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Modified porous copper-nickel alloy plate and preparation method and application thereof

A porous copper and nickel alloy technology, applied in the field of materials, can solve the problems of large equipment loss, complex supporting devices, low efficiency, etc., achieve high degradation rate and degradation efficiency, improve catalytic degradation effect, and improve degradation treatment effect

Active Publication Date: 2021-03-19
FOSHAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the prior art, methods such as adsorption, combustion and catalytic degradation are generally used to degrade VOCs; among them, the adsorption method will produce certain hazardous waste; the combustion method is only suitable for processing high-concentration VOCs, and the scope of application Narrow and large equipment loss; while catalytic degradation methods, including photocatalytic degradation methods, do not produce hazardous waste and are suitable for treating high-concentration and low-concentration VOCs, but their cost is high and efficiency is low, and additional energy supply devices are required. The device is complex, and it is difficult to popularize industrialization; in addition, the catalytic materials in the prior art are basically granules or powders, which cannot cope with large-scale processing and cannot be widely used in industry
These defects greatly limit the development of catalytic degradation methods

Method used

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  • Modified porous copper-nickel alloy plate and preparation method and application thereof
  • Modified porous copper-nickel alloy plate and preparation method and application thereof
  • Modified porous copper-nickel alloy plate and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A preparation method of a modified porous copper-nickel alloy plate, comprising the following steps:

[0038]Step 1, mix polysulfone, pyrrolidone (pvp), copper powder (particle size 1000 μm), nickel powder (particle size 500nm) and N-methylpyrrolidone (NMP) to form a metal powder slurry with a certain viscosity, wherein, in In the metal powder slurry, the mass percent of copper powder is 63%, the mass percent of nickel powder is 5%, the mass percent of polysulfone is 5.12%, the mass percent of described viscosity regulator is 1.45%, the mass percent of described organic solvent The percentage is 25.43%; then put the metal powder slurry in a vacuum drying oven to vacuum for 4 hours to remove the air bubbles in the metal powder slurry, and then scrape the metal powder slurry on the glass plate, the thickness is controlled between 0.2 ~ 2mm , and then quickly immersed in water for 8 hours to prepare the precursor of the porous copper-nickel alloy plate. Its electron micros...

Embodiment 2

[0043] Change the heating temperature of Step 3 in Example 1 to 500°C, and follow the same steps and conditions as in Example 1 to prepare a porous copper-nickel alloy plate with amorphous carbon grown on the surface in situ as Experiment Group 1;

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PUM

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Abstract

The invention discloses a modified porous copper-nickel alloy plate and a preparation method and application thereof. The preparation method of the modified porous copper-nickel alloy plate comprisesthe following steps: uniformly mixing raw materials comprising a polymer binder, a viscosity regulator, copper powder, nickel powder and an organic solvent, coating a carrier plate with the obtained mixture, and immersing the carrier plate in a soaking solution which is water or a mixed solution of water and ethanol, then sequentially placing the prepared porous copper-nickel alloy plate precursorin an oxygen or air atmosphere and a hydrogen or carbon monoxide atmosphere to be heated, and finally placing the prepared porous copper-nickel alloy plate in a carbon source gas atmosphere to be heated. The novel catalytic material provided by the invention is simple to prepare and low in industrial popularization difficulty, the degradation rate and the degradation efficiency are greatly improved when the novel catalytic material is used for VOCs treatment, an additional energy supply device is not needed during application, and in addition, a device matched with the modified porous copper-nickel alloy plate is simple in structure and convenient to use. The application prospect of the catalytic degradation method is greatly expanded.

Description

technical field [0001] The invention relates to the field of materials, in particular to a modified porous copper-nickel alloy plate and its preparation method and application. Background technique [0002] VOCs refer to a series of volatile organic compounds. Due to the continuous enrichment of human daily life and the continuous development of industrialization, the emission of VOCs in domestic waste gas and industrial waste gas is also increasing. VOCs can cause certain damage to the human body. In mild cases, they can cause inflammation and pain in the eyes, nose, and throat, making people feel sick and dizzy. In severe cases, they can increase the risk of cancer, especially lung and liver cancer. [0003] In the prior art, methods such as adsorption, combustion and catalytic degradation are generally used to degrade VOCs; among them, the adsorption method will produce certain hazardous waste; the combustion method is only suitable for processing high-concentration VOCs,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/755B01J21/18B01J35/10B01J37/02B01J37/14B01J37/18B01J37/08B01D53/86B01D53/44B22F3/11B22F3/24C23C16/26
CPCB01J23/755B01J21/185B01J37/0219B01J37/14B01J37/18B01J37/08B01D53/8687B22F3/1143B22F3/24C23C16/26B01D2257/708B22F2003/242B01J35/657Y02A50/20
Inventor 刘德飞陈忻何梓鹏杨希贤王运磊
Owner FOSHAN UNIVERSITY
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