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Preparation method of pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film

A nano-cellulose and stimuli-responsive technology, which is applied in the direction of protecting fruits/vegetables with a coating protective layer, can solve the problems of short timeliness of preservatives, serious residues, and no fruit responsiveness, etc., to extend the storage period, The effect of energy consumption reduction and full and efficient utilization

Active Publication Date: 2020-06-30
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the preservative prolongs the fresh-keeping period of mangoes, it cannot respond to the needs of the fruit to control the release of preservatives, resulting in short timeliness and serious residues of the preservative
Chinese patent 201810569081.5 discloses a straw cellulose antibacterial plastic wrap and its preparation method. The straw cellulose antibacterial plastic wrap can prevent the growth of bacteria during the fruit preservation process, thereby prolonging the freshness period of the fruit, but it does not have fruit responsiveness

Method used

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  • Preparation method of pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film
  • Preparation method of pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film
  • Preparation method of pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film

Examples

Experimental program
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Effect test

Embodiment 1

[0034] 100g of wheat straw with a water content of 8% was pulverized with a pulverizer, treated with a mixed solution of 5wt% sodium hydroxide and 1wt% sodium sulfite at 120°C for 3h, then boiled in 15wt% hydrogen peroxide solution for 5h, and then distilled water Washing and drying to obtain wheat straw cellulose. Weigh 0.75g of TEMPO (2,2,6,6-tetramethylpiperidine oxide), 5g of sodium bromide in a 250mL three-necked flask containing 100ml of deionized water, stir and dissolve, and add 50g of wheat straw cellulose powder. At 25°C, adjust the pH value of the sodium hypochlorite (available chlorine 12%, 5mmol / g) solution to about 10 by 0.1mol / L HCl, and slowly add the sodium hypochlorite solution dropwise to the flask, while adjusting the pH of the reaction system with 0.5mol / L NaOH Keep the pH around 10, and after the sodium hypochlorite solution is dripped within one hour, continue the reaction until the pH does not drop. Then use a high-speed shear homogenizer (AD200L-H) at...

Embodiment 2

[0036]Weigh 1g of N-isopropylacrylamide, 1.5g of acrylamide, 0.01g of cross-linking agent N,N-methylenebisacrylamide and 0.025g of 2-aminoethyl methacrylate hydrochloride and dissolve in 50ml deionized water, add 0.1g nanocellulose solution and mix well. Under nitrogen protection, add initiator potassium persulfate (0.0032g) and 2-2'-azobis-(2-2-ylpropane hydrochloride) (0.00814g), and catalyst 1, 2 of 0.045ml - Bis(dimethylamino)ethane. Afterwards, the mixed solution was poured into a PVA (polyvinyl alcohol) template, and reacted at 25° C. for 8 hours to obtain a pH and temperature double stimulus-responsive nanocellulose hydrogel film with a thickness of 0.08 mm and a tensile strength of 5.4 Kpa. The obtained hydrogel film was soaked in distilled water to remove unreacted monomers, and the distilled water was changed every 4 hours for 3 days. Subsequently, the hydrogel was dried in an oven at 30° C. for 24 hours, and then 1.25 g of the xerogel film was soaked in 100 ml of ...

Embodiment 3

[0038] Weigh 1.25g of N-isopropylacrylamide, 1.86g of acrylamide, 0.012g of crosslinking agent N,N-methylenebisacrylamide and 0.038g of 2-aminoethyl methacrylate hydrochloride Dissolve in 40ml deionized water, add 0.078g nanocellulose solution and mix well. Under the protection of nitrogen, add initiator potassium sulfate (0.004g) and 2-2'-azobis-(2-2-ylpropane hydrochloride) (0.01g), and 0.056ml of catalyst 1, 2- Bis(dimethylamino)ethane. Afterwards, the mixed solution was poured into the PVA template and reacted at 30°C for 6 hours to obtain a nanocellulose hydrogel film with dual stimulus response to pH and temperature, with a thickness of 0.075mm and a tensile strength of 3.36Kpa. The obtained hydrogel film was soaked in distilled water to remove unreacted monomers, and the distilled water was replaced every 4 hours for 3 days. Subsequently, the hydrogel film was freeze-dried for 24 hours, and then 0.625 g of the dry gel film was soaked in 50 ml of 1 mg / mL sodium benzoat...

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Abstract

The invention discloses a preparation method of a pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film. According to the preparation method, nanocellulose, N-isopropylacrylamide, a comonomer, a cross-linking agent and free amino are reacted to prepare a hydrogel film, then a preservative is loaded on the hydrogel film, and the pH and temperature dual stimuli-responsive food fresh-keeping nano cellulose hydrogel film is obtained. The hydrogel film can be directly wrapped on the periphery of fruits, adaptively release the preservative according to the changeof pH and temperature, and can effectively inhibit the rotting of fruit, thereby prolonging the storage period of fruit, enabling the preservative to be fully and efficiently utilized, and solving the problems of large residual quantity and short timeliness of the preservative; meanwhile, the loss of moisture in fruits can be inhibited; the flexibility of the hydrogel film is remarkably improved,rotting caused by damage of the packaging film is reduced, and fruits are protected more effectively; the preparation can be completed at room temperature, so that the energy consumption is obviouslyreduced.

Description

technical field [0001] The invention relates to a preparation method of a pH- and temperature-responsive food fresh-keeping nano-cellulose hydrogel film, which belongs to the field of food fresh-keeping. Background technique [0002] In recent years, with the improvement of people's living standards, the demand for various fruits has gradually increased, but fruits are prone to rot and deterioration during storage and transportation. Preservatives are a simple and effective means of fresh-keeping, but preservatives are time-sensitive, which makes it difficult to play a role in fresh-keeping in the later stages of storage, and it is easy to cause fruit rot and deterioration. Moreover, the fruit is prone to rot and deterioration under high temperature, and the fruit will release acidic substances during the ripening stage, which will cause the pH around the fruit to change. Therefore, a system that can control the release of preservatives in response to the needs of fruits is...

Claims

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Application Information

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IPC IPC(8): C08J7/00C08J5/18C08L51/02C08F251/02C08F220/56C08F220/54C08F222/38C08F220/34A23B7/16
CPCC08J7/00C08J5/18C08F251/02A23B7/16C08J2351/02C08F220/56C08F220/54C08F222/385C08F220/34
Inventor 徐徐郭丽珍沙哈勒·希芭王钰琪林详宇刘炜祺王石发
Owner NANJING FORESTRY UNIV
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