A kind of horizontal continuous casting method of copper alloy

A horizontal continuous casting and copper alloy technology, which is applied in the field of non-ferrous metal processing, can solve the problems of early precipitation and decomposition of supersaturated solid solution, affect the strength and conductivity of copper alloy, and lose the hardening effect of cold rolling, so as to ensure high conductivity characteristics , Improve tissue uniformity, increase the effect of production beat

Active Publication Date: 2021-11-05
ZHEJIANG UNIV
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Problems solved by technology

However, the existing copper alloy preparation methods introduced into the horizontal continuous casting process cannot obtain a slab in which the alloy elements are in a supersaturated solid solution state in the horizontal continuous casting process, so it is necessary to carry out further high-temperature solution treatment on the slab to make the cast The alloying elements in the slab are in a supersaturated solid solution state, which still needs to be improved in terms of energy saving
The existing continuous extrusion process also generally has the problem of early precipitation and decomposition of supersaturated solid solutions, which affects the strength and electrical conductivity of copper alloys
If you want the material to have a solid solution state before aging, the most direct way is to do a high-temperature solution heat treatment before aging. However, this idea not only consumes high energy, but also leads to the complete loss of the pre-sequence cold rolling hardening effect.

Method used

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  • A kind of horizontal continuous casting method of copper alloy
  • A kind of horizontal continuous casting method of copper alloy
  • A kind of horizontal continuous casting method of copper alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 0

[0091] Embodiment 0: the preparation embodiment of forging high-temperature nickel-based alloy:

[0092] The alloy ingot is smelted by vacuum smelting + electroslag remelting process, the composition is: 0.05wt.%C, 15wt.%Cr, 6wt.%Mo, 5wt.%W, 2wt.%Ti, 5.5wt.%Al, the rest For you. After the alloy ingot was homogenized at 1250°C for 1h, it was formed by isothermal forging at 1000°C with a deformation of 80%. After that, it was kept at 800°C for 16 hours, quenched and tempered at 350°C for 1 hour, and the tensile properties of the alloy at room temperature to 800°C were tested. The results are shown in Table 1:

[0093] Table 1 High Temperature Mechanical Properties of Alloys

[0094] temperature / ℃ Tensile strength / MPa Yield strength / MPa Elongation / % room temperature 1200 1100 8 500 1220 1120 9 800 1280 1150 9

Embodiment 1-1

[0096] The first step: batching melting: according to the alloy composition of Cu-0.5wt.%Ag, batching is carried out, put into the melting furnace and fully melted, carry out sampling inspection and analysis of oxygen content and alloy element content, feed and fully deoxidize to within 10ppm according to the analysis results, The melt is introduced into the holding furnace through the inner guide groove of the melting furnace.

[0097] The second step: horizontal continuous casting: horizontal continuous casting is carried out under the side of the holding furnace, and two crystallizers with an interval of 400mm are arranged horizontally and installed under the side of the holding furnace. Group 1 cooling units are closest to the holding furnace. The reverse cooling method is adopted, and the temperature of the water inlet is lower than 20°C. The water flow V3 of the third group of cooling units is 2000L / min, the water flow V2 of the second group of cooling units is 2400L / mi...

Embodiment 1-2

[0100] Step 2: Horizontal continuous casting: 4 crystallizers are used with an interval of 200mm. The water flow V3 of the third cooling unit is 100L / min, and the water flow V2 of the second cooling unit is 120L / min. The water flow V1 of the unit is 150L / min, the electromagnetic stirring frequency used is 2Hz, and the cross-sectional area of ​​the blank is 50mm 2 , the extraction speed is 100mm / min, 30 atomizing nozzles are set, the distance between the nozzles is 20mm, the distance between the nozzle and the surface of the billet is 50mm, and the water pressure is 0.5MPa.

[0101] The remaining steps and parameters are the same as in Example 1-1.

[0102] Similar to Example 1-1, the XRD pattern of the as-cast green body shows that it has a supersaturated solid solution structure.

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Abstract

The invention discloses a copper alloy horizontal continuous casting method. The method is to carry out horizontal continuous casting of the copper alloy melt in the holding furnace under the side of the holding furnace: at least one multi-channel water-cooled crystallizer is installed under the side of the holding furnace, The multi-channel water-cooled crystallizer is provided with three groups of independent cooling units sequentially along the direction of the billet lead-out, the first group of cooling units is closest to the holding furnace; the temperature of the water inlet of each group of cooling units is lower than 20°C, and the temperature of the three cooling units is controlled. The temperature gradient of the group cooling unit; the outer wall of the water cooling jacket of the first group and the second group cooling unit of the multi-channel water-cooled crystallizer is provided with an electromagnetic induction coil to realize electromagnetic stirring, and a water curtain spray is provided at the outlet of the multi-channel water-cooled crystallizer The cooling device cools the preform to obtain a cast preform in which all alloy elements are in a supersaturated solid solution state. The invention can not only save the high-temperature solid solution link that consumes the most energy in the traditional high-strength and high-conductivity copper alloy preparation process, but also can effectively refine the crystal grains and ensure the high strength of the alloy.

Description

Technical field: [0001] The invention relates to the technical field of nonferrous metal processing, in particular to a method for horizontal continuous casting of copper alloys. Background technique: [0002] As a typical representative of conductor materials, copper alloys are widely used in the field of electrical engineering. With the development of the 5G information age, higher performance requirements are put forward for the key copper alloy conductors used. Taking large-scale integrated circuits as an example, due to the increasingly high level of circuit integration and continuous increase in power density, this requires copper alloys as integrated circuit lead frames to have not only high strength but also high electrical and thermal conductivity, so as to ensure the generation of Lowest possible thermal effect and fast heat dissipation. At the same time, in order to meet the requirements of the semiconductor process, the lead frame copper alloy must also have ex...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22D11/045B22D11/115B22D11/12B22D11/124B22D11/22
CPCB22D11/045B22D11/115B22D11/1206B22D11/124B22D11/22B22D11/004Y02P10/25
Inventor 王宏涛方攸同刘嘉斌方晓阳张进东王立天孟亮
Owner ZHEJIANG UNIV
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