Cotton fiber-based durable antibacterial fiber fabric and preparation method thereof

A technology of antibacterial fiber and cotton fiber, which is applied in the field of antibacterial cotton fiber, can solve the problems of easy wash-off, long-lasting antibacterial effect, and reduced fabric air permeability, so as to reduce heterogeneous expansion, good wearing comfort, and improve dimensional stability sexual effect

Pending Publication Date: 2021-11-26
陈小琴
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in a humid environment, cotton fabrics are prone to mildew and deterioration and absorb bacteria, which are corroded by bacteria and cause health problems. Moreover, the sweat from the human body and the shed sebum provide rich nutrients for the reproduction of fungi, resulting in the growth of bacteria. Breeding will not only cause cross-infection and spread diseases, produce peculiar smell, cause health problems, but also easily damage fibers. The bonds are disassembled and new hydrogen bonds are generated. When the external force is eliminated, creep will occur. When the external force is too large and the acting time is too long, it is easy to wrinkle and deform. Therefore, it is necessary to carry out antibacterial and anti-wrinkle finishing on cotton fabrics. , the development of antibacterial modified anti-wrinkle cotton fibers has excellent prospects
[0003] Generally speaking, textile antibacterial agents are divided into inorganic antibacterial agents, organic antibacterial agents and natural antibacterial agents according to the source of materials. At present, natural antibacterial agents have poor antibacterial effects, and organic antibacterial agents such as quaternary ammonium salt type polymer antibacterial agents are

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Cotton fiber-based durable antibacterial fiber fabric and preparation method thereof
  • Cotton fiber-based durable antibacterial fiber fabric and preparation method thereof
  • Cotton fiber-based durable antibacterial fiber fabric and preparation method thereof

Examples

Experimental program
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Effect test

Example Embodiment

[0025] Example 1

[0026] A low-end antibacterial fiber fabric based on cotton fiber, the raw material comprising: 10 kg of cotton fibers, cerium nitrate 60 kg, 2-acrylamide-2-methylpropulfonic acid 1 kg, a weight average molecular weight of 5073, a terminal amino super branched polymer 4kg, oxide oxide 2kg.

[0027] The above-described cotton fiber-based persistent antibacterial fiber fabric preparation method includes the following steps:

[0028] S1, the cotton fibers soak the cotton fiber to a concentration of 2 mol / L sodium hydroxide solution, stirred at 80 ° C for 2 h, filtered, washed 2 times with ethanol, 50 ° C drying;

[0029] Soak to a concentration of 0.1 mol / l Nitrate, the ultrasonic treatment under nitrogen protection for 2 h, and the ultrasonic power is 400 W, 2-acrylamide-2-methylpropulfonic acid continues to ultrasonic 2h, and take out the cotton fabric after using ethanol Wash 2 times, drying to obtain preprocessing cotton fibers;

[0030] S2, the end amino s...

Example Embodiment

[0032] Example 2

[0033] A durable antibacterial fiber fabric based on cotton fiber, including: cotton fibers 20kg, nitrate 4 kg, 2-acrylamide-2-methylpropulfonic acid 4 kg, a weight average molecular weight of 9930 end amino hyperanization polymers 2kg, oxide oxide 4kg.

[0034] The above-described cotton fiber-based persistent antibacterial fiber fabric preparation method includes the following steps:

[0035] S1, the cotton fiber soaked to a concentration of 1 mol / L sodium hydroxide solution, stirred at 100 ° C for 1 h, filtered, washed 4 times with ethanol, 40 ° C drying;

[0036] In addition to the concentration of 1 mol / L nitrate, oxygen treatment is 1 h, and the ultrasonic power is 500W, and 2-acrylamide-2-methylpropulfonic acid continues to ultrasonic 1 h, and remove the cotton fabric after washing 4 times, drying to get pre-treatment cotton fibers;

[0037] S2, the end amino super branched polymer is added to a water solution of 40% by weight, and the pretreatment co...

Example Embodiment

[0039] Example 3

[0040] A low-lasting antibacterial fiber fabric based on cotton fiber includes: cotton fiber 12kg, nitrate 48kg, 2-acrylamide-2-methylpropulfonic acid 2 kg, a weight average molecular weight of 6670 end amino hyperanization polymer 3.5kg, graphene 2.5kg.

[0041] The above-described cotton fiber-based persistent antibacterial fiber fabric preparation method includes the following steps:

[0042] S1, soaking cotton fibers into a solution of 1.7 mol / L sodium hydroxide, stirred at 85 ° C for 1.7 h, filtered, washed 3 times with ethanol, 43 ° C drying;

[0043] Soak to a concentration of 0.8 mol / L nitrate, the ultrasonic treatment was 1.3 h under nitrogen protection, and the ultrasonic power was 480W, and 2-acrylamide-2-methylpropulfonic acid continued to ultrasonic 1.4 h, remove the cotton fabric 3 times were washed with ethanol, dried to give preconditioning cotton fibers;

[0044] S2, the end amino super branched polymer is added to a water solution of 55% aque...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a cotton fiber-based durable antibacterial fiber fabric. The durable antibacterial fiber fabric is prepared from cotton fibers, ceric ammonium nitrate, an anion modifier, an amino-terminated hyperbranched polymer and graphene oxide. The invention discloses a preparation method of the cotton fiber-based durable antibacterial fiber fabric. The preparation method comprises the following steps of alkalizing the cotton fibers, soaking the cotton fibers in an ammonium ceric nitrate solution, performing ultrasonic treatment under the protection of nitrogen, adding the anion modifier, continuing ultrasonic treatment, taking out the cotton fibers, washing the cotton fibers, and drying the cotton fibers to obtain pretreated cotton fibers; adding the amino-terminated hyperbranched polymer into an ethanol water solution, performing uniform stirring, adding the pretreated cotton fibers into a mixture under the protection of nitrogen, performing stirring for 1-2 hours at 50-70 DEG C, performing washing, and performing drying in vacuum to obtain grafted cotton fibers; and adding the graphene oxide into dilute acid, performing uniform stirring, adding the grafted cotton fibers, performing stirring at 70-90 DEG C for 1-2 hours, taking out the cotton fibers, washing the cotton fibers, drying the cotton fibers, and performing spinning and weaving to obtain the cotton fiber-based durable antibacterial fiber fabric.

Description

technical field [0001] The invention relates to the technical field of antibacterial cotton fibers, in particular to a durable antibacterial fiber fabric based on cotton fibers and a preparation method thereof. Background technique [0002] Cotton fiber is an important textile fiber material. Its products are cheap, moisture-absorbing, breathable, comfortable, biodegradable, safe and environmentally friendly, and are favored by people. However, in a humid environment, cotton fabrics are prone to mildew and deterioration and absorb bacteria, which are corroded by bacteria and cause health problems. Moreover, the sweat from the human body and the shed sebum provide rich nutrients for the reproduction of fungi, resulting in the growth of bacteria. Breeding will not only cause cross-infection and spread diseases, produce peculiar smell, cause health problems, but also easily damage fibers. The bonds are disassembled and new hydrogen bonds are generated. When the external force ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M11/65D06M11/74D06M13/438D06M15/61D06M101/06
CPCD06M11/65D06M15/61D06M11/74D06M16/00D06M13/438D06M2101/06D06M2200/20
Inventor 陈小琴
Owner 陈小琴
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