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Technology for solving hydrogen sulphide corrosion of pipe drilling tool and pump during oil gas dislodging

A technology for oil and gas exploitation and hydrogen sulfide, applied in metal material coating process, liquid chemical plating, coating, etc., can solve problems such as lack of mature and effective solutions, internal corrosion of tubing and casing, and difficulty in salvaging pipe drilling tools. , to achieve the effect of eliminating personal casualties, low consumption and low investment

Inactive Publication Date: 2007-08-08
李天忠
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] After entering 2006, the production period of major oil and gas fields in China has been more than 30 years. The continuous production of oil fields has deteriorating well conditions. Especially in the middle and late stages, the recovery rate of oil wells and oil-gas mixed wells has become more difficult. In order to stabilize and increase oil production The amount of oil well reinjection is inevitable, and the oil and gas wells in the oil production area contain different levels of H 2 S, CO 2 , oil and gas wells containing sulfur and high salinity are complex in composition, and the various special tubular drilling tool pumps, tubing and casing used are all in this harsh environment. Oil well corrosion, internal corrosion of tubing and casing is especially Seriously, especially in some old oil fields that have been continuously exploited for many years, the proportion of discarded pipes and tools directly attributable to corrosion accounts for more than 60%. In some areas with high oil and gas content, oil wells are shut down due to corrosion; it is difficult to salvage the pipes and drilling tools that have fallen into the well. , in severe cases, it will cause the oil well to be scrapped or lead to serious pollution and vicious accidents
[0005] Market research shows that there is no mature and effective solution to the corrosion of pipe drilling tools and pumps caused by hydrogen sulfide in the domestic oil and gas exploitation industry; most of the measures to reduce the corrosion rate in development and production are the addition of compound corrosion inhibitors, dehydration, and internal protection. Anti-corrosion layer lining, etc. to alleviate the corrosion of this medium

Method used

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Embodiment Construction

[0015] The present invention is realized in this way. Pure water, stannous chloride, nickel sulfate, sodium hypophosphite, boric acid, sodium saccharin, etc. are weighed in proportion, put into a dissolver with a stirrer and stirred, and after all are dissolved ready to use. When plating is required, heat the plating solution to 50-80°C, and determine the plating time according to the required thickness. The materials therein are pure water: stannous chloride: nickel sulfate: sodium hypophosphite: boric acid: sodium saccharin: lead ion=90:3:3:2:1.9:0.3:0.02.

[0016] Technical process steps:

[0017] 1. Early pretreatment process: quench and temper the metal workpiece before plating to reduce or eliminate internal stress, then degrease and derust the workpiece, and use mechanical sandblasting to remove burrs and oxide layers on the surface , Dirt layer, cleaning, drying, to achieve a flat, smooth and clean surface of the workpiece substrate.

[0018] 2. Plating treatment pr...

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PUM

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Abstract

The invention discloses an alloy plating liquid on the metal piece, which comprises the following parts: pure water, tin chloride, nickel sulphate, sodium hypophosphite, boric acid, saccharin sodium and lead ion with molar rate at 90:3:3:2:1.9:0.3:0.02, wherein the plating liquid is heat to 50-80 deg.c with plating time affirmed according to the needed thickness.

Description

Technical field: [0001] The invention belongs to the application fields of oil and gas field exploitation and equipment production and manufacturing, and relates to the corrosion of hydrogen sulfide on tubular drilling tools and pumps in oil and gas exploitation, specifically an alloy plating solution with anti-hydrogen sulfide corrosion performance and a surface treatment technology. Background technique: [0002] Hydrogen sulfide (H 2 S) is a colorless gas with an odor of rotten eggs. The molecular weight is 34.08; the relative density is 1.1906; it is easily soluble in water, methanol, petroleum solvent and crude oil, and it is compatible with CO in oil and gas exploitation 2 and O 2 In comparison, hydrogen sulfide has the highest solubility in water, and it is also a strong hydrogen permeable medium. It shows strong corrosion damage to steel in many corrosive media, and is the main corrosive gas in the oil and gas industry. . Once hydrogen sulfide dissolves in water,...

Claims

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Application Information

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IPC IPC(8): C23C18/50C23C18/18
Inventor 李天忠
Owner 李天忠
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