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A kind of anti-corrosion and anti-corrosion cold-rolled steel plate surface silanization protective treatment agent and preparation method thereof

A cold-rolled steel plate and silanization technology, applied in anti-corrosion coatings, coatings, etc., can solve problems such as environmental hazards, high energy consumption, and unstable anti-corrosion performance, and achieve the effect of low polarization current density and enhanced corrosion resistance

Active Publication Date: 2016-06-08
广东粤华不锈钢型材股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The phosphating treatment process uses phosphoric acid, zinc, manganese, and nickel as the main raw materials, causing serious environmental pollution such as heavy metals, phosphorus, and nitrite, and will more or less produce sediment and harmful gases during the treatment process, which affects production. If it is carried out normally, the discharged wastewater COD and heavy metals will endanger the environment if it is not treated in an environmentally friendly way; in addition, most of the phosphating treatment needs to be carried out under heating conditions, which consumes a lot of energy, the process is complicated, and the operation is inconvenient
Silane surface treatment technology has appeared, but the film formation of silane surface treatment agent on the metal surface is unstable, the anti-corrosion performance is unstable, and the effect is not good

Method used

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Embodiment Construction

[0018] A corrosion-inhibiting and anti-corrosion cold-rolled steel sheet surface silanization protection treatment agent is made of the following components, and the weight (grams) of each raw material component in every 500 grams of mixed solution is:

[0019] Ammonium Bicarbonate 1, Monoethanolamine Benzoate 2, Sodium Lauryl Sulfate 0.5, Isobutanol 5, Rosin 5, Trihydroxyethyl Isocyanurate 1.5, Maleic Anhydride 12, Diethylene Glycol Butyl Ether 6, propylene glycol 8, phytic acid 5, anilinomethyltriethoxysilane 1, and the balance is deionized water.

[0020] The preparation method of described metal surface silanization protective treatment agent comprises the following steps:

[0021] (1) Heat and melt the rosin to 110-115°C, add diethylene glycol butyl ether, anilinomethyltriethoxysilane, and stir for 35-50 minutes;

[0022] (2), heat up to 145-160°C, add trihydroxyethylisocyanurate, maleic anhydride, sodium lauryl sulfate, and stir for 40-50 minutes;

[0023] (3) Continue...

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Abstract

The invention discloses a corrosion inhibition and corrosion prevention cold rolling steel sheet surface silanization protection treating agent. The corrosion inhibition and corrosion prevention cold rolling steel sheet surface silanization protection treating agent is prepared from compositions of, by weight (g) in every 500g of mixed liquor, 1-2g of ammonium bicarbonate, 1-2g of benzoic acid mono ethanol amine, 0.3-0.5g of lauryl sodium sulfate, 5-8g of isobutyl alcohol, 3-5g of rosin, 1.2-1.5g of 1,3,5-tris(2-hydroxyethyl)cyanuric acid, 10-12g of maleic anhydride, 4-6g of diethylene glycol monobutyl ether, 5-8g of propylene glycol, 3-5g of phytic acid, 1-2 g of anilino-methyl-triethoxysilane, and the balance deionized water. The corrosion inhibition and corrosion prevention cold rolling steel sheet surface silanization protection treating agent uses the rosin as reaction raw materials, polymerizes the rosin with raw materials of the maleic anhydride, silane and the like, can form strong protective film on the surface of metal, and strengthens corrosion resistance of a metallic matrix.

Description

technical field [0001] The invention relates to a silanization treatment agent on the metal surface and a process for silanization treatment on the metal surface. Background technique [0002] Phosphating treatment has been widely used in metal coating pretreatment, lubrication, antirust and other industries. Especially in the coating pretreatment industry, phosphating treatment is one of the most commonly used pretreatment methods. Phosphating treatment is the process of forming a phosphate protective film on the surface of a metal after reacting in an acidic phosphate solution. Phosphate film also has good lubricity, insulation and corrosion resistance, so it is widely used in the manufacturing fields of automobiles, machinery manufacturing, aerospace and household appliances. The phosphating treatment process uses phosphoric acid, zinc, manganese, and nickel as the main raw materials, causing serious environmental pollution such as heavy metals, phosphorus, and nitrite,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/06C09D7/12C09D5/08
Inventor 夏坤财
Owner 广东粤华不锈钢型材股份有限公司
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