Ozone catalytic oxidation wastewater treatment device and treatment method

A technology of ozone catalytic oxidation and wastewater treatment, which is applied in the direction of oxidized water/sewage treatment, special compound water treatment, water/sewage treatment, etc., can solve the problems of low efficiency, high cost, large volume, etc., and achieve high mass transfer efficiency, The effect of reducing loss and increasing the contact area

Active Publication Date: 2021-03-09
江苏治水有数环保科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The object of the present invention is to solve the problems of low efficiency, poor effect, large volume and high cost of the existing ozone catalytic oxidation treatment sewage equipment, and provide an ozone catalytic oxidation wastewater treatment device, which improves the transmission between ozone, pollutants and catalysts. High quality and efficiency, promote catalytic oxidation and degradation of organic matter at gas, solid and liquid interfaces, improve ozone utilization rate and catalytic oxidation reaction rate, and at the same time effectively reduce equipment volume and reduce investment and operation costs

Method used

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  • Ozone catalytic oxidation wastewater treatment device and treatment method
  • Ozone catalytic oxidation wastewater treatment device and treatment method
  • Ozone catalytic oxidation wastewater treatment device and treatment method

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Embodiment 1

[0046] In order to make the present invention clearer, a kind of ozone catalytic oxidation wastewater treatment device and treatment method of the present invention will be further described below in conjunction with the accompanying drawings. The specific embodiments described here are only used to explain the present invention and are not intended to limit the present invention.

[0047] Such as figure 1 Shown, a kind of ozone catalytic oxidation wastewater treatment device is characterized in that:

[0048] Including pure oxygen source bin, ozone generator and membrane element reactor connected in sequence, a rotameter is set between the pure oxygen source bin and the ozone generator, and an electronic flowmeter is set between the ozone generator and the membrane element reactor There is a first ball valve and a second ball valve between the electronic flow meter and the pressure sensor. A membrane module for sewage treatment is installed in the membrane element reactor, an...

Embodiment 2

[0062] For the PTFE hollow fiber membrane coated by the method of the present invention, the mass ratio of the effective components of the catalyst / promoter / adsorbent is Cu: Co: hydroxyl carbon nanotubes = 6: 3: 1, and the effective length of the membrane filament is 40cm. The packing density is 15%, and it is applied in the oil extraction wastewater treatment process that contains emulsified oil that is the main pollutant in the presence of surfactant in Example 2. The influent COD content is 800 ~ 840mg / L, and the SS is 232mg / L. TDS is 1.629g / L, pH is 7.95~8.59, and the dosage of ozone is 16.35 mg / min / m 2 .

[0063] Among them, the membrane element reactor is also filled with a commercial aluminum-based catalyst bed equivalent to 60% of the total volume of the reactor. The hydraulic retention time HRT is set to 1h. Such as Figure 4 Shown is the change graph of COD removal curve of product water with adsorption, catalytic membrane only and catalytic membrane plus catalyti...

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Abstract

The invention relates to an ozone catalytic oxidation wastewater treatment device which comprises a pure oxygen source bin, a rotor flow meter, an ozone generator, an electronic flow meter, a pressuresensor and a membrane element reactor which are connected in sequence; a first ball valve and a second ball valve are arranged between the electronic flow meter and the pressure sensor; and a membrane assembly is arranged in the membrane element reactor. The lower part of the membrane element reactor is connected with a wastewater pool through a peristaltic pump, the upper part of the membrane element reactor is provided with a sampling detection port and an ozone degradation outlet, and the ozone degradation outlet is provided with a third ball valve; and the membrane module takes a fluorine-containing hollow fiber membrane as a carrier, and the surface of the membrane module is coated with an ozone catalyst, a cocatalyst, an adsorbent and a blending binder. The device has the advantagesthat the mass transfer efficiency among ozone, pollutants and the catalyst is improved, the ozone utilization rate and the catalytic oxidation reaction rate are increased, the equipment size is effectively reduced, and the investment and operation cost is reduced.

Description

technical field [0001] The invention relates to the technical field of advanced oxidation water treatment equipment, in particular to an ozone catalytic oxidation wastewater treatment device and treatment method. Background technique [0002] my country has long faced the problems of sewage disposal, recycling, and standard discharge from a large number of petrochemical, papermaking, printing and dyeing, coking, and pesticide enterprises. This type of wastewater generally has complex pollutant components, high organic concentration, high salinity components and Difficult to biodegrade and so on. The traditional physicochemical and microbial water treatment processes are only suitable for the treatment of easily degradable organic pollutants, but the treatment methods for refractory organic substances are not mature. [0003] Advanced oxidation technology, as a chemical oxidation water treatment technology, such as Fenton, Fenton-like and micro-electrolysis, is often used to ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/78C02F1/72C02F1/28B01J23/755B01J23/75C02F101/34
CPCC02F1/725C02F1/78C02F1/283C02F1/281B01J23/755B01J23/75C02F2305/023C02F2101/34C02F2209/08C02F2201/782
Inventor 郭毅
Owner 江苏治水有数环保科技有限公司
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