Functional polymer with supported pressure-sensitive luminophore, and pressure-sensitive paint and pressure-sensitive element using same

Abstract

An oxygen-quenching luminophore constituting part of a pressure-sensitive luminophore is directly bonded by a covalent bond to an organic polymer compound having trimethylsilyl groups, so the luminophore molecules are retained in the polymer and free aggregation is inhibited when the organic solvent is evaporated. It is therefore possible to prevent light response from being reduced by the aggregation of the luminophore molecules during evaporation of the organic solvent, which is a drawback of forming films from conventional mixed-type pressure-sensitive paints. A thin-film sensor with uniform characteristics can be formed by spraying or application from a pressure-sensitive paint obtained by mixing a functional polymer with a solvent. In addition, a coating solution that has high reproducibility and is suitable for spraying or application can be obtained merely by dissolving the functional polymer as a single component in a suitable solvent. It is possible to obtain a functional polymer, a pressure-sensitive paint, and a pressure-sensitive element in which a reduction in light response due to luminophore aggregation can be prevented, and a thin sensor film having uniform characteristics can be formed, even when the organic solvent has evaporated.

Description

1. Field of the InventionThe present invention relates to a functional polymer with a supported pressure-sensitive luminophore that has high pressure sensitivity and rapid response, such as the one that can be used, for example, in sensors for the optical sensing of oxygen; and to a pressure-sensitive paint and pressure-sensitive element featuring the same.2. Description of the Related ArtIn conventional practice, pressure-sensitive paints known as oxygen sensors are coating materials obtained by dissolving light-excitable substances having oxygen quenching properties in polyvinyl chloride, polystyrene, and other oxygen-transmitting resins. Oxygen sensors are produced by applying such paints to matrices, but the extent to which the light-excitable substances and oxygen are brought into contact with each other in such sensors depends on the phenomenon of oxygen diffusion in the resins, and the sensors are thus disadvantageous in the sense that their oxygen sensitivity depends on the ...

AI Technical Summary

Benefits of technology

The pressure-sensitive luminophore containing a sensor portion that has oxygen pressure sensing functionality as oxygen quenching properties in the functional polymer with a supported pressure-sensitive luminophore in accordance with the present invention is present in a covalently bonded state in the acetylene derivative, so the luminophore molecules are retained as part of the acetylene derivative even when the organic solvent evaporates, and free aggregation is inhibited. It is thus possible to prevent response from being reduced by the aggregation of luminophore molecules during the evaporation of organic solvents, which is a drawback of forming films from conventional mixed-type pressure-sensitive paints.

Trimethyl-1-silyl propyne can be copolymerized with the acetylene derivative in this functional polymer with a supported pressure-sensitive luminophore. Trimethyl-1-silyl propyne is used as a material for preventing steric hindrance in polymer compounds containing this acetylene derivative.

A pressure-sensitive paint can be obtained by admixing the aforementioned functional polymer with a supported pressure-sensitive luminophore into a solvent. Specifically, not only can production be facilitated, but high function reproducibility can also be achieved because the product can be applied and formed into a film using a solution that is merely dissolved in a solvent without the addition of binders or other materials. Storage and transport are simplified by allowing the product to stand as a pressure-sensitive paint, and the pressure-sensitive paint can also be used as needed in the form of a thin layer on a substrate by spraying the paint with a spray, applying the paint with a brush, or employing various other means.

The functional polymer with a supported pressure-sensitive luminophore newly synthesized in accordance with the present invention contains a covalently bonded pressure-sensitive luminophore and polymer, making it possible to prevent the luminophore from aggregating during the evaporation of the organic solvent, and to use the polymer in the formation of a uniform pressure sensor film that has high photoresponsivity. The functional polymer according to the present invention can be merely mixed with a solvent without any binders, stored and transported in the form of pressure-sensitive paint, and used at any time for application and film forming. This functional polymer has a single component as a pressure-sensitive paint, and is thus a paint that can be readily applied by spray coating, dipping, casting onto a substrate, or another method. It is also possible to use the pressure-sensitive paint as a film formed on a substrate by spraying or application, and to obtain a pressure sensor of uniform thickness. The distribution of pressure on a wing surface (specimen) can be measured with high sensitivity and resolution even in an ultralow-pressure environment by employing the pressure sensor thus obtained in cryogenic wind tunnel tests or impact wind tunnel tests.

Problems solved by technology

Oxygen sensors are produced by applying such paints to matrices, but the extent to which the light-excitable substances and oxygen are brought into contact with each other in such sensors depends on the phenomenon of oxygen diffusion in the resins, and the sensors are thus disadvantageous in the sense that their oxygen sensitivity depends on the temperature and that the temporal response in relation to pressure variations is inadequate.

In addition, the oxygen permeability of such resins decreases in low-temperature environments, making the sensors much less sensitive and unsuitable for use in measuring the ultralow-pressure on the surfaces of objects or detecting the traces of oxygen in the high-altitude environment; for use in measuring the distribution of pressure on the surface of a specimen in a cryogenic wind tunnel; or the like.

Although the sensor produced by this method is an exceptionally good product in the sense that high oxygen detection sensitivity can be ensured and the reduction in sensitivity at low temperatures is minimal, problems still remain because there are limits as to the materials suitable for forming porous films as sensor matrices, it is impossible to say which specimens would be better for conducting operations in which light-excitable substances are adsorbed on the porous films, and the like.

However, even these high-performance pressure-sensitive paints still have drawbacks that need to be overcome, such as nonuniform characteristics of the thin films formed by application, and a reduction in photoresponsivity due to luminophore aggregation during the evaporation of organic solvents.

It is thus possible to prevent response from being reduced by the aggregation of luminophore molecules during the evaporation of organic solvents, which is a drawback of forming films from conventional mixed-type pressure-sensitive paints.

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