Environment-friendly water-based adhesive and preparation method thereof

A water-based adhesive, environmentally friendly technology, applied in the direction of adhesives, adhesive additives, adhesive types, etc., can solve the problems of easy deterioration, poor dispersion stability, etc., to achieve sufficient initial adhesion, excellent weather resistance, storage and transportation. good stability

Inactive Publication Date: 2020-05-08
庄明磊
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the dispersion stability of this water-based adhesive in water is poor, and it is easy to deteriorate during storage and transportation; the comprehensive performance of the obtained adhesive needs to be further improved after curing

Method used

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  • Environment-friendly water-based adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] An environmentally friendly water-based adhesive is characterized in that it comprises the following raw materials in parts by weight: 30 parts of acrylic acid modified amino-terminated water-soluble hyperbranched polyamide, (chloromethyl) boric acid pinacol ester ionized modified N ,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic rosin 10 parts, triethoxysilylpropyl maleic acid 3 parts, 5 parts of polyethylene glycol diacrylate, 4-8 parts of attapulgite, 1 part of fullerene-based carbon quantum dots, 0.5 parts of sodium dodecylbenzenesulfonate, 25 parts of deionized water, 3 parts of ethanol, benzoin 1 part of ether, 0.5 parts of silane coupling agent KH5500.

[0033] The (chloromethyl)boronic acid pinacol ester ionized modified N,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic acid The preparation method of rosin, comprises the steps:

[0034] Step S1. Add bis(trimethoxysilylpropyl...

Embodiment 2

[0039] An environmentally friendly water-based adhesive is characterized in that it comprises the following raw materials in parts by weight: 33 parts of acrylic acid modified amino-terminated water-soluble hyperbranched polyamide, (chloromethyl) boric acid pinacol ester ionized modified N ,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic rosin 11 parts, triethoxysilylpropyl maleic acid 4 parts, 6 parts of polyethylene glycol diacrylate, 5 parts of attapulgite, 1.5 parts of fullerene-based carbon quantum dots, 0.7 parts of polyoxypropylene polyoxyethylene glyceryl ether, 27 parts of deionized water, 4 parts of tetrahydrofuran, benzoin isopropyl 1.5 parts of ether, 0.6 parts of silane coupling agent KH5600.

[0040] The (chloromethyl)boronic acid pinacol ester ionized modified N,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic acid The preparation method of rosin, comprises the steps:

[0041]...

Embodiment 3

[0046] An environmentally friendly water-based adhesive is characterized in that it includes the following raw materials in parts by weight: 35 parts of acrylic acid modified amino-terminated water-soluble hyperbranched polyamide, (chloromethyl) boric acid pinacol ester ionized modified N , N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic rosin 13 parts, triethoxysilylpropyl maleic acid 4.5 parts, 7 parts of polyethylene glycol diacrylate, 6 parts of attapulgite, 2 parts of fullerene-based carbon quantum dots, 1 part of nonylphenol polyoxyethylene ether, 30 parts of deionized water, 4.5 parts of dioxane, α , 2 parts of α-diethoxyacetophenone, 0.8 parts of silane coupling agent KH5700.

[0047] The (chloromethyl)boronic acid pinacol ester ionized modified N,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic acid The preparation method of rosin, comprises the steps:

[0048] Step S1. Add bis(trim...

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Abstract

The invention discloses an environment-friendly water-based adhesive. The water-based adhesive comprises the following raw materials in parts by weight: 30-40 parts of acrylic acid modified amino-terminated water-soluble hyperbranched polyamide, 10-15 parts of (chloromethyl)boronic acid pinacol ester ionic-modified N,N'-bis(2-hydroxyethyl)-N,N'-bis(trimethoxysilylpropyl)ethylenediamine / hydrogenated acrylic acid rosin, -3-6 parts of triethoxysilyl propyl maleic acid, 5-10 parts of polyethylene glycol diacrylate, 4-8 parts of attapulgite, 1-3 parts of fullerene-based carbon quantum dots, 0.5-1.5parts of an emulsifier, 25-35 parts of deionized water, 3-6 parts of a cosolvent, 1-3 parts of a photoinitiator and 0.5-1 part of a coupling agent. The invention also discloses a preparation method of the environment-friendly water-based adhesive. The environment-friendly water-based adhesive disclosed by the invention has the advantages of good water resistance, higher peel strength, sufficientinitial adhesion, excellent water resistance and weather resistance, good storage and transportation stability, safer use process, greenness, environmental protection and high economic value, social value and ecological value.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to an environmentally friendly water-based adhesive and a preparation method thereof. Background technique [0002] In recent years, with the rapid development of my country's economy and social progress, people's living standards have gradually improved, and people's requirements for quality of life have become higher and higher. Higher requirements are put forward for the performance of adhesives for bonding, not only requiring high bonding strength, but also requiring good water resistance, heat resistance, weather resistance, and good performance stability. Environmental protection requirements during the preparation and use of adhesives are becoming more and more stringent. [0003] Adhesive is a natural or synthetic, organic or inorganic substance that connects two or more parts or materials together through interface adhesion and cohesion. At present, the common adhesives...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J177/00C09J193/04C09J171/02C09J11/04
CPCC08L2201/04C08L2201/08C08L2205/025C08L2205/03C08L2205/035C09J11/04C09J177/00C08L93/04C08L71/02C08K13/02C08K3/346C08K3/04C08K5/42
Inventor 庄明磊
Owner 庄明磊
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