A kind of anti-high temperature gel plugging agent for oil-based drilling fluid and its preparation method and application

A technology of oil-based drilling fluid and loss-stopping agent, which is applied in chemical instruments and methods, earth-moving drilling and production, wellbore/well components, etc. Leakage, inability to apply to high temperature formations, etc., to achieve the effects of low cost, small performance impact, and controllable crosslinking time

Active Publication Date: 2022-06-24
CHINA UNIV OF PETROLEUM (EAST CHINA)
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example: Chinese patent document CN105646763A provides an oil-based gel plugging agent, which is composed of the following raw materials in parts by weight: 20-40 parts of styrene, 2-10 parts of biodiesel, 0.5-5 parts of divinylbenzene, dimethyl 0.1-5 parts of diethylene glycol acrylate and 0.01-1 part of azobisisobutyronitrile, but the volume expansion rate of the above-mentioned oil-based gel plugging agent is low, and the plugging effect is good when facing cracks of 3mm and above bad
Chinese patent document CN105199693A provides an oil-based gel plugging slurry, which is composed of 35-70 parts of base oil, 5-25 parts of curing agent, 0.1-1 part of activator, 0.5 -4 parts of water, 0-60 parts of weighting agent, the base oil is at least one of castor oil, soybean oil, rapeseed oil, peanut oil, animal oil, fatty acid methyl ester, dimethyl maleate, Described curing agent is at least one in calcium oxide, magnesium oxide, zinc oxide, sodium carbonate, sodium bicarbonate, magnesium carbonate, sodium acetate, and described activator is potassium hydroxide, sodium hydroxide, sodium carbonate, At least one of potassium carbonate, and the weighting agent is at least one of barite, limestone, and iron ore powder, but the gel formed by the oil-based gel plugging slurry has poor temperature resistance and cannot be applied to High temperature formation, and can't seal malignant leakage
[0006] At present, gel plugging agents suitable for oil-based drilling fluids generally have defects such as low gel strength and poor temperature resistance, and cannot be used in ultra-high temperature formations.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of anti-high temperature gel plugging agent for oil-based drilling fluid and its preparation method and application
  • A kind of anti-high temperature gel plugging agent for oil-based drilling fluid and its preparation method and application
  • A kind of anti-high temperature gel plugging agent for oil-based drilling fluid and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] An anti-high temperature gel plugging agent for oil-based drilling fluid, comprising the following raw materials in parts by weight: 22 parts of a gelling agent, 5 parts of a crosslinking agent, 0.8 parts of an initiator, and 73.2 parts of a base oil;

[0036] Wherein, the gelling agent is a combination of diethylene glycol dimethacrylate and cetyl methacrylate, and the mass ratio of diethylene glycol dimethacrylate and cetyl methacrylate is 1 : 2; the crosslinking agent is the combination of dibutylammonium oleate and zinc acrylate, and the mass ratio is 1:1; the initiator is azobisisobutyronitrile; the base oil is white oil.

[0037] The preparation method of the above-mentioned high temperature anti-high temperature gel plugging agent for oil-based drilling fluid comprises the following steps:

[0038] (1) adding the gelling agent to the white oil at 40°C, then warming up to 50°C, at 50°C, stirring at a stirring rate of 500 rev / min for 25min to dissolve it completely...

Embodiment 2

[0042] An anti-high temperature gel plugging agent for oil-based drilling fluid, comprising the following raw materials in parts by weight: 22 parts of a gelling agent, 5 parts of a crosslinking agent, 0.4 parts of an initiator, and 72.6 parts of a base oil;

[0043] Wherein, the gelling agent is a combination of diethylene glycol dimethacrylate and cetyl methacrylate, and the mass ratio of diethylene glycol dimethacrylate and cetyl methacrylate is 1 : 2; the crosslinking agent is the combination of dibutylammonium oleate and zinc acrylate, and the mass ratio is 1:1; the initiator is azobisisobutyronitrile; the base oil is white oil.

[0044] The preparation method of the above-mentioned high temperature anti-high temperature gel plugging agent for oil-based drilling fluid is as described in Example 1.

Embodiment 3

[0046] An anti-high temperature gel plugging agent for oil-based drilling fluid, comprising the following raw materials in parts by weight: 22 parts of gelling agent, 7 parts of crosslinking agent, 0.8 part of initiator, and 70.2 parts of base oil;

[0047] Wherein, the gelling agent is a combination of diethylene glycol dimethacrylate and cetyl methacrylate, and the mass ratio of diethylene glycol dimethacrylate and cetyl methacrylate is 1 : 2; the crosslinking agent is the combination of dibutylammonium oleate and zinc acrylate, and the mass ratio is 1:1; the initiator is azobisisobutyronitrile; the base oil is white oil.

[0048] The preparation method of the above-mentioned high temperature anti-high temperature gel plugging agent for oil-based drilling fluid is as described in Example 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
densityaaaaaaaaaa
widthaaaaaaaaaa
lengthaaaaaaaaaa
Login to view more

Abstract

The invention provides a high temperature resistant gel plugging agent for oil-based drilling fluid and its preparation method and application. The gel plugging agent includes the following raw materials in parts by weight: 15-30 parts of gel agent, 2-2 parts of crosslinking agent 7 parts, 0.3-1 part of initiator, 60-80 parts of base oil, described gelling agent is diethylene glycol dimethacrylate, pentylene glycol diacrylate, cetyl methacrylate, A combination of two or more than three of polyurethane resins, the cross-linking agent is two or three of dibutylammonium oleate, zinc acrylate and divinylbenzene. The leak-stopping agent of the present invention enters the cracks under the action of the pressure difference, and automatically forms a gel to form a high-strength, high-temperature-resistant gel, thereby sealing the cracks; the leak-stopping agent of the present invention has good oil-based drilling resistance and can The wide range of cracks works, which has a good plugging effect on malignant leakage, and has the advantages of high temperature resistance, fast volume expansion, high gel formation strength and controllable gelation time.

Description

technical field [0001] The invention relates to an anti-high temperature gel plugging agent for oil-based drilling fluid, a preparation method and application thereof, and belongs to the technical field of drilling fluid plugging. Background technique [0002] In order to ensure the safety, speed and efficiency of the drilling process, the bottom hole pressure must be kept higher than the formation pressure during drilling, and this pressure difference will lead to the loss of drilling fluid when drilling into permeable or fractured formations. Loss of drilling fluid leads to the loss of a large amount of drilling fluid, which increases the drilling cost; and the lost drilling fluid will destroy the permeability of the reservoir and reduce the oil and gas field recovery after entering the formation, which is a problem that must be faced in oil and gas exploitation. [0003] Existing plugging technologies, such as bridging plugging, curable plugging and polymer plugging, have...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/035C09K8/32C09K8/44E21B33/13C08F220/18C08F222/20C08F220/06
CPCC09K8/035C09K8/32C09K8/426C09K8/44E21B33/13C08F220/1818C08F222/102C08F220/06
Inventor 孙金声邱加先白英睿吕开河郝惠军张洁刘凡刘敬平黄贤斌王金堂金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products