High-temperature-resistant and aging-resistant thermoplastic elastomer material

A thermoplastic elastomer and anti-aging technology, which is applied in the field of thermoplastic elastomers, can solve the problems of greatly affecting production efficiency, insufficient high temperature resistance, and accelerated aging speed, so as to improve heat resistance, good mechanical properties, and improve processing performance Effect

Inactive Publication Date: 2020-08-11
六安市叶集区聚诚高分子材料有限公司
View PDF4 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The thermoplastic elastomer materials currently produced have insufficient high temperature resistance in some special fields (such as sealing rings). After the thermal aging test at 135°C×1000h, the material will often fail in performance and the aging speed will be accelerated. Therefore, it can only be used in If it is used in a short period of time, it needs to be replaced frequently, which has a great impact on production efficiency, and the material may fail at any time, causing safety hazards

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High-temperature-resistant and aging-resistant thermoplastic elastomer material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A thermoplastic elastomer material with high temperature resistance and aging resistance, its raw materials include: thermoplastic elastomer 100kg, nitrile rubber 15kg, phenolic resin 10kg, polypropylene fiber 10kg, carbon nanotube 10kg, maleic anhydride grafted ethylene-octene copolymer Compound 4kg, composite zirconium dioxide 2kg, di-tert-butyl hydroperoxide 2kg, naphthenic oil 1kg, 2-tert-butyl-4-methylphenol 8kg, chlorinated paraffin 0.2kg, benzyl silicone oil 0.8kg.

[0026] The thermoplastic elastomer is composed of thermoplastic polyurethane elastomer rubber and ethylene-butyl acrylate copolymer in a mass ratio of 1:0.6.

[0027] Composite zirconia is prepared by the following process: 10kg of alumina fiber and 5kg of zirconia precursor are mixed, vacuum ground for 1 hour, sent to a high-temperature calcination furnace, calcined at 1300°C for 10 minutes, cooled to room temperature, and pulverized to obtain composite zirconia Zirconia.

[0028] The preparation m...

Embodiment 2

[0034] A thermoplastic elastomer material with high temperature and aging resistance, its raw materials include: 100kg thermoplastic elastomer, 25kg nitrile rubber, 4kg phenolic resin, 40kg polyborate fiber, 2kg maleic anhydride grafted ethylene-ethylene propylene rubber copolymer , 6kg of composite zirconium dioxide, 1kg of dicumyl peroxide, 2kg of naphthenic oil, 4kg of 2-tert-butyl-4-methylphenol, 1kg of chlorinated paraffin, and 1kg of benzyl silicone oil.

[0035] The thermoplastic elastomer is composed of thermoplastic polyurethane elastomer rubber and ethylene-butyl acrylate copolymer in a mass ratio of 1:0.2.

[0036] Composite zirconia is prepared by the following process: 16 kg of alumina fiber and 1 kg of zirconia precursor are mixed, vacuum ground for 2 hours, sent to a high-temperature calcination furnace, calcined at 1250 ° C for 20 minutes, cooled to room temperature, and pulverized to obtain a composite zirconia Zirconia.

[0037] The preparation method of the...

Embodiment 3

[0043] A thermoplastic elastomer material with high temperature resistance and aging resistance, its raw materials include: thermoplastic elastomer 100kg, nitrile rubber 18kg, phenolic resin 8kg, basalt fiber 10kg, nano-cellulose whiskers 15kg, maleic anhydride grafted ethylene-propylene copolymer Compound 3.5kg, composite zirconia 3kg, 1,3-bis(tert-butylperoxyisopropyl)benzene 1.7kg, naphthenic oil 1.2kg, 2,2'-methylenebis(4-methyl-6 -tert-butylphenol) 7kg, polyethylene wax 1.3kg.

[0044] The thermoplastic elastomer is composed of thermoplastic polyurethane elastomer rubber and ethylene-butyl acrylate copolymer in a mass ratio of 1:0.5.

[0045] Composite zirconia is prepared by the following process: 12kg of alumina fiber and 4kg of zirconia precursor are mixed, vacuum ground for 1.3h, sent to a high-temperature calciner, calcined at a temperature of 1280°C for 13min, cooled to room temperature, and pulverized to obtain a composite zirconium dioxide.

[0046] The preparat...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a high-temperature-resistant and aging-resistant thermoplastic elastomer material. The material comprises the following raw materials in parts by weight: 100 parts of a thermoplastic elastomer, 15-25 parts of butadiene-acrylonitrile rubber, 4-10 parts of phenolic resin, 20-40 parts of a reinforcing agent, 2-4 parts of an interfacial compatibilizer, 2-6 parts of composite zirconium dioxide, 1-2 parts of a peroxide vulcanizing agent, 1-2 parts of naphthenic oil, 4-8 parts of an antioxidant and 1-2 parts of a lubricant. The thermoplastic elastomer comprises thermoplastic polyurethane elastomer rubber and an ethylene-butyl acrylate copolymer; the reinforcing agent is at least one of polypropylene fibers, carbon nanotubes, basalt fibers, polyborate fibers and nanocellulose whiskers; the interfacial compatibilizer is at least one of a maleic anhydride grafted ethylene-vinyl acetate copolymer, a maleic anhydride grafted ethylene-propylene copolymer, a maleic anhydridegrafted ethylene-octene copolymer and a maleic anhydride grafted ethylene-ethylene-propylene rubber copolymer.

Description

technical field [0001] The invention relates to the technical field of thermoplastic elastomers, in particular to a high temperature and aging resistant thermoplastic elastomer material and a preparation method thereof. Background technique [0002] Thermoplastic elastomer TPE / TPR, also known as artificial rubber or synthetic rubber, is a new type of polymer material between rubber and resin. It can not only replace part of rubber, but also modify plastic. Thermoplastic elastomer has rubber It has the dual properties and broad characteristics of plastics. It not only has the excellent properties of high elasticity, aging resistance and oil resistance of traditional cross-linked vulcanized rubber, but also has the characteristics of more convenient processing and wide processing methods of ordinary plastics. Therefore, thermoplastic elastomers TPE / TPR material has become the latest material to replace traditional rubber. [0003] The thermoplastic elastomer materials current...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L23/08C08L9/02C08L61/06C08K13/04C08K3/22C08K7/08
CPCC08K2003/2244C08L75/04C08L2201/08C08L2205/035C08L2205/16C08L2207/04C08L23/0869C08L9/02C08L61/06C08K13/04C08K3/22C08K7/08
Inventor 饶从庆
Owner 六安市叶集区聚诚高分子材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap