Magnetic particle chemiluminescence kit for detecting diazepam, and applications thereof
A technology of chemiluminescent reagents and kits, which is applied in the fields of chemiluminescence/bioluminescence, analysis through chemical reactions of materials, and measurement devices, which can solve the problems of cumbersome operation, high detection cost, and poor stability of kits, and achieve The effect of low detection time, fast detection and high sensitivity
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Embodiment 1
[0030] The preparation of embodiment 1 kit specific components
[0031] 1) Synthesis of stable hapten
[0032] The diazepam hapten is prepared by condensation of diazepam and carboxymethyl hydroxylamine.
[0033] 2) Preparation of stabilized artificial antigen
[0034] The immunogen is obtained by coupling the stable hapten with bovine serum albumin by a water-soluble carbodiimide method.
[0035] 3) Preparation of monoclonal antibodies
[0036] Animal immunization: Immunize Balb / c mice with the immunogen at a dose of 100 μg / mouse to produce antiserum.
[0037] Cell fusion and cloning: Splenocytes from immunized Balb / c mice were fused with SP2 / 0 myeloma cells at a ratio of 9:1 to obtain hybridoma cell lines of monoclonal antibodies.
[0038] Cell cryopreservation and recovery: the hybridoma cells were made into 1×10 cryopreservation medium 9 cells / ml for long-term storage in liquid nitrogen. When recovering, take out the cryopreservation tube, put it into a 37°C water ba...
Embodiment 2
[0049] The formation of embodiment two kits
[0050] Construct the direct competition chemiluminescent detection kit for detecting the residual magnetic particles of diazepam so that it contains the following components:
[0051] Fluorescent marker for FITC-labeled diazepam monoclonal antibody
[0052] Luminescent marker of ABEI-labeled stable hapten
[0053] Separation reagent of paramagnetic nanobeads coated with goat anti-FITC monoclonal antibody
[0054] Stability standard solution (0ng / ml, 0.01ng / ml, 0.03ng / ml, 0.1ng / ml, 0.3ng / ml, 1.0ng / ml), the standard diluent is pH7.2, 0.3%NaN 3 , 0.05mol / L TRIS buffer. The percentage content is a mass percentage content.
[0055] The concentrations of stable quality control solution are 0.02ng / ml and 0.8ng / ml respectively, and the dilution solution of quality control is pH7.4, 0.03% NaN3, 0.05mol / L TRIS buffer. The percentage content is a mass percentage content.
[0056] Concentrated lotion pH 7.2, 0.4% Tween-20, 0.3% NaN 3 , ...
Embodiment 3
[0057] The detection of stability in the actual sample of embodiment three
[0058] 1. Sample pretreatment
[0059] (1) Animal tissues (muscle, liver, etc.),
[0060] Take the tissue sample and homogenize it with a homogenizer above 4000rpm for 1min; weigh 2.0±0.05g of the homogenate into a 50ml centrifuge tube, add 8ml of 0.1M sodium hydroxide solution, and shake for 5min. Above 3000g, centrifuge at 15°C for 10min; take 1ml of the supernatant, add 10ml of n-hexane, shake for 5min, and above 3000g, centrifuge at 15°C for 5min; take 5ml of the upper n-hexane phase and dry it in a water bath at 50-60°C under nitrogen flow; add 1ml of complex Dissolve the working solution to dissolve the residue; take 50 μl for analysis, sample dilution factor: 10.
[0061] (2) Urine
[0062] Take 1ml of clear urine sample, add 4ml of 0.1M sodium hydroxide solution to a 50ml centrifuge tube, shake for 2-5min; take 1ml of the mixed solution into another centrifuge tube, add 10ml of n-hexane, sh...
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