Hyperbranched conjugated polyelectrolyte based on tripolyindole and preparation method and use thereof

A technology of conjugated polyelectrolyte and tripolybenzazole, which is applied in the direction of circuits, photovoltaic power generation, electrical components, etc., can solve the problems of low device efficiency, poor film formation, difficult orthogonal solvent solution processing and preparation, etc., and achieve good transparency The effect of light efficiency and good thermal stability
CN110698654AActive Publication Date: 2020-01-17CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI
Publication Date
2020-01-17

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Abstract

The invention belongs to the field of organic semiconductor photoelectric materials, in particular to a hyperbranched conjugated polyelectrolyte based on tripolyindole and a preparation method and anapplication thereof. The invention solves the technical problems in the prior art that the hole transport material based on tripolyindole and its derivatives has poor film forming property, it is difficult to prepare devices by using orthogonal solvent method solution, and the prepared devices have low efficiency. The hyperbranched conjugated polyelectrolyte material based on tripolyindole provided by the invention is neutral in pH and does not corrode corresponding electrodes and organic materials; the hole transport layer of the organic photoelectric device can be prepared by orthogonal solvent method solution processing. It has the advantages of good light transmittance in visible light region and good thermal stability. The hyperbranched conjugated polyelectrolyte based on tripolyindole prepared by the invention is used as a hole transport layer to prepare the organic photovoltaic device or the organic electroluminescent device, and the organic photovoltaic device or the organic electroluminescent device has higher efficiency.
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Description

technical field

[0001] The invention belongs to the field of organic semiconductor optoelectronic materials, and in particular relates to a trimerindole-based hyperbranched conjugated polyelectrolyte and its preparation method and application. Background technique

[0002] Organic semiconductor materials have attracted extensive attention due to their advantages of light weight, low cost, flexibility, and large-area devices that can be prepared by solution processing, and have great application prospects. In the past ten years, as two important applications of organic semiconductor optoelectronic materials, organic light-emitting diodes (OLEDs) and organic solar cells (OPVs) have achieved important development. In these two types of devices, the interfacial layer plays an important role in improving the device performance. The interfacial layer includes a hole-transport layer and an electron-transport layer, which facilitate the ohmic contact between the corresponding elect...

Claims

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