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Preparation of rare earth contained hydrocracking catalyst

A technology for hydrocracking and catalyst, which is applied in the direction of hydrocarbon oil cracking, petroleum industry, etc., to achieve the effect of simple operation method

Inactive Publication Date: 2003-03-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Based on the existing technology, the introduction of rare earths in rare earth-containing hydrocracking catalysts is generally achieved by exchanging the framework cations (such as sodium ions) of molecular sieves with rare earth ions. The problem is that the exchange of rare earth ions is affected by zeolite ions. Due to the limitation of balance, more than two rare earth ion exchange steps are often required to make the catalyst obtain the desired higher rare earth content

Method used

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preparation example Construction

[0014] The preparation method of the rare earth-containing hydrocracking catalyst provided by the present invention includes: mixing molecular sieves, alumina precursors and / or amorphous silicon aluminum, and rare earth salts according to the required ratio, and adding a peptizer when necessary Methods Kneading or extruding to form, then drying and roasting to obtain a shaped catalyst carrier; the obtained shaped catalyst carrier is loaded with a required amount of hydrogenation metal active components according to a conventional method.

[0015] In a specific embodiment of the present invention, the alumina precursor refers to boehmite, pseudoboehmite, diaspore, gibbsite or bayolite. The amorphous silica-alumina SiO 2 / Al 2 o 3 The molar ratio is 2-10.

[0016] The rare earths mentioned in the method provided by the present invention are well known to those skilled in the art, and include, for example, lanthanum, cerium, praseodymium, neodymium, samarium, yttrium, etc., or...

Embodiment 1

[0022] Preparation of acid-containing rare earth mixed solution: take RECl 3 (the percentage by weight of each composition in its rare earth total amount is: Ce 2 o 3 63%, La 2 o 3 25%, PR 6 o 11 2.1%, Nd 2 o 3 5.0%, Sm 2 o 3 0.5%, other 4.4%, the same below) 8.50g, mix with concentrated nitric acid 3ml, add water to 80ml and mix evenly, set aside.

[0023] Get amorphous silicon aluminum (production of Lanzhou Refinery Catalyst Factory, SiO 2 / Al 2 o 3 The molar ratio is 4.5, the same below) 60g (dry basis), SB alumina powder (commercial product produced in Germany, trade name is SB) 20g (dry basis weight) and molecular sieve (production of Lanzhou Refinery Catalyst Factory, unit cell constant is 2.439 nanometers , with a crystallinity of 78.9%, Na 2 O content is 0.68% by weight, hereinafter the same) 20g (dry basis) are mixed evenly, add above-mentioned acid-containing mixed rare earth liquid, knead and extrude to obtain a diameter of 2.2 mm cylindrical bar,...

Embodiment 2

[0025]Prepare the catalyst support 100g (dry basis weight) of molding and roasting according to embodiment 1, add to 1M (NH 4 ) 2 SO 4 In 800ml of the solution, place it at 90°C for 2 hours (shake it by hand from time to time), pour off the solution and add it again (NH 4 ) 2 SO 4 800ml of the solution was treated like this for 3 times, dried at 120°C for 3 hours, and baked at 350°C for 2 hours. Take nickel nitrate 17g and add to 30ml containing WO 3 In 120g / ml ammonium metatungstate solution, add water to 80ml, stir evenly, prepare mixed metal impregnation solution, place the prepared catalyst carrier in the impregnation solution, immerse for 2 hours, dry and roast at 450°C After 2 hours, a hydrocracking catalyst was obtained, denoted as B.

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Abstract

The preparation method of hydrocracking catalyst containing rare earth includes the following steps: mixing molecular sieve, alumina precursor and / or amorphous silica-alumina and rare earth salt according to the required propertion, and is necessary, adding peptizator, kneading or extruding-forming, drying and roasting to obtain formed catalyst carrier, then loading the hydrogenated metal active component on the formed catalyst carrier. The adoption of said invention method can make the rare earth content of catalyst reach to the required level by one-step operation, at the same time its operation is simple.

Description

technical field [0001] The invention relates to a preparation method of a petroleum hydrocarbon hydrocracking catalyst. technical background [0002] Hydrocracking is a conversion process in which hydrocarbon molecules and hydrogen undergo cracking and hydrogenation reactions on the surface of a catalyst under a relatively high hydrogen partial pressure to generate smaller molecules. The main raw material processed by hydrocracking is heavy distillate oil, including catalytic cracking cycle oil and coking distillate oil, etc. The products are mainly high-quality oil products, especially the production of high-quality aviation kerosene and low freezing point diesel oil. Hydrocracking has the characteristics of strong adaptability to raw materials, and various inferior raw materials can be used, such as coking distillate oil, catalytic cracking cycle oil, etc., and the yield of light oil products is high, the quality is good, and the operation flexibility is large. Different t...

Claims

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Application Information

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IPC IPC(8): C10G47/02
Inventor 董松涛李宣文李大东石亚华聂红史建文
Owner CHINA PETROLEUM & CHEM CORP
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