Double-component aqueous epoxy coating

A water-based epoxy coating, two-component technology, used in epoxy resin coatings, coatings, latex paints, etc., can solve low chemical corrosion resistance and mechanical properties, product stability is not ideal, denuclearization pollution It can reduce the impact, facilitate migration and evaporation, and achieve the effect of excellent nuclear power performance.

Inactive Publication Date: 2006-10-18
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above-mentioned self-dispersing and curing epoxy resin must be dispersed in specially designed high-shear equipment, and in order to ensure the stability of the dispersion, it must be produced according to a specific reaction sequence, the production process is more complicated, and the product stability is not good. Too ideal; US Patent 4246148 describes a water-soluble amine-epoxy adduct prepared by reacting an epoxy resin with a polyamine and a capping agent containing a saturated Monoglycidyl ether of linear aliphatic monohydric alcohol mixture, which has 8 to 10 carbon atoms, also introduces an emulsifiable epoxy resin composition, which is prepared by an epoxy resin and a 40% non- An aqueous solution of ionic surfactant emulsifies it into an epoxy emulsion and is used as one component of a two-component coating, and uses the above-mentioned amine-epoxy adduct as another component to form a two-component environmentally friendly industrial anti-corrosion coating
Although this kind of coating has low VOC, good chemical corrosion resistance and mechanical properties, it still needs to be emulsified with surfactants, and has poor nuclear radiation resistance and poor denuclear pollution.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Example 1 Preparation of amine-terminated aqueous amine-epoxy adducts

[0033] 1. See Table 1 for the formula

[0034]

components

raw material name

Dosage

Amount added

Percentage(%)

Alkenyl polyamine

Diethylenetriamine

640

17.63

Polyepoxides

Single shrinkage of 8 to 10 carbon atoms

Glyceryl ether

280

7.72

Bisphenol A Diglycidyl

oil ether

Bisphenol A diglycidyl ether

(n=2, epoxy equivalent 500)

960

26.45

Acetic acid

Acetic acid

150

4.13

Co-solvent

Ethylene glycol monomethyl ether

700

19.28

Deionized water

Deionized water

900

24.79

[0035] Note: "percentage" refers to the percentage of the total amount added.

[0036] 2. Operation method

[0037] In the reactor equipped with stirring, heating equipment, nitrogen conduit, reflux condenser and thermometer, add 41...

Embodiment 2

[0038] Embodiment 2 Preparation of component B of waterborne epoxy coating

[0039] 1. See Table 2 for the formula

[0040]

components

raw material name

Dosage

Amount added

Percentage(%)

Bisphenol A Diglycidyl

oil ether

Bisphenol A diglycidyl ether

(n=0.13, epoxy equivalent 190)

920

82.11

Amine-terminated aqueous amine-

epoxy adduct

Example 1 Self-made

120

10.71

Polyphenols

Bisphenol A

80

7.14

catalyst

Triphenyl Phosphate

0.5

0.04

[0041] Note: The percentage refers to the percentage of the total amount added.

[0042] 2. Operation method

[0043] In the reaction flask equipped with stirring, heating system, reflux condenser and thermometer, add bisphenol A diglycidyl ether, amine-terminated water-based amine-epoxy adduct, bisphenol A, catalyst according to the formula, and stir While heating to 150°C, keep it...

Embodiment 3

[0044] Embodiment 3 Preparation of components A1 and A2 of two-component waterborne epoxy paint

[0045] 1. See Table 3 for the formula

[0046] component name

raw material name

Dosage

Component A1

Component A2

Amount added

%

Amount added

%

Amine-terminated aqueous

Amine-epoxy adducts

Example 1,

self made

34.5

34.5

42.5

42.5

paint

Titanium dioxide

16.5(A

type)

27.5

28.5(R

type)

28.5

Zinc phosphate

11.0

/

filler

Precipitated Barium Sulfate

9.0

9.0

/

/

Flash corrosion inhibitor

Alkyl imidazole

0.5

0.50

/

/

Defoamer

BYK-019

0.5

0.50

0.5

0.5

Wetting and dispersing agent

BYK-348

0.5

0.50

0.5

0.5

Deionized water

24.0

24.0

24.5

24.5

Co...

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Abstract

The invention relates to a two-component water-based epoxy coating, component A: 30-50% of amine-terminated water-based amine-epoxy adduct; 20-40% of pigment; 0-15% of filler; flash corrosion inhibitor 0 ~1%; defoamer 0.1~1%; wetting and dispersing agent 0.1~1%; deionized water 15~30%; cosolvent 1~8%; component B: diglycidyl ether of bisphenol A 70~ 85%; amine-terminated water-based amine-epoxy adduct 5-12%; polyphenol 5-10%; catalyst 0.01-1%; component A and component B are mixed in a weight ratio of 2.0-3.33:1 before use The above-mentioned amine-terminated water-based amine-epoxy adduct is composed of olefin-based polyamine 15-20%, polyepoxy compound 5-12%; bisphenol A diglycidyl ether 2-30%, acetic acid 1-8% , 15-20% of co-solvent and 20-30% of deionized water are prepared by stepwise polymerization.

Description

technical field [0001] The invention relates to a two-component waterborne epoxy paint, which is especially suitable for the concrete surface and steel structure of nuclear power plants. Background technique [0002] At present, the coatings used on the concrete surface and steel structure surface of domestic nuclear power plants are all solvent-based. Due to growing concerns about the adverse effects of organic solvents on the environment and human health, many industries, including the paint and coatings industry, are required to reduce the volatile organic compound (VOC) content of their products. There are many methods of VOC reduction in the coatings industry, but undoubtedly the most important method is the use of water-based (WB) coatings, in which water is used in whole or in part instead of the viscosity previously used to reduce the viscosity of paint formulations to the extent necessary for coating. of organic solvents. Of course, since water is not a solvent fo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/02C09D5/02
Inventor 王留方赵宝华张睿倪爱兵
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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