Continuous reaction device and method for microwave biomass pyrolysis
A biomass pyrolysis and reaction device technology, applied in the microwave heating application, biomass pyrolysis device field, can solve the problem of continuous reaction without reasonable reaction operation mode, closed biomass pyrolysis, small, only less than 5 kg and other problems, to achieve the effect of industrial application, good effect and efficiency improvement
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Embodiment 1
[0066] The broad-leaved poplar sawdust is used as raw material, the particle size distribution is 0.025-0.8mm, the single-mode resonant cavity and the screw are used to advance the feeding mode, and the microwave pyrolysis experiment is carried out with the above steps of the present invention. The microwave power is 2kW, and the biomass is reacting The residence time in the vessel was 5min, the feed rate was 10kg / h, and the reaction temperature was 400°C. Liquid and gaseous products were collected. The yield of pyrolysis liquid bio-oil is 44%, the yield of gas products is 29%, and the low calorific value is 22.68MJ / Nm 3 .
Embodiment 2
[0068] Using sawdust as raw material, particle size distribution is 0.025-0.8mm, adding 5wt% activated carbon, using multi-mode resonant cavity, carrying out microwave pyrolysis experiment according to the above steps of the present invention, microwave power 1kW, feed rate 20kg / h, biomass The residence time in the reactor was 3 min, and the liquid and gaseous products were collected. The yield of pyrolysis liquid bio-oil is 39%, the yield of gas products is 40%, and the low calorific value is 16.07MJ / Nm 3 .
Embodiment 3
[0070] Using sawdust as raw material, the particle size distribution is 0.025-0.8mm, adding 5wt% potassium carbonate, using a multi-mode resonant cavity, carrying out microwave pyrolysis experiments according to the above steps of the present invention, the feed rate is 20kg / h, and the biomass is in the reactor The medium residence time is 3min, the microwave power is 1kW, and the liquid product and gas product are collected. The yield of pyrolysis liquid bio-oil is 37%, and the yield of gas product is 47%.
[0071] The bio-oil composition generated in Example 2 is more complex than that in Example 3, so adding potassium carbonate can simplify the bio-oil composition. Fourier transform ion cyclotron resonance mass spectrometry results are as follows figure 2 and image 3 as shown, figure 2 and image 3 The ordinate DBE of is the equivalent double bond (DBE), which is defined as the sum of the double bond and the number of naphthenes. If the molecular formula of the compo...
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