A ceria-modified copper hydroxide composite electrode and its application in glucose sensor

A technology of ceria and composite electrodes, which is applied in the field of biochemical sensors, can solve the problems of insufficient sensitivity of electrodes and poor conductivity, and achieve the effects of improving electrode performance, high sensitivity, and low preparation cost
CN111796014BActive Publication Date: 2021-07-16SOUTH CHINA UNIV OF TECH +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SOUTH CHINA UNIV OF TECH
Publication Date
2021-07-16

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Abstract

The invention discloses a ceria-modified copper hydroxide composite electrode and its application in a glucose sensor. The composite electrode includes an electrode base, a protective layer, and nano-CeO in sequence from the inside to the outside. 2 ‑Cu(OH) 2 Composite modification layer; the nano-CeO 2 ‑Cu(OH) 2 The composite has a three-dimensional nanograss array structure. The present invention adopts simple and feasible electrochemical deposition and oxidation method to prepare nano-CeO 2 ‑Cu(OH) 2 The nanograss array structure greatly improves the electrode performance, the preparation cost is low, and no special environment and large instruments are required. When the electrode of the invention is used for glucose, it has lower detection limit, higher sensitivity and good anti-interference performance.
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Description

technical field

[0001] The invention belongs to the field of biochemical sensors, and relates to a ceria-modified copper hydroxide (CeO 2 -Cu(OH) 2 ) composite electrode and its application in glucose sensor. Background technique

[0002] Copper and its oxides have good catalytic activity, so they are excellent materials for non-enzymatic glucose sensors. Many reported non-enzymatic glucose sensors based on copper and its oxide nanomaterials have been demonstrated for glucose sensing.

[0003] The sensing performance of electrochemical glucose sensors requires not only efficient redox reactions at the electrode / electrolyte interface but also fast electron transport. However, nano-copper materials are easily oxidized, and copper oxides have poor conductivity, which makes the electrodes not sensitive enough. Contents of the invention

[0004] Primary purpose of the present invention is to provide a kind of nanometer CeO 2 -Cu(OH) 2 composite electrode.

[0005] Anothe...

Claims

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