Inorganic nanoparticle modified PVC composite material craft shoe sole and preparation method thereof
A technology of inorganic nanoparticles and composite materials, applied in the field of inorganic nanoparticle modified PVC composite material craft soles and its preparation, can solve the problems of matrix resin damage, system performance deterioration, poor effect, etc., and achieve good heat resistance , enhanced wear resistance, strong antibacterial ability
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Embodiment 1
[0040] An inorganic nano-particle modified PVC composite material process shoe sole, comprising the following parts by weight of raw materials: 125 parts of PVC resin, 10 parts of composite modified nanoparticles, 11 parts of chlorinated polyethylene, 2 parts of calcium stearate, and phthalic acid 5 parts of dioctyl ester, 2 parts of stabilizer;
[0041] Composite modified nanoparticles made of nano-TiO 2 , Nano ZnO and Nano SiO 2 Manufactured by emulsion polymerization composite process, composite modified nanoparticles include the following raw materials by weight: nano TiO 2 15 parts, 5 parts of nano-ZnO, nano-SiO 2 6 parts, 20 parts of butyl acrylate, 20 parts of methyl methacrylate, 4 parts of sodium lauryl sulfate, 0.5 parts of 5wt% sodium hydroxide solution, 0.5 parts of sodium persulfate.
[0042] The preparation method of the above-mentioned inorganic nano particle modified PVC composite material craft sole includes the following steps:
[0043] (1) The nano TiO 2 , Nano Z...
Embodiment 2
[0048] An inorganic nano-particle modified PVC composite material process shoe sole, comprising the following parts by weight of raw materials: 130 parts of PVC resin, 12 parts of composite modified nanoparticles, 10 parts of chlorinated polyethylene, 1 part of calcium stearate, and phthalic acid 8 parts of di-n-butyl ester, 3 parts of stabilizer;
[0049] Composite modified nanoparticles made of nano-TiO 2 And nano ZnO and nano SiO 2 Manufactured by emulsion polymerization composite process, composite modified nanoparticles include the following raw materials by weight: nano TiO 2 20 parts, 7 parts of nano-ZnO, nano-SiO 2 6 parts, 27 parts of butyl acrylate, 27 parts of methyl methacrylate, 4 parts of sodium lauryl sulfate, 0.2 parts of 5 wt% sodium hydroxide solution, 0.5 parts of potassium persulfate.
[0050] The preparation method of the above-mentioned inorganic nano-particle modified PVC composite material craft shoe sole includes the following steps:
[0051] (1) The nano T...
Embodiment 3
[0056] An inorganic nano particle modified PVC composite material craft shoe sole, comprising the following parts by weight of raw materials: 135 parts of PVC resin, 12 parts of composite modified nanoparticles, 10 parts of chlorinated polyethylene, 1 part of calcium stearate, and phthalic acid 5 parts of diethyl ester, 3 parts of stabilizer;
[0057] Composite modified nanoparticles made of nano-TiO 2 , Nano ZnO and Nano SiO 2 Manufactured by emulsion polymerization composite process, composite modified nanoparticles include the following raw materials by weight: nano TiO 2 25 parts, 5 parts of nano-ZnO, nano-SiO 2 6 parts, 30 parts of butyl acrylate, 30 parts of methyl methacrylate, 5 parts of sodium lauryl sulfate, 0.8 parts of 5 wt% sodium hydroxide solution, 0.5 parts of ammonium persulfate.
[0058] The preparation method of the above-mentioned inorganic nano-particle modified PVC composite material craft shoe sole includes the following steps:
[0059] (1) The nano TiO 2 , N...
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