Method for preparing electromagnetic shielding light graphite based nanometer magnetic metal composite material

A metal composite material and nano-magnetic technology, applied in the direction of magnetic/electric field shielding, shielding, electrical components, etc., can solve problems such as damage to physical and mental health, difficulty in controlling the content and type of magnetic substances, and leakage of electromagnetic information confidentiality, etc., to achieve good electrical conductivity Sexual and magnetic properties, improved electromagnetic shielding performance, excellent magnetic and electrical conductivity effects

Inactive Publication Date: 2008-05-14
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

2. Electromagnetic information will leak confidentiality, which will seriously affect the interests of enterprises and national political, economic, and military security issues; it is reported that equipment in a certain country can receive and display information on ordinary computers 1,000 meters away
3. Electromagnetic environmental pollution is the fourth major public hazard besides the three industrial wastes, causing certain harm to the human body and organisms; existing evidence shows that the human body is exposed to electromagnetic wave radiation for a long time, which will seriously damage the physical and mental health and affect the normal life order
This method is not easy to control the content and type of magnetic substances in the material, the electromagnetic shielding effect is general, and the scope of application is limited
Vovchenko et al. (Journal of Physics and Chemistry of Solids 65 (2004) 171-175) introduced a method for loading nano-metal particles on expanded graphite substrates, but before loading, the expanded graphite needs to be treated with acid. The method is more complicated and practical. Sexual restriction

Method used

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  • Method for preparing electromagnetic shielding light graphite based nanometer magnetic metal composite material
  • Method for preparing electromagnetic shielding light graphite based nanometer magnetic metal composite material
  • Method for preparing electromagnetic shielding light graphite based nanometer magnetic metal composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] (1) Dissolve 21.23g of nickel nitrate in 250ml of ethanol, add 10g of expanded graphite, stir evenly, evaporate the solvent in a water bath, and dry the sample.

[0031] (2) The obtained solid mixture is treated in a mixed gas of hydrogen and nitrogen (hydrogen volume fraction 1%) at 300°C for 10 hours, and the sample is passivated with ordinary nitrogen with an oxygen content of 0.1% (volume fraction) and cooled to room temperature. The composite material of graphite and nano metallic nickel is obtained, wherein the mass content of metallic nickel is 30%.

[0032] (3) The composite material can be pressed into various shapes required. In this embodiment, it is pressed into a sheet-like sample with a thickness of 0.5 mm.

Embodiment 2

[0034] (1) Dissolve 10.03g of cobalt chloride in 150ml of acetone, add 10g of expanded graphite, stir evenly, evaporate the solvent in a water bath, and dry the sample.

[0035] (2) The obtained solid mixture was treated in a carbon monoxide atmosphere at 400°C for 6 hours, and the sample was passivated with ordinary nitrogen with an oxygen content of 1% (volume fraction) and cooled to room temperature to obtain a composite material of graphite and nano-metallic nickel. The mass content of metallic nickel is 20%.

[0036] (3) The composite material can be pressed into various shapes required, and is pressed into a sheet in this embodiment.

Embodiment 3

[0038] (1) Dissolve 27.8 g of ferric nitrate in 300 ml of ether, add 10 g of expanded graphite, stir evenly, evaporate the solvent in a water bath, and dry the sample.

[0039] (2) The obtained solid mixture was treated at 600°C for 8 hours in a hydrogen and nitrogen mixed gas (V / V=1 / 1) atmosphere, and the sample was passivated with ordinary nitrogen with an oxygen content of 0.5% (volume fraction) and cooled to At room temperature, a composite material of graphite and nano-metallic iron is obtained, in which the mass content of metallic iron is 40%.

[0040] (3) The composite material can be pressed into various shapes required, and is pressed into a sheet in this embodiment.

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Abstract

The invention relates to a preparation method of a lightweight graphite-based nano-magnetic metal composite material used for electromagnetic shielding, which belongs to the related field of electromagnetic shielding materials; the precursor solution of expanded graphite and magnetic metal is mixed and stirred evenly, and dried after evaporating the solvent. The obtained mixture is treated in a reducing atmosphere at 300°C-1000°C, passivated with ordinary nitrogen and cooled to room temperature to obtain a composite material of expanded graphite and magnetic nanometer metal, and the relative content of the two can be adjusted. The composite material is light in texture, has excellent electromagnetic properties, and can be pressed into various shapes required. The material has excellent electromagnetic shielding performance in the range of 300kHz-1.5GHz, reaching 70-105dB, and the addition of magnetic metal improves the electromagnetic shielding performance of the expanded graphite in the low-frequency band. The method is simple and efficient, suitable for mass preparation, and the obtained product is expected to be applied in aerospace, military, electronic and electrical products.

Description

1. Technical Field: [0001] The invention relates to a preparation method of a lightweight graphite-based nano magnetic metal composite material used for electromagnetic shielding. 2. Background technology: [0002] With the rapid development of the electronics, electrical, communications and information industries and the widespread use of computers and mobile phones in daily life, there is more and more serious electromagnetic radiation in the human living environment. The study found that electromagnetic radiation not only interferes with electronic devices, but also harms the human body. In the past two decades, the increase in the incidence of cancer, leukemia and other diseases has a certain relationship with the increase in electromagnetic radiation. Electromagnetic wave pollution has become an increasingly important issue. Serious social problems. [0003] Electromagnetic radiation hazards mainly come from three aspects: 1. Electromagnetic interference (EMI), which mainly ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H05K9/00G12B17/02
Inventor 沈俭一黄玉安徐铮黄润生唐涛
Owner NANJING UNIV
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