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A super high temperature high strength toughness cement slurry system

An ultra-high-temperature, high-strength technology, which is applied in the field of oil and gas exploration and development, can solve the problems of unsatisfactory cementing operations in ultra-high-temperature, ultra-deep wells, complex formations, ultra-high-temperature cement stone strength decline, and insufficient ultra-high-temperature strength, so as to improve rheology And pumpability, good application performance, good temperature resistance

Active Publication Date: 2022-03-25
BC P INC CHINA NAT PETROLEUM CORP +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Invention patent "An oil well cement slurry system for preventing high-temperature strength decline and its preparation method" (CN110484223A) uses a graphene emulsion as a strength enhancer, and micron-sized shaped silica and 8-12% xanthan gum as a suspension stabilizer. The construction performance of the cement slurry is good at 180°C, the strength is 35MPa, and it will not decline within 14 days, but the cost of materials used in this method is high, and it is not suitable for cementing construction under ultra-high temperature conditions above 200°C
Invention patent "A cementing cement for ultra-high temperature deep wells and its preparation method and application" (CN 110563428 A) uses silicon powder as the first anti-strength decay agent, and the second anti-strength decay agent is aluminum oxide, hydrogen One or more of alumina, zinc oxide, zinc hydroxide and strontium chloride, the strength of cement stone at 200℃~240℃ does not decline to 30MPa, but the ultra-high temperature strength of this method is not high enough, and the toughness modification is not carried out
[0005] Although the above-mentioned technologies have achieved certain effects in the mechanical modification of high-temperature cement, there are still problems in the stability of ultra-high-temperature cement slurry, strength decline and toughening of ultra-high-temperature cement stones, and cannot meet the requirements of solidification in complex formations of ultra-high-temperature and ultra-deep wells. well operation

Method used

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  • A super high temperature high strength toughness cement slurry system
  • A super high temperature high strength toughness cement slurry system
  • A super high temperature high strength toughness cement slurry system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, 10 parts of anti-high temperature strength decline material (100-mesh wollastonite and 100-mesh coke gemstone in a mass ratio of 1:1) , 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (mass ratio of bentonite, magnesium aluminum silicate, and wenlun glue is 1:2:1), 2 parts of fluid loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of clear water.

[0031] The cement slurry preparation process is as follows: take 100 parts of oil well cement, 40 parts of 600-mesh acid-washed quartz sand, 10 parts of high-temperature strength decay resistance material, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of poly...

Embodiment 2

[0033]Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, anti-high temperature strength decline material (100-mesh wollastonite and 200-mesh bauxite in a mass ratio of 1:1) 15 3 parts, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (the mass ratio of bentonite, magnesium aluminum silicate, and wenlun gum is 1:2:1) , 2 parts of water loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of water.

[0034] The cement slurry preparation process is as in Example 1.

Embodiment 3

[0036] Formula: 100 parts of high sulfate-resistant G-grade oil well cement, 40 parts of 600-mesh acid-washed quartz sand, anti-high temperature strength decline material (200-mesh kyanite and 200-mesh bauxite compounded at a mass ratio of 1:1) 15 3 parts, 3 parts of ultra-high temperature toughening agent halloysite nanotubes, 1 part of polycarboxylic acid dispersant, 3 parts of ultra-high temperature stabilizer (the mass ratio of bentonite, magnesium aluminum silicate, and wenlun gum is 1:2:1) , 2 parts of water loss reducer (patent application number 201910693705.9), 1.2 parts of retarder (patent number CN 104403056 B), 0.1 part of tributyl phosphate (defoamer), 55 parts of water.

[0037] The cement slurry preparation process is as in Example 1.

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Abstract

The invention relates to an ultra-high-temperature high-strength toughness cement slurry system, which is composed of the following components in parts by weight: 100 parts of high sulfate-resistant G-grade oil well cement, 35-45 parts of pickling quartz sand, and ultra-high temperature strength anti-fading 10-20 parts of material, 2-5 parts of ultra-high temperature toughening material, 0.5-2 parts of dispersant, 2-4 parts of ultra-high temperature stabilizer, 0.5-4 parts of fluid loss reducer, 0.2-2 parts of retarder, 0.1-1 part of foaming agent, 40-80 parts of clear water. The acid-washed quartz sand is refined quartz sand treated with acid, and the ultra-high temperature strength anti-recession material is a mixture of two or more of wollastonite, kyanite, burnt gemstone, and bauxite. The super high temperature toughening material is halloysite nanotube, the dispersant is polycarboxylic acid dispersant for oil well cement, and the super high temperature stabilizer is a mixture of bentonite, magnesium aluminum silicate and wenlun gum. The cement stone of the invention does not decline in strength under ultra-high temperature conditions, has good toughness, and effectively improves the cementing quality of unconventional oil and gas wells and high-temperature deep wells.

Description

technical field [0001] The invention relates to an ultra-high-temperature high-strength toughness cement slurry system in the field of petroleum and natural gas exploration and development, which is suitable for ultra-high-temperature deep well cementing operations with a bottom-hole circulation temperature (BHCT) above 210°C and a bottom-hole static temperature (BHST) above 240°C. Background technique [0002] With the rapid development of my country's economy and society, the demand for oil and gas resources continues to grow. In order to ensure national energy security and reduce oil and gas dependence on foreign countries, it is necessary to increase exploration and development efforts. Deep and ultra-deep oil and gas have great potential and are important replacement resources. Basins such as Tarim, Junggar, Sichuan, and Qaidam have successively proven oil and gas reservoirs deeper than 8,000 m. With the deepening of oil and gas exploration and development, the number o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/02
CPCC04B28/02C04B2201/50C04B2111/00724C04B14/06C04B14/043C04B14/10C04B14/005C04B14/104C04B14/04C04B24/38C04B24/003C04B2103/408C04B2103/0068C04B2103/22
Inventor 刘慧婷靳建洲于永金张华刘子帅张弛徐明刘硕琼李明夏修建纪宏飞郭雪利
Owner BC P INC CHINA NAT PETROLEUM CORP
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