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A kind of high temperature porcelain and its preparation method

A technology of high-temperature porcelain and kaolin, which is applied in the field of ceramic materials, can solve problems such as poor high-temperature deformation resistance, poor mechanical strength, formula improvement and design difficulties, and achieve the effects of improving mechanical strength, thermal stability and mechanical strength

Active Publication Date: 2022-06-28
上海信传信息技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, compared with low-temperature porcelain, the formula design of high-temperature porcelain is more difficult. High-temperature porcelain needs to be fired under high-temperature conditions, and uncontrollable changes in grain boundaries and microstructures will occur, which will affect material properties; There is no mature mechanism for the relationship between performance change and ceramic chemical composition, and there is not a simple one-to-one correspondence between its performance and materials or additives. For example, adding a reinforcing agent to improve strength often affects the thermal stability of the material And the apparent light transmittance of the material, the introduction of additives to improve the light transmittance will easily affect the mechanical properties of the material, etc., and the interaction between components has no mature rules, and it is difficult to balance and reconcile different properties, resulting in the formulation of It is very difficult to improve and design
At present, high-temperature porcelain on the market generally has defects such as poor high-temperature deformation resistance, poor mechanical strength, and poor appearance quality, which affect the application of high-temperature porcelain

Method used

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  • A kind of high temperature porcelain and its preparation method
  • A kind of high temperature porcelain and its preparation method
  • A kind of high temperature porcelain and its preparation method

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preparation example Construction

[0058] The present invention also provides a preparation method of the high-temperature porcelain described in the above technical scheme, comprising the following steps:

[0059] a) mixing the material with water and ball-milling to obtain a slurry;

[0060] The materials include potassium feldspar, quartz, plasticizer, activated alumina, kaolin washed mud and dolomite;

[0061] b) refining and molding the mud to obtain a green body;

[0062] c) firing the china to obtain high temperature porcelain.

[0063] According to the present invention, the material is first mixed with water and ball-milled to obtain a slurry.

[0064] Among them, the materials include potassium feldspar, quartz, plasticizer, activated alumina, kaolin washing mud and dolomite; the types and dosages of each material are consistent with those described in the above technical solutions, and will not be repeated here. Repeat.

[0065] In the present invention, the mass ratio of the material to water is...

Embodiment 1

[0077] (1) Raw material formula:

[0078] Potassium feldspar 20%, quartz 20%, plasticizer 5%, activated alumina 4%, kaolin washing mud 50.8%, dolomite 0.2%.

[0079] (2) Preparation:

[0080] S1, mixing, ball milling:

[0081] The raw materials are poured into the ball mill tank according to the above proportion, and water is added in the ratio of material: water ratio = 1: 0.8; high alumina ball stone is used as the ball milling medium, and added according to the gradation of large: medium: small = 1: 2: 1 , the volume of the added ball stone is 1 / 3 of the volume of the ball mill.

[0082] The ball mill was carried out with a 10Kg ball mill jar, the raw material loading was 6Kg, the ball milling speed was 61r / min, and the time was 18h.

[0083] After the ball milling is completed, the slurry is discharged, sieved (220 mesh national standard steel screen), and iron is removed.

[0084] S2, mud training, molding:

[0085] The mud is squeezed into mud cakes through a mud pr...

Embodiment 2

[0095] (1) Raw material formula:

[0096] Potassium feldspar 21%, quartz 20%, plasticizer 7%, activated alumina 5%, kaolin washing mud 46.5%, dolomite 0.5%.

[0097] (2) Preparation:

[0098] S1, mixing, ball milling:

[0099] The raw materials are poured into the ball mill tank according to the above proportion, and water is added in the ratio of material: water ratio = 1: 0.8; high alumina ball stone is used as the ball milling medium, and added according to the gradation of large: medium: small = 1: 2: 1 , the volume of the added ball stone is 1 / 3 of the volume of the ball mill.

[0100] The ball mill was carried out with a 10Kg ball mill jar, the raw material loading was 6Kg, the ball milling speed was 61r / min, and the time was 18h.

[0101] After the ball milling is completed, the slurry is discharged, sieved (220 mesh national standard steel screen), and iron is removed.

[0102] S2, mud training, molding:

[0103] The mud is squeezed into mud cakes through a mud pr...

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Abstract

The invention provides a high-temperature porcelain and a preparation method thereof. The high-temperature porcelain provided by the invention is prepared from raw materials comprising the following mass ratio materials: 20% to 40% of potassium feldspar; 10% to 20% of quartz; 5% to 8% of plasticizer; 4% to 6% of activated alumina %; Kaolin washing mud 40% to 60%; dolomite powder 0.2% to 0.8%. The present invention introduces activated alumina and dolomite into the mud washing system of potassium feldspar, quartz and kaolin, and mixes the two in a specific ratio, and then cooperates with a plasticizer, which can promote the system to produce more mullite during the reaction process crystal, and the microcrystalline structure of activated alumina plays a whisker toughening role in the sintering reaction of the porcelain body, which can improve the thermal stability and mechanical strength of the porcelain; dolomite can accelerate the high-temperature sintering reaction and generate sufficient The liquid phase filling ensures sufficient glass phase without affecting the reaction between activated alumina and other components, and improves the transmittance of porcelain on the basis of ensuring thermal stability and mechanical strength.

Description

technical field [0001] The invention relates to the technical field of ceramic materials, in particular to a high-temperature ceramic and a preparation method thereof. Background technique [0002] High-temperature porcelain is a kind of special ceramics, which refers to ceramic materials whose melting temperature is above the melting point of silicon oxide (1728℃) and firing temperature is above 1200℃. Compared with low-temperature porcelain, high-temperature porcelain is fired at high temperature, with high crystal density, high ceramic surface strength, fine and white porcelain, and can be fired at high temperature again; it has the characteristics of high temperature resistance, high hardness, good electrical properties, etc. As a high temperature structural material, it is used in aerospace, machinery, chemical industry, metallurgy and other fields. [0003] However, compared with low-temperature porcelain, the formula design of high-temperature porcelain is more diffi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B33/13C04B33/04C04B33/16
CPCC04B33/131C04B33/04C04B33/16C04B2235/3472C04B2235/3217C04B2235/442C04B2235/3418C04B2235/3272C04B2235/3232C04B2235/3208C04B2235/3206C04B2235/3201C04B2235/9607C04B2235/96C04B2235/9646
Inventor 李根李尧
Owner 上海信传信息技术有限公司