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Preparation method of self-adhesive acrylic acid paint for coating

A manufacturing method and self-adhesive technology, applied in the coating and other directions, can solve the problems of high cost, no longer able to be used for printing and composite use, and increased cost.

Active Publication Date: 2014-03-19
HAINAN BNK WATER BASED NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, domestic food packaging films have higher and higher requirements for appearance. Because acrylic acid has high transparency and high gloss, the conventional method is to coat a layer of acrylic paint on the film to make it have a beautiful appearance. At present, the coating of acrylic acid The processing technology is to first coat a layer of polyurethane primer on the substrate, and then coat a layer of acrylic topcoat. The main reason is that the existing acrylic paint and the substrate have poor adhesion. After the machine is cured, almost all the coatings are peeled off with adhesive tape, and the subsequent process can no longer be used for printing and compounding. If a layer of primer is added before acrylic coating, it will not only increase the cost, but also because the current mature technology is mainly solvent-based polyurethane primer. Coating, this coating method pollutes the environment greatly and has a certain impact on the health of operators. Although water-based polyurethane and water-based acrylic primers have been used in recent years, the cost is too high, and the technology has yet to be verified.

Method used

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  • Preparation method of self-adhesive acrylic acid paint for coating
  • Preparation method of self-adhesive acrylic acid paint for coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Put 10kg deionized water, 300g sodium polystyrene sulfonate, 360g methacrylic acid, 100g hydroxypropyl acrylate, 4950g methyl methacrylate and 4540g methyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, the stirring speed is controlled Prepare monomer pre-emulsion A at 100 rpm; add 25kg of deionized water to the polymerization kettle, start stirring at 150 rpm, heat up to 75°C under nitrogen protection, and quickly add 4g of potassium persulfate After 5 minutes, add 5% monomer pre-emulsion A1.01kg, the nucleation polymerization reaction starts, the temperature of the material rises automatically, and the material in the kettle changes from milky white to translucent and bluish; when the temperature in the kettle tends to be stable Finally, keep the temperature at 82°C for half an hour, and start to add the remaining monomer pre-emulsion A, 80g polyvinyl alcohol dispersant and 60g oxidized initiator potassium persulfate dropwise at the same time, and ...

Embodiment 2

[0033] Put 18kg deionized water, 380g sodium vinyl sulfonate, 450g acrylic acid, 150g hydroxypropyl acrylate, 5100g methyl methacrylate and 4800g ethyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, and control the stirring speed at 200 rpm Minutes into the monomer pre-emulsion A; in the polymerization kettle, first add 25kg of deionized water, start stirring, the stirring speed is 120 rpm, the temperature is raised to 80°C under the protection of nitrogen gas, and 2.8g of sodium persulfate is quickly added, and the After 5 minutes, add 5% monomer pre-emulsion liquid A1.43kg, nucleation polymerization promptly begins, and material temperature rises automatically, and material in the kettle becomes translucent pan-blue light by milky white; After the temperature in the kettle tends to be steady, Keep the temperature at 84°C for half an hour, start to add the remaining monomer pre-emulsion A, 80g sodium polyacrylate dispersant and 63g oxidized initiator sodiu...

Embodiment 3

[0035]Put 30kg deionized water, 296g sodium vinyl sulfonate, 378g acrylic acid, 250g hydroxyethyl acrylate, 7500g methyl methacrylate and 6800g n-butyl acrylate into the pre-emulsification tank, mix and stir for 1 hour, and the stirring speed is controlled at 150 rpm Configured as monomer pre-emulsion A per minute; in the polymerization kettle, first add 32 kg of deionized water, start stirring, the stirring speed is 130 rpm, and the temperature is raised to 78 ° C under nitrogen protection, and 5 g of potassium persulfate is quickly added. After 5 minutes, add 5% monomer pre-emulsion A2.21kg, the nucleation polymerization reaction starts, the temperature of the material rises automatically, and the material in the kettle changes from milky white to translucent blue light; after the temperature in the kettle becomes stable, At a constant temperature of 85 °C for half an hour, the remaining monomer pre-emulsion A, 100 g of sodium hexametaphosphate dispersant and 78 g of oxidativ...

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Abstract

The present invention relates to a self-adhesive acrylic acid paint for coating, and a preparation method thereof. The self-adhesive acrylic acid paint is prepared from the following raw materials, 0.6-2% of a functional monomer, 8-11% of a hard monomer, 8-10% of a soft monomer, 0.1-0.8% of an emulsifier, 0.1-0.3% of a dispersing agent, 0.05-0.25% of an antifoaming agent, 0.015-0.2% of an oxidation-type initiator, 0.001-0.02% of a reduction-type initiator, 0.02-0.15% of an electrolyte, 1-5% of ammonia water and 72-82% of deionized water. The method comprises: adding the monomers, the initiators, the emulsifier, the dispersing agent and other components to a reactor; carrying out a polymerization reaction to a certain extent; continuously adding the remaining monomers, the initiators and other raw materials to the reactor in a certain time interval until the reaction is completed. According to the present invention, the paint can be directly coated on the substrate without the base coating; the case of the coating falling is not generated after the coating is cured; the peeling strength of the compounded coating is not affected after performing the next printing compounding process; the paint has high transparency and high glossiness after the paint forms the film; the method has characteristics of low production cost, safety and environmental protection; the primer precoating process in the traditional coating process is reduced so as to substantially save the cost, and provide the pollution-free production for the coating environment.

Description

Technical field [0001] The invention relates to a method for manufacturing a self-adhesive acrylic paint that can be applied to coating various substrate films, and belongs to the field of new environment-friendly polymer materials. Background technique [0002] At present, domestic food packaging films have higher and higher requirements for appearance. Because acrylic acid has high transparency and high gloss, the conventional method is to coat a layer of acrylic paint on the film to make it have a beautiful appearance. At present, acrylic coating The processing technology is to first coat a layer of polyurethane primer on the substrate, and then coat a layer of acrylic topcoat. The main reason is that the existing acrylic paint and the substrate have poor adhesion. After the machine is cured, the coating is almost completely peeled off with adhesive tape, and the subsequent process can no longer be used for printing and compounding. If a layer of primer is added before ac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/00C09D133/12C09D7/12C08F220/14C08F2/24
Inventor 黄宏存邢青涛
Owner HAINAN BNK WATER BASED NEW MATERIAL CO LTD