Modified molecular sieve for hydro-desulfurization as well as preparation and application thereof
A molecular sieve and modification technology, which is applied in molecular sieve catalysts, refined hydrocarbon oils, chemical instruments and methods, etc., can solve the problems of octane number loss, affecting the desulfurization effect of sulfur-containing hydrocarbons, and high deactivation rate of adsorbents
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preparation example Construction
[0045] The preparation method of the modified molecular sieve provided by the invention comprises the steps of preparing a suspension and mixing the suspension with molecular sieve raw materials. The preparation method of the suspension includes: forming a mixture of metal powder, a hydroxyl-containing solvent and a surfactant, and treating it under ultrasonic waves to obtain a mixed liquid after ultrasonic treatment; wherein, during the ultrasonic treatment process, the fine particles are peeled off from the metal powder The metal particles are suspended in the solvent; the ultrasonically mixed solution separates the larger particles to obtain a suspension, which contains fine particles containing modified metals. The metal powder (metal powder) can be pure metal powder (when the metal film only contains modified metal and the modified metal is one kind), alloy powder containing modified metal and boron, containing multiple Alloy powders of modified metals. When the prepared...
specific Embodiment approach
[0057] The present invention provides a specific implementation of the preparation method of the modified molecular sieve, which includes the following steps: uniformly mixing the metal powder and the hydroxyl-containing solvent, and then using a specific ultrasonic power of 50-250W / (100g hydroxyl-containing solvent), preferably 100-150W / (100g hydroxyl-containing solvent) under the power of ultrasonic treatment for 4 to 10 hours, such as 5 to 8 hours, and then the ultrasonic mixture is centrifuged at 1200 to 3000 rpm, preferably 1500 to 2500 rpm, and the suspension is obtained after separation liquid; then put the molecular sieve solid powder or the molecular sieve slurry containing the molecular sieve solid powder into the obtained suspension, disperse evenly, and freeze-dry to prepare the modified molecular sieve. The average particle diameter of the metal fine powder is less than 20 microns, preferably 1-15 microns or 3-18 microns; the D of the molecular sieve solid powder...
Embodiment 1
[0070] This example is used to illustrate the modified molecular sieve of the present invention and its preparation method.
[0071] First, add 10g of nickel powder (average particle size of nickel powder is 10 microns, source: Sinopharm Group) and 100ml of ethylene glycol (Sinopharm Group, purity AR) to a 200ml jar, mix well, then add 60mg of surfactant Gandan Na2SO4 (purity AR, source: Nanjing Pars Biotechnology Co., Ltd.); then, the reaction vessel (jar) was placed in an ultrasonic cleaning machine, and was ultrasonically treated with 160W power for 6h (frequency 40KHz); the ultrasonically The liquid is centrifuged at 1500r / min for 20min in a centrifuge, and the supernatant (i.e. suspension) is taken out with a straw. The concentration of metallic nickel in the suspension is 15g / Kg, D 90 is 5nm;
[0072] 14.5 grams (on a dry basis) of SAPO-11 molecular sieve powder (Si: Al: P molar ratio = 1: 9: 10, D 90 =14 microns, relative crystallinity 91%, industrial grade, product o...
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