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A kind of preparation method of whitening foaming agent

A technology of foaming agent and stabilizer, which is applied in the preparation of whitening foaming agent, whitening foaming agent for polyvinyl chloride and its preparation field, which can solve the problem of unstable production quality of downstream product manufacturers and increase the amount of stabilizer , the decline in mechanical properties of the product, etc., to avoid insufficient gas generation, avoid severe corrosion, and improve grinding efficiency

Active Publication Date: 2022-03-15
浙江杰上杰新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Polyvinyl chloride is a chain-like high polymer formed by the homopolymerization of vinyl chloride monomers. Its decomposition temperature is lower than its glass transition temperature, and it is prone to dehydrochlorination and decomposition, which will cause discoloration of the product, affect the processing performance of polyvinyl chloride and cause mechanical damage to the product. Performance drop
The introduction of ultra-fine high-residue inorganic foaming agent sodium bicarbonate increases the strength of the melt, the fluidity of the melt becomes poor, and the heat generated by internal friction increases. Insulation performance and mechanical properties cause great adverse effects; the introduction of exothermic AC foaming agent (azodicarbonamide) leads to local overheating of PVC melt and scorching and yellowing
[0004] The above problems are prominent in the existing conventional foaming agents, resulting in extremely unstable production quality of downstream product manufacturers, so they have to increase the amount of stabilizers and often shut down for debugging

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] A preparation method of whitening foaming agent, comprising the following steps:

[0053] S1, the preparation of semi-finished product A:

[0054] S11. Put the sodium bicarbonate and the composite calcium-zinc stabilizer into a high-speed mixer and stir evenly, and the mixing temperature does not exceed 80°C;

[0055] S12, sending the mixed material in step S11 into a jet mill, and performing jet milling to obtain modified ultrafine sodium bicarbonate, i.e. semi-finished product A;

[0056] S2, the preparation of semi-finished product B:

[0057] S21. After uniformly mixing the citrate and citric acid, send them into a jet mill for jet milling to obtain a powder with a median particle size of 5-25um;

[0058] S22, adding the powder obtained in step S21 into a high mixer, dissolving fatty acid and its derivatives with a low-boiling point organic solvent to obtain a solution of fatty acid and its derivatives; then spraying the solution of fatty acids and its derivatives...

Embodiment 2

[0078] A preparation method of whitening foaming agent, comprising the following steps:

[0079] S1, the preparation of semi-finished product A:

[0080] S11. Put the sodium bicarbonate and the composite calcium-zinc stabilizer into a high-speed mixer and stir evenly, and the mixing temperature does not exceed 80°C;

[0081] S12, sending the mixed material in step S11 into a jet mill, and performing jet milling to obtain modified ultrafine sodium bicarbonate, i.e. semi-finished product A;

[0082] S2, the preparation of semi-finished product B:

[0083] S21, after citrate and citric acid are mixed uniformly, send into jet mill, carry out jet pulverization, obtain the powder body that median particle size is 25um;

[0084] S22, adding the powder obtained in step S21 into a high mixer, dissolving fatty acid and its derivatives with a low-boiling point organic solvent to obtain a solution of fatty acid and its derivatives; then spraying the solution of fatty acids and its deriv...

Embodiment 3

[0104] A preparation method of whitening foaming agent, comprising the following steps:

[0105] S1, the preparation of semi-finished product A:

[0106] S11. Put the sodium bicarbonate and the composite calcium-zinc stabilizer into a high-speed mixer and stir evenly, and the mixing temperature does not exceed 80°C;

[0107] S12, sending the mixed material in step S11 into a jet mill, and performing jet milling to obtain modified ultrafine sodium bicarbonate, i.e. semi-finished product A;

[0108] S2, the preparation of semi-finished product B:

[0109] S21, after citrate and citric acid are mixed uniformly, send into jet mill, carry out jet pulverization, obtain the powder body that median particle diameter is 5um;

[0110] S22, adding the powder obtained in step S21 into a high mixer, dissolving fatty acid and its derivatives with a low-boiling point organic solvent to obtain a solution of fatty acid and its derivatives; then spraying the solution of fatty acids and its de...

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PUM

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Abstract

The invention discloses a preparation method of a whitening foaming agent, comprising the following steps: S11, stirring and mixing sodium bicarbonate and a composite calcium-zinc stabilizer evenly; S12, performing jet crushing to obtain a semi-finished product A; S21, mixing citric acid After the salt and citric acid are mixed evenly, airflow milling is carried out; S22, the coating of the fatty acid and its derivatives on the citrate and citric acid is completed, and the semi-finished product B is obtained; S3, the preparation of the whitening foaming agent: the semi-finished product A Mix with the semi-finished product B, then add an appropriate amount of urea and its derivatives and epoxy compounds to obtain the whitening foaming agent; the mass ratio of the sodium bicarbonate to the composite calcium-zinc stabilizer is 100: (1-5) . The whitening foaming agent prepared by the preparation method of the whitening foaming agent of the present invention has an excellent foaming effect on polyvinyl chloride, moderate foaming rate, less heat in the foaming process, and can significantly improve the foaming effect of polyvinyl chloride. Whiteness, surface gloss, cell fineness, etc. of foam products.

Description

technical field [0001] The invention relates to the field of foaming agents, in particular to a preparation method of a whitening foaming agent, more particularly to a whitening foaming agent for polyvinyl chloride and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC for short) is one of the five general-purpose plastics in the world, among which rigid polyvinyl chloride foam has the characteristics of low density, geothermal conductivity, high chemical stability, and high energy absorption, and is widely used as heat insulation , Noise-reducing and shock-absorbing materials, especially suitable for the production and processing of bathroom cabinet boards, special boards for building templates, special boards for automobiles and ships, special boards for advertising engraving, and special boards for chemical anticorrosion. [0003] Polyvinyl chloride is a chain-like high polymer formed by the homopolymerization of vinyl chloride monomers. I...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/08C08L27/06C08K13/04C08K5/09C08K5/098C08K5/1515C08K3/26C08K7/26C08K5/21
CPCC08J9/08C08J9/0095C08J9/0023C08J9/0028C08J9/0066C08J2203/02C08J2327/06
Inventor 罗李华
Owner 浙江杰上杰新材料股份有限公司
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