The invention discloses a gas distributing mechanism for an engine and a car with the gas distributing mechanism. The gas distributing mechanism comprises a valve mechanism, a rocker arm assembly, a first roller, a second roller, a cam shaft, a bearing structure, a phase adjusting mechanism, and a third roller or a limiting pin. A driving molded surface is constructed at the bottom of the rocker arm assembly and is suitable for driving a valve to move, the first roller and the second roller can be arranged on the rocker arm assembly in a pivoted mode, the cam shaft comprises an inner shaft and an outer shaft, the inner shaft and the outer shaft are coaxially arranged, an inner shaft cam and an outer shaft cam which rotate along with the corresponding shafts are arranged on the inner shaft and the outer shaft respectively, the outer shaft cam abuts against the first roller, the inner shaft cam abuts against the second roller, the phase adjusting mechanism is used for adjusting the relative phase of the inner shaft and the outer shaft, a circular-arc curved surface or a sliding groove is formed in the bearing structure, the third roller can be tightly attached to the circular-arc curved surface in a rolling mode, and the limiting pin can be arranged in the sliding groove in a sliding and matching mode. The gas distributing mechanism can achieve secondary opening of the valve, the continuous opening time of the valve can be prolonged at the same time, the structure is simple and compact, and the influence on the height of the engine is small.