Continuous reaction device and method for microwave biomass pyrolysis

A technology of biomass pyrolysis and microwave reaction, which is applied in the preparation of biofuels, liquid hydrocarbon mixtures, chemical/physical/physicochemical processes of energy application, etc. Biomass pyrolysis, small, only less than 5 kg, etc., to achieve industrial application, good effect, and improve efficiency

Inactive Publication Date: 2012-07-18
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, under continuous operation conditions, various abnormal conditions may occur in the reactor, such as the reactor is blocked by the feed, and external force is required to dredge the material, which is easy to cause the reactor to break during the actual operation.
In the reports of continuous microwave reactors, there are tube or conveyor belt heating methods, but the heating tube materials used are either polytetrafluoroethylene and other materials that cannot withstand high temperatures, or although the reactor can withstand high temperatures, the reaction is Open system, cannot be used in closed biomass pyrolysis
The utility model patent CN201252654Y adopts a spiral conveying and stirring microwave heating device, but because the microwave enters through the window, once the system is blocked, the system pressure will rise rapidly. If the window is broken, the material will enter the waveguide, which will affect the microwave magnetism Control is destructive and security cannot be guaranteed
CN2015207545U discloses a continuous microwave low-temperature dry distillation device, mainly for dry distillation of pulverized coal at low temperature, but the device has a long heating time, takes 15-30 minutes from room temperature to 750°C, and has a small processing capacity. up to 5 kg
Therefore, there is still no continuous reaction device that can realize microwave biomass pyrolysis
Moreover, the operating conditions of continuous reaction and batch reaction are also very different. At present, there is still no reasonable reaction operation method to achieve continuous reaction.

Method used

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  • Continuous reaction device and method for microwave biomass pyrolysis
  • Continuous reaction device and method for microwave biomass pyrolysis
  • Continuous reaction device and method for microwave biomass pyrolysis

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] The broad-leaved poplar sawdust is used as raw material, the particle size distribution is 0.025-0.8mm, the single-mode resonant cavity and the screw are used to advance the feeding mode, and the microwave pyrolysis experiment is carried out with the above steps of the present invention. The microwave power is 2kW, and the biomass is reacting The residence time in the vessel was 5min, the feed rate was 10kg / h, and the reaction temperature was 400°C. Liquid and gaseous products were collected. The yield of pyrolysis liquid bio-oil is 44%, the yield of gas products is 29%, and the low calorific value is 22.68MJ / Nm 3 .

Embodiment 2

[0068] Using sawdust as raw material, particle size distribution is 0.025-0.8mm, adding 5wt% activated carbon, using multi-mode resonant cavity, carrying out microwave pyrolysis experiment according to the above steps of the present invention, microwave power 1kW, feed rate 20kg / h, biomass The residence time in the reactor was 3 min, and the liquid and gaseous products were collected. The yield of pyrolysis liquid bio-oil is 39%, the yield of gas products is 40%, and the low calorific value is 16.07MJ / Nm 3 .

Embodiment 3

[0070] Using sawdust as raw material, the particle size distribution is 0.025-0.8mm, adding 5wt% potassium carbonate, using a multi-mode resonant cavity, carrying out microwave pyrolysis experiments according to the above steps of the present invention, the feed rate is 20kg / h, and the biomass is in the reactor The medium residence time is 3min, the microwave power is 1kW, and the liquid product and gas product are collected. The yield of pyrolysis liquid bio-oil is 37%, and the yield of gas product is 47%.

[0071] The bio-oil composition generated in Example 2 is more complex than that in Example 3, so adding potassium carbonate can simplify the bio-oil composition. Fourier transform ion cyclotron resonance mass spectrometry results are as follows figure 2 and image 3 as shown, figure 2 and image 3 The ordinate DBE of is the equivalent double bond (DBE), which is defined as the sum of the double bond and the number of naphthenes. If the molecular formula of the compo...

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Abstract

The invention relates to a continuous reaction device and a method for microwave biomass pyrolysis. The continuous reaction device for the microwave biomass pyrolysis mainly comprises a microwave generator, a reactor and a resultant separating device. The continuous reaction device is a continuous operating system and can process 10-50kg of the biomass every hour. According to the continuous reaction device for the microwave biomass pyrolysis, characteristics of microwave volume heating, transient heating and selective heating are fully utilized, undried biomass is directly pyrolyzed so as toobtain three products of liquid bio-oil, bio-gas and solid coke, the pylolysis efficiency of the biomass is greatly improved, the yield and the quality of the liquid bio-oil are improved, the structure is simple, the design is reasonable, and the achievement of industrial application of the microwave biomass pyrolysis is facilitated.

Description

technical field [0001] The invention relates to a biomass pyrolysis device and method, and belongs to the technical fields of microwave heating application technology and regeneration and utilization of biomass waste resources. Background technique [0002] With the rapid reduction of fossil fuels such as petroleum, biomass energy has risen rapidly and has been favored by researchers. Bio-oil, a liquid product of biomass pyrolysis, has attracted widespread attention as a liquid energy source that is very likely to replace fossil fuels. It is of great significance to the protection of the ecological environment, and its economic benefits will become more and more significant with the rise of the fuel market price. my country's biomass pyrolysis technology to produce bio-oil started relatively late, and microwave pyrolysis biomass technology is particularly immature. According to the principle of microwave heating, microwave pyrolysis of biomass has the advantages of fast spe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J19/12C10B53/02C10B57/00C10G1/00
CPCY02E50/14Y02E50/10
Inventor 商辉路冉冉
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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