Preparation method of self-adhesive acrylic acid paint for coating
A manufacturing method and self-adhesive technology, applied in the coating and other directions, can solve the problems of high cost, no longer able to be used for printing and composite use, and increased cost.
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Embodiment 1
[0031] Put 10kg deionized water, 300g sodium polystyrene sulfonate, 360g methacrylic acid, 100g hydroxypropyl acrylate, 4950g methyl methacrylate and 4540g methyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, the stirring speed is controlled Prepare monomer pre-emulsion A at 100 rpm; add 25kg of deionized water to the polymerization kettle, start stirring at 150 rpm, heat up to 75°C under nitrogen protection, and quickly add 4g of potassium persulfate After 5 minutes, add 5% monomer pre-emulsion A1.01kg, the nucleation polymerization reaction starts, the temperature of the material rises automatically, and the material in the kettle changes from milky white to translucent and bluish; when the temperature in the kettle tends to be stable Finally, keep the temperature at 82°C for half an hour, and start to add the remaining monomer pre-emulsion A, 80g polyvinyl alcohol dispersant and 60g oxidized initiator potassium persulfate dropwise at the same time, and ...
Embodiment 2
[0033] Put 18kg deionized water, 380g sodium vinyl sulfonate, 450g acrylic acid, 150g hydroxypropyl acrylate, 5100g methyl methacrylate and 4800g ethyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, and control the stirring speed at 200 rpm Minutes into the monomer pre-emulsion A; in the polymerization kettle, first add 25kg of deionized water, start stirring, the stirring speed is 120 rpm, the temperature is raised to 80°C under the protection of nitrogen gas, and 2.8g of sodium persulfate is quickly added, and the After 5 minutes, add 5% monomer pre-emulsion liquid A1.43kg, nucleation polymerization promptly begins, and material temperature rises automatically, and material in the kettle becomes translucent pan-blue light by milky white; After the temperature in the kettle tends to be steady, Keep the temperature at 84°C for half an hour, start to add the remaining monomer pre-emulsion A, 80g sodium polyacrylate dispersant and 63g oxidized initiator sodiu...
Embodiment 3
[0035]Put 30kg deionized water, 296g sodium vinyl sulfonate, 378g acrylic acid, 250g hydroxyethyl acrylate, 7500g methyl methacrylate and 6800g n-butyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, and the stirring speed is controlled at 150 rpm Configured as monomer pre-emulsion A per minute; in the polymerization kettle, first add 32 kg of deionized water, start stirring, the stirring speed is 130 rpm, and the temperature is raised to 78 ° C under nitrogen protection, and 5 g of potassium persulfate is quickly added. After 5 minutes, add 5% monomer pre-emulsion A2.21kg, the nucleation polymerization reaction starts, the temperature of the material rises automatically, and the material in the kettle changes from milky white to translucent blue light; after the temperature in the kettle becomes stable, At a constant temperature of 85 °C for half an hour, the remaining monomer pre-emulsion A, 100 g of sodium hexametaphosphate dispersant and 78 g of oxidativ...
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Abstract
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