high safety, small compression coefficient, low use and maintenance costs, green and pollution-free, and many other advantages. Salvage and salvage, marine resources survey, offshore oil and gas exploita...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/35C23C14/16C23C14/06C23C14/18C23C14/32
CPCC23C14/0057C23C14/0084C23C14/0605C23C14/0635C23C14/165C23C14/185C23C14/32C23C14/35
Inventor 汪爱英刘林林孙丽丽郭鹏李昊
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI